硅酸盐学报

Y₂O₃-MgO纳米复相中红外激光基质材料研究进展

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穆浩洁 , 李晓东

硅酸盐学报 | 综合评述 2024,52(3): 1117-1127

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硅酸盐学报 |综合评述 2024 , 52 (3) : 1117 -1127

Y₂O₃-MgO纳米复相中红外激光基质材料研究进展

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穆浩洁, 李晓东

作者信息

东北大学材料科学与工程学院，材料各向异性与织构教育部重点实验室，沈阳 110819

通讯作者:

李晓东（1971—），男，博士，教授。

作者简介:

穆浩洁（1999—），女，博士研究生。

Research Progress on Y₂O₃-MgO Nanocomposite Ceramics as Medium Infrared Laser Host Materials

Haojie MU, Xiaodong LI

Affiliations

School of Materials Science and Engineering, Northeastern University, Key Laboratory of Material Anisotropy and Texture, Ministry of Education, Shenyang 110819, China

Corresponding Author:

LI Xiaodong (1971-), male, Ph.D., Professor. E-mail: xdli@mail.neu.edu.cn

MU Haojie (1999-), female, Doctor candidate. E-mail: 2110169@stu.neu.edu.cn

出版时间: 2024-03-20 doi: 10.14062/j.issn.0454-5648.20230519

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摘要

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采用激光二极管直接泵浦中红外激光材料的激光器具有系统简单、转换效率高及激光光束质量好等优势，受到越来越广泛的关注。目前，常用的激光材料如玻璃、晶体、单相多晶透明陶瓷均存在不足。具有优异的光学、热学及力学性能的纳米复相陶瓷成为了中红外激光器的理想激光材料。本文介绍了Y₂O₃-MgO纳米复相陶瓷的性能，同时概述了其新型的制备方法、性能优化思路以及稀土离子掺杂中红外激光基质材料的研究现状，并对Y₂O₃-MgO纳米复相陶瓷作为中红外激光基质材料的发展前景做了展望与分析。

关键词

纳米复相陶瓷 / 红外透明 / 中红外激光 / 基质材料

Abstract

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The 3-5 μm mid-infrared laser can be used in infrared countermeasures, biomedicine, atmospheric remote sensing and environmental monitoring. All solid-state lasers using LD directly pumped laser materials become a main output method for mid infrared lasers due to their advantages like simple system, high conversion efficiency, and good beam quality. Polycrystalline transparent ceramics are commonly used as laser materials due to their preparation easiness, superior thermal and mechanical properties as well as the ability to achieve high doping concentrations. However, the development of high-power lasers requires overcoming the inevitable thermal effects during laser operation, i.e., thermal birefringence, thermal lensing, and depolarization, which arise from the temperature gradient inside the laser material. It is crucial to use laser materials with a high thermal conductivity to alleviate thermal effects and ensure the quality and stability of laser output. Moreover, laser host materials must also have a lower phonon energy to suppress non-radiative transition processes that compete with the luminescence processes. It is thus difficult for materials to simultaneously possess all of these properties.

In recent years, a large number of reports have claimed that Y₂O₃-MgO nanocomposite ceramics have ideal properties required for laser host materials, including high infrared transmittance, low phonon energy, high thermal conductivity, and good mechanical properties. The microstructure and properties of Y₂O₃-MgO nanocomposite ceramics doped with rare-earth activation ions are investigated, indicating that nanocomposite ceramics can be used as potential host materials for mid infrared lasers.

This review summarized the existing research results of Y₂O₃-MgO nanocomposite ceramics as a laser host material and also represented recent technologies and methods for preparing Y₂O₃-MgO nanocomposite ceramics.

The existing studies by theoretical models and experiments indicate that Y₂O₃-MgO nanocomposite ceramics have a high thermal conductivity, compared with Y₂O₃ ceramics, and a low maximum phonon energy (591cm^-1). This is due to a synergistic effect of composite properties, combined with a high thermal conductivity of the second phase MgO and a low phonon energy of Y₂O₃. However, the optical transmittance of Y₂O₃-MgO nanocomposite ceramics is mainly affected by grain size, porosity, and phase domain distribution, which makes it imperative to improve their microstructure. Therefore, some technologies and methods for preparing ceramics are emerged, i.e., colloidal forming, two-step sintering, high-pressure sintering, and reducing a difference in refractive index between the two phases. Moreover, the research results of rare-earth ion doped nanocomposite ceramics, such as Er: Y₂O₃-MgO and Ho:Y₂O₃-MgO, also confirm that the introduction of high thermal conductivity MgO can effectively improve the thermal conductivity of ceramics without affecting the photoluminescence properties of the luminescent components, indicating that Y₂O₃-MgO nanocomposite ceramics can be used as promising laser host materials.

Summary and prospects

Y₂O₃-MgO nanocomposite ceramics are promising laser host materials. However, there is still a gap between the optical quality requirements of Y₂O₃-MgO nanocomposite ceramics and infrared laser materials, even though researchers have made significant efforts to improve the microstructure of Y₂O₃-MgO nanocomposite ceramics. This leads to the preliminary characterization and analysis of the photoluminescence characteristics of rare-earth ion doped Y₂O₃-MgO nanocomposite ceramics, and has not yet achieved infrared laser output. There are still some aspects that need further research and exploration before its practical application: 1) Developing preparation methods and optimizing processing parameters are the main direction of future research to obtain the dense samples, while effectively suppressing their grain growth. If the grain size is small enough, it is expected to expand the transmittance range of Y₂O₃-MgO nanocomposite ceramics to the visible light band and apply it to the field of mid infrared lasers, 2) Different activation ions and pump light sources are needed to be selected for laser output at different wavelengths, and even sensitizers need to be added to match the existing pump light. As a result, it is necessary to investigate the influence of rare-earth dopants on the microstructure, thermal properties, optical properties, and laser output performance of nanocomposite ceramic systems, and 3) In order to expand the selection range of laser host materials, a further diversified research on nanocomposite ceramics needs to be carried out.

Key words

nanocomposite ceramics / infrared transparency / mid-infrared laser / matrix material

引用本文

穆浩洁, 李晓东. Y₂O₃-MgO纳米复相中红外激光基质材料研究进展. 硅酸盐学报, 2024 , 52 (3) : 1117 -1127 . DOI: 10.14062/j.issn.0454-5648.20230519

Haojie MU, Xiaodong LI. Research Progress on Y₂O₃-MgO Nanocomposite Ceramics as Medium Infrared Laser Host Materials[J]. Journal of the Chinese Ceramic Society, 2024 , 52 (3) : 1117 -1127 . DOI: 10.14062/j.issn.0454-5648.20230519

基金

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国家重点研发计划项目(2017YFB0310300)

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2024年第52卷第3期

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文章信息

doi: 10.14062/j.issn.0454-5648.20230519

接收时间：2023-07-22
首发时间：2026-10-22
出版时间：2024-03-20

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收稿日期：2023-07-22
修回日期：2023-08-22

基金

国家重点研发计划项目(2017YFB0310300)

作者信息

东北大学材料科学与工程学院，材料各向异性与织构教育部重点实验室，沈阳 110819

通讯作者:

李晓东（1971—），男，博士，教授。

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https://castjournals.cast.org.cn/joweb/gsyxb/CN/10.14062/j.issn.0454-5648.20230519

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2种不同金属材料的力学参数

科 Family	属数 Number of genus	种数 Number of species	占总种数比例 Percentage of total species (%)	属 Genus	种数 Number of species	占总种数比例 Percentage of total species (%)
鹅膏菌科Amanitaceae	2	11	5.26	鹅膏菌属 Amanita	10	4.78
小菇科 Mycenaceae	2	12	5.74	丝盖伞属 Inocybe	5	2.39
多孔菌科 Polyporaceae	8	14	6.70	蜡蘑属 Laccaria	5	2.39
红菇科 Russulaceae	3	23	11.00	小皮伞属 Marasmius	6	2.87
				小菇属 Mycena	11	5.26
				光柄菇属 Pluteus	5	2.39
				红菇属 Russula	17	8.13
				栓菌属 Trametes	5	2.39

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