硅酸盐学报

高熵化透明陶瓷研究进展

PDF下载

韩文瀚 ¹^,² , 朱兴华 ³ , 承刚 ³ , 郭浩 ¹ , 李诗睿 ¹ , 顾博森 ¹ , 卢开雷 ¹^,² , 卢铁城 ¹^,²^,⁴ , 叶昱成 ⁵ , 齐建起 ¹^,²^,⁴

硅酸盐学报 | 综合评述 2024,52(3): 945-972

收起

硅酸盐学报 |综合评述 2024 , 52 (3) : 945 -972

高熵化透明陶瓷研究进展

全屏

韩文瀚¹^,², 朱兴华³, 承刚³, 郭浩¹, 李诗睿¹, 顾博森¹, 卢开雷¹^,², 卢铁城¹^,²^,⁴, 叶昱成⁵, 齐建起¹^,²^,⁴

作者信息

^1．四川大学物理学院，成都 610064

^2．高能量物理及技术教育部重点实验室，成都 610064

^3．四川文理学院，四川达州 635000

^4．辐射物理及技术教育部重点实验室，成都 610064

^5．香港大学李嘉诚医学院，香港 999077

通讯作者:

叶昱成（2000—），男，博士研究生。

齐建起（1981—），男，博士，教授。

作者简介:

韩文瀚（2000—），男，硕士研究生。

Research Progress on High-Entropy Transparent Ceramics

Wenhan HAN¹^,², Xinghua ZHU³, Gang CHENG³, Hao GUO¹, Shirui LI¹, Bosen GU¹, Kailei LU¹^,², Tiecheng LU¹^,²^,⁴, Yucheng YE⁵, Jianqi QI¹^,²^,⁴

Affiliations

^1.College of Physics, Sichuan University, Chengdu 610064, China

^2.Key Laboratory of High Energy Density Physics of Ministry of Education, Sichuan University, Chengdu 610064, China

^3.Sichuan University of Arts and Science, Dazhou 635000, Sichuan, China

^4.Key Laboratory of Radiation Physics and Technology of Ministry of Education, Sichuan University, Chengdu 610064, China

^5.School of Biomedical Sciences, LKS Faculty of Medicine, University of Hong Kong, Hong Kong 999077, China

Corresponding Author:

YE Yucheng (2000-), male, Doctorial candidate. E-mail: 1005636408@qq.com;

QI Jianqi (1981-), male, Ph.D., Professor. qijianqi@scu.edu.cn

HAN Wenhan (2000-), male, Master candidate. E-mail: 1010393029@qq.com

出版时间: 2024-03-20 doi: 10.14062/j.issn.0454-5648.20230665

文章导航

摘要

收起

透明陶瓷作为一种具有优异理化性能的结构功能一体化材料，多年来已在诸多领域替代传统透明材料进行使用，如固态照明、高功率固体激光器、高密度屏蔽窗口、光学元件及光电器件等，而近年来高熵陶瓷的研究为透明陶瓷的进一步发展提供新思路。透明陶瓷高熵化使其可利用高的构型熵来改善或提升其力、热、光学等性能，从而实现更多领域、更深层次的功能化应用。综述了作为高熵透明陶瓷潜在结构的几种陶瓷体系的结构、制备、性能和应用进展，详细介绍了当前透明陶瓷高熵化研究的现况，并对其未来的发展及应用进行展望。

关键词

透明陶瓷 / 高熵化 / 光功能材料

Abstract

收起

High-entropy transparent ceramics (HETCs) are a type of ceramic material that is transparent and has high mechanical strength and thermal stability, which have attracted recent attention. The fabrication of HETCs involves the use of multiple elements in equal atomic proportions, leading to their unique properties. This review discussed the significance, progress, conclusion, and prospects of HETCs.

HETCs have a potential to revolutionize several industries like aerospace, defense, and optoelectronics. HETCs can be used as a transparent armor in military vehicles, and transparent windows in aerospace vehicles, and as protective covers for electronic devices. The unique properties of HETCs (i.e., high mechanical strength, thermal stability, and transparency) make them ideal for these applications. Furthermore, HETCs can be used as a substrate for thin-film solar cells with the better light transmission, compared to glass substrates.

The development of HETCs that are transparent in the visible and near-infrared regions of the electromagnetic spectrum is a significant achievement, as it allows for their use in optoelectronic applications. The high thermal stability of HETCs makes them suitable for high-temperature applications, which is essential in several industries.

The high-entropy concept in these ceramics refers to the deliberate mixing of multiple elements in equal or nearly equal proportions. This random arrangement of elements results in a high degree of disorder, or entropy, within the crystal structure of the material. HETCs can achieve a unique combination of properties that surpass those of conventional ceramics via incorporating different elements.

One of the key characteristics of HETCs is their ability to maintain transparency even under extreme conditions. Unlike conventional ceramics, which are typically opaque, HETCs exhibit a high degree of optical transparency, allowing a light to pass through them with minimal distortion. This property is particularly advantageous in applications on optical devices, windows, and lenses.

Besides, one of the most significant advantages of HETCs is their exceptional mechanical strength. These ceramics exhibit great hardness, toughness, and resistance to fracture, making them suitable for high-stress environments. This property has some possibilities for their use in structural applications, such as protective coatings and armor.

Another remarkable characteristic of HETCs is the superior thermal stability. These ceramics can withstand at high temperatures without undergoing significant structural or optical degradation. This thermal resilience makes them ideal for applications that require exposure to extreme heat, such as in aerospace and power generation systems.

Furthermore, HETCs have a great potential in the field of optoelectronics. Their unique combination of transparency and electrical conductivity makes them suitable for various electronic and photonic devices. For instance, HETCs can be utilized in transparent electrodes, transparent conductive films, and even as substrates for flexible electronics.

Despite their immense potential, the development of HETCs is still in its early stages, and there are numerous challenges that need to be addressed. The fabrication of these ceramics requires a precise control on the composition and processing conditions to achieve the desired properties. Also, the cost of production remains an obstacle that needs to be overcome for their widespread adoption.

The fabrication of HETCs is a complex process that involves the use of high-temperature sintering techniques. HETCs are typically produced via a solid-state sintering process, in which the constituent powders are compacted and heated at high temperatures to form a dense, homogeneous material. In sintering, the constituent powders diffuse and react with one another, leading to the formation of a complex, multi-component material. Progress on the development of HETCs is made in recent years. One of the most significant achievements in this field is the development of HETCs that are transparent in the visible and near-infrared regions of the electromagnetic spectrum. HETCs with a high thermal stability is also developed for high-temperature applications.

Summary and prospects

High-entropy transparent ceramics represent a fascinating and promising material. Their unique combination of transparency, mechanical strength, thermal stability, and electrical conductivity makes them highly desirable for a wide range of applications. With their development, HETCs revolutionize various industries, having some possibilities in applications like optoelectronics, thermal management, and beyond.

However, the development of HETCs is still in its early stages, and there are many challenges that need to be addressed before these materials can be widely adopted. One of the main challenges is an ability to produce HETCs in a reproducible and scalable manner. HETCs are typically produced via solid-state sintering process, in which is difficult to control and scale up to industrial levels.

Another challenge is an ability to tailor the properties of HETCs for specific applications. The properties of these materials can be highly complex and difficult to predict decause HETCs are composed of multiple principal elements. Therefore, a fundamental understanding for the relationship among composition, processing and properties is critical for the development of HETCs.

Key words

transparent ceramics / high entropy / optical function materials

引用本文

韩文瀚, 朱兴华, 承刚, 郭浩, 李诗睿, 顾博森, 卢开雷, 卢铁城, 叶昱成, 齐建起. 高熵化透明陶瓷研究进展. 硅酸盐学报, 2024 , 52 (3) : 945 -972 . DOI: 10.14062/j.issn.0454-5648.20230665

Wenhan HAN, Xinghua ZHU, Gang CHENG, Hao GUO, Shirui LI, Bosen GU, Kailei LU, Tiecheng LU, Yucheng YE, Jianqi QI. Research Progress on High-Entropy Transparent Ceramics[J]. Journal of the Chinese Ceramic Society, 2024 , 52 (3) : 945 -972 . DOI: 10.14062/j.issn.0454-5648.20230665

基金

收起

国家自然科学基金项目(U21A20441)
四川大学-达州市人民政府战略合作项目(2021CDDZ-02)

参考文献

收起

文献

收起

参考文献引证文献

排序方式：

2024年第52卷第3期

PDF下载

引用本文

BibTeX

文章信息

doi: 10.14062/j.issn.0454-5648.20230665

接收时间：2023-08-31
首发时间：2026-10-22
出版时间：2024-03-20

补充材料

相关文章

文章信息

作者

出版历史

收稿日期：2023-08-31
修回日期：2023-10-14

基金

国家自然科学基金项目(U21A20441)

四川大学-达州市人民政府战略合作项目(2021CDDZ-02)

作者信息

^1．四川大学物理学院，成都 610064

^2．高能量物理及技术教育部重点实验室，成都 610064

^3．四川文理学院，四川达州 635000

^4．辐射物理及技术教育部重点实验室，成都 610064

^5．香港大学李嘉诚医学院，香港 999077

通讯作者:

叶昱成（2000—），男，博士研究生。

齐建起（1981—），男，博士，教授。

参考文献

分享链接

https://castjournals.cast.org.cn/joweb/gsyxb/CN/10.14062/j.issn.0454-5648.20230665

分享至

全文二维码

扫描看全文

引用本文

BibTeX

本文的引用情况

2种不同金属材料的力学参数

科 Family	属数 Number of genus	种数 Number of species	占总种数比例 Percentage of total species (%)	属 Genus	种数 Number of species	占总种数比例 Percentage of total species (%)
鹅膏菌科Amanitaceae	2	11	5.26	鹅膏菌属 Amanita	10	4.78
小菇科 Mycenaceae	2	12	5.74	丝盖伞属 Inocybe	5	2.39
多孔菌科 Polyporaceae	8	14	6.70	蜡蘑属 Laccaria	5	2.39
红菇科 Russulaceae	3	23	11.00	小皮伞属 Marasmius	6	2.87
				小菇属 Mycena	11	5.26
				光柄菇属 Pluteus	5	2.39
				红菇属 Russula	17	8.13
				栓菌属 Trametes	5	2.39

关闭全屏

BibTeX
EndNote
RefWorks
TxT