Article(id=1319237185568616663, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319237171312177253, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20220522, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1656345600000, receivedDateStr=2022-06-28, revisedDate=1662134400000, revisedDateStr=2022-09-03, acceptedDate=null, acceptedDateStr=null, onlineDate=1792460255280, onlineDateStr=2026-10-20, pubDate=1671465600000, pubDateStr=2022-12-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792460255280, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792460255280, creator=13701087609, updateTime=1792460255280, updator=13701087609, issue=Issue{id=1319237171312177253, tenantId=1146029695717560320, journalId=1263187385517883426, year='2022', volume='50', issue='12', pageStart='3091', pageEnd='3336', issueExtLink='null', onlineDate='null', pubDate='1671465600000', pubDateStr='2022-12-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1792460251882, creator='13701087609', updateTime=1792460721974, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319239143067071226, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319237171312177253, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319239143067071227, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319237171312177253, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=3103, endPage=3109, ext={EN=ArticleExt(id=1319237185769943256, articleId=1319237185568616663, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Constructing Energy Traps and Regulating Multimode Luminescence in Garnet-Type Na2CaSn2Ge3O12:Mn2+, columnId=1321891473390415997, journalTitle=Journal of the Chinese Ceramic Society, columnName=Advanced Rare Earth Luminescence Materials for Sensing and Detection—Research Articles, runingTitle=null, highlight=null, articleAbstract=

Mn2+ doped garnet-type Na2CaSn2Ge3O12 phosphor was selected and studied due to its abundant chemical compositions and several crystallographic sites. Several ion substitution strategies including the chemical substitution of Na+/Sr2+/Ba2+ on Ca2+ sites and the anti-site occupation of Sn4+/Ge4+ were designed for regulating the different energy traps and promoting multimode luminescence properties like persistent luminescence, X-ray storage capacities and mechano-luminescence. In addition, the X-ray luminescence storage and mechano-luminescence properties of these materials as well as their applications on X-ray luminescence extension imaging and stress sensing were also investigated.

, authors=Xinquan ZHOU1, Zhiguo XIA1, 2, authorsList=Xinquan ZHOU, Zhiguo XIA, authorCompany=null, correspAuthors=Zhiguo XIA, authorNote=

ZHOU Xinquan (1995-), male, Doctoral candidate. E-mail:

, correspAuthorsNote=
XIA Zhiguo (1979-), male, Ph.D., Professor. E-mail:
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以Mn2+掺杂石榴石结构Na2CaSn2Ge3O12无机发光材料为研究对象,基于其丰富的化学组成与多样化的晶体学格位特征,采用不同化学计量比Na+/Sr2+/Ba2+阳离子对Ca2+格位取代,以及Sn4+/Ge4+反位占据等掺杂调控手段,实现了该材料体系中能量陷阱的类型、浓度和分布调制的多样化构筑,由此提升并精准调控该无机发光材料的余辉、X射线发光存储和应力发光的多模式发光性能。探索并展示了掺杂型Na2CaSn2Ge3O12:Mn2+基发光材料在X射线发光扩展成像、应力传感等领域的潜在应用前景。

, authors=周新全1, 夏志国1, 2, authorsList=周新全, 夏志国, authorCompany=null, correspAuthors=夏志国, authorNote=

周新全(1995—),男,博士研究生。

, correspAuthorsNote=
夏志国(1979—),男,博士,教授。
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石榴石结构Na2CaSn2Ge3O12:Mn2+的能量陷阱构筑与多模式发光性能调控
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周新全 1 , 夏志国 1, 2
硅酸盐学报 | 稀土发光传感与探测新材料专题—研究论文 2022,50(12): 3103-3109
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硅酸盐学报 |稀土发光传感与探测新材料专题—研究论文 2022 , 50 (12) : 3103 -3109
石榴石结构Na2CaSn2Ge3O12:Mn2+的能量陷阱构筑与多模式发光性能调控
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周新全1 , 夏志国1, 2
作者信息
  • 1.华南理工大学材料科学与工程学院,发光材料与器件国家重点实验室,广东省光纤激光材料与应用技术重点实验室,广州 510641
  • 2.华南理工大学物理与光电学院,广州 510641
通讯作者:
夏志国(1979—),男,博士,教授。
作者简介:

周新全(1995—),男,博士研究生。

Constructing Energy Traps and Regulating Multimode Luminescence in Garnet-Type Na2CaSn2Ge3O12:Mn2+
Xinquan ZHOU1 , Zhiguo XIA1, 2
Affiliations
  • 1.State Key Laboratory of Luminescent Materials and Devices, Guangdong Provincial Key Laboratory of Fiber Laser Materials and Applied Techniques, School of Materials Science and Engineering, South China University of Technology, Guangzhou 510641, China
  • 2.School of physics and Optoelectronics, South China University of Technology, Guangzhou 510641, China
  • Corresponding Author:
    XIA Zhiguo (1979-), male, Ph.D., Professor. E-mail:

    ZHOU Xinquan (1995-), male, Doctoral candidate. E-mail:

出版时间: 2022-12-20 doi: 10.14062/j.issn.0454-5648.20220522
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以Mn2+掺杂石榴石结构Na2CaSn2Ge3O12无机发光材料为研究对象,基于其丰富的化学组成与多样化的晶体学格位特征,采用不同化学计量比Na+/Sr2+/Ba2+阳离子对Ca2+格位取代,以及Sn4+/Ge4+反位占据等掺杂调控手段,实现了该材料体系中能量陷阱的类型、浓度和分布调制的多样化构筑,由此提升并精准调控该无机发光材料的余辉、X射线发光存储和应力发光的多模式发光性能。探索并展示了掺杂型Na2CaSn2Ge3O12:Mn2+基发光材料在X射线发光扩展成像、应力传感等领域的潜在应用前景。

无机发光材料  /  能量陷阱  /  应力发光  /  传感

Mn2+ doped garnet-type Na2CaSn2Ge3O12 phosphor was selected and studied due to its abundant chemical compositions and several crystallographic sites. Several ion substitution strategies including the chemical substitution of Na+/Sr2+/Ba2+ on Ca2+ sites and the anti-site occupation of Sn4+/Ge4+ were designed for regulating the different energy traps and promoting multimode luminescence properties like persistent luminescence, X-ray storage capacities and mechano-luminescence. In addition, the X-ray luminescence storage and mechano-luminescence properties of these materials as well as their applications on X-ray luminescence extension imaging and stress sensing were also investigated.

multimode luminescent materials  /  energy trap  /  mechano-luminescence  /  sensor
周新全, 夏志国. 石榴石结构Na2CaSn2Ge3O12:Mn2+的能量陷阱构筑与多模式发光性能调控. 硅酸盐学报, 2022 , 50 (12) : 3103 -3109 . DOI: 10.14062/j.issn.0454-5648.20220522
Xinquan ZHOU, Zhiguo XIA. Constructing Energy Traps and Regulating Multimode Luminescence in Garnet-Type Na2CaSn2Ge3O12:Mn2+[J]. Journal of the Chinese Ceramic Society, 2022 , 50 (12) : 3103 -3109 . DOI: 10.14062/j.issn.0454-5648.20220522
  • 国家自然科学基金(51972118)
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doi: 10.14062/j.issn.0454-5648.20220522
  • 接收时间:2022-06-28
  • 首发时间:2026-10-20
  • 出版时间:2022-12-20
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  • 收稿日期:2022-06-28
  • 修回日期:2022-09-03
基金
国家自然科学基金(51972118)
作者信息
    1.华南理工大学材料科学与工程学院,发光材料与器件国家重点实验室,广东省光纤激光材料与应用技术重点实验室,广州 510641
    2.华南理工大学物理与光电学院,广州 510641

通讯作者:

夏志国(1979—),男,博士,教授。
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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