Article(id=1319236734316040450, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319236705027207343, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20220085, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1643126400000, receivedDateStr=2022-01-26, revisedDate=1643817600000, revisedDateStr=2022-02-03, acceptedDate=null, acceptedDateStr=null, onlineDate=1792460147693, onlineDateStr=2026-10-20, pubDate=1666195200000, pubDateStr=2022-10-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792460147693, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792460147693, creator=13701087609, updateTime=1792460147693, updator=13701087609, issue=Issue{id=1319236705027207343, tenantId=1146029695717560320, journalId=1263187385517883426, year='2022', volume='50', issue='10', pageStart='2579', pageEnd='2808', issueExtLink='null', onlineDate='null', pubDate='1666195200000', pubDateStr='2022-10-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1792460140711, creator='13701087609', updateTime=1792460672919, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319238937323884737, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319236705027207343, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319238937323884738, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319236705027207343, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=2754, endPage=2761, ext={EN=ArticleExt(id=1319236734542532867, articleId=1319236734316040450, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Construction of Expansion Molybdenite/Carbon Composites Material and Its Lithium Storage Properties, columnId=1321898015569331178, journalTitle=Journal of the Chinese Ceramic Society, columnName=Advanced Founctional Geomaterials—Research Articles, runingTitle=null, highlight=null, articleAbstract=

Natural molybdenite has the advantages of low cost and high lithium storage capacity, which can be directly used as an anode material of lithium-ion batteries. In this paper, expanded molybdenite/carbon (EM/C) composites were constructed via expanding molybdenite and surface modification with dopamine. The worm-like structure of expanded molybdenite (EM) has a high specific surface area that is conducive to electrolyte infiltration and diffusion of lithium ions. The amorphous carbon layer effectively increases its electrical conductivity and provides a buffer space for volume enlargement during MoS₂ cycle. The EM/C composites have a long cycle life and a high capacity, with a capacity of 1 213 mA·h/g at 100 mA/g after 200 cycles and a reversible capacity of 623 mA·h/g even at 1 A/g. The strategy of EM/C composite material constructed from molybdenite fine powder has a specific guiding significance to achieve the superior electrochemical performance of lithium-ion battery.

, authors=Chenglong PENG^{1, 2}, Mingming SHI^{1, 2}, qian LIU^{1, 2}, Huasheng LIU^{1, 2}, Zhen LI^{1, 2}, authorsList=Chenglong PENG, Mingming SHI, qian LIU, Huasheng LIU, Zhen LI, authorCompany=null, correspAuthors=Zhen LI, authorNote=, correspAuthorsNote=, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1319236734823551236, articleId=1319236734316040450, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=膨胀辉钼矿/碳复合材料构筑及其储锂性能, columnId=1321898015758074859, journalTitle=硅酸盐学报, columnName=高性能矿物功能材料专题—研究论文, runingTitle=null, highlight=null, articleAbstract=

天然辉钼矿具有低成本、高储存锂的优势，可直接用作锂离子电池负极材料。首先对辉钼矿进行膨胀处理，然后利用多巴胺进行表面改性，构建了膨胀辉钼矿/碳（EM/C）复合材料。膨胀法制备的蠕虫状膨胀辉钼矿（EM）具有较高的比表面积，有利于电解质的渗透和锂离子的扩散。无定形碳层有效地提高了其电导率，并为MoS₂循环过程中体积变大提供了缓冲空间。EM/C复合材料具有较长的循环寿命和高容量，在电流密度100 mA/g下，循环200圈容量仍可高达1 213 mA·h/g，即便在1 A/g的大电流密度下，仍有623 mA·h/g的可逆容量。以辉钼矿精粉为原料构建EM/C复合材料的策略，对实现锂离子电池优异的电化学性能具有一定指导意义。

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PENG Chenglong (1993−), male, Doctoral candidate. E-mail: clpeng@cug.edu.cn

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PENG Chenglong (1993−), male, Doctoral candidate. E-mail: clpeng@cug.edu.cn

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彭成龙（1993—），男，博士研究生。

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彭成龙（1993—），男，博士研究生。

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