Article(id=1319236585116255036, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319236561179366013, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20211074, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1639065600000, receivedDateStr=2021-12-10, revisedDate=1641657600000, revisedDateStr=2022-01-09, acceptedDate=null, acceptedDateStr=null, onlineDate=1792460112122, onlineDateStr=2026-10-20, pubDate=1663603200000, pubDateStr=2022-09-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792460112122, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792460112122, creator=13701087609, updateTime=1792460112122, updator=13701087609, issue=Issue{id=1319236561179366013, tenantId=1146029695717560320, journalId=1263187385517883426, year='2022', volume='50', issue='9', pageStart='2351', pageEnd='2578', issueExtLink='null', onlineDate='null', pubDate='1663603200000', pubDateStr='2022-09-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1792460106415, creator='13701087609', updateTime=1792460650608, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319238843744764843, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319236561179366013, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319238843744764844, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319236561179366013, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=2455, endPage=2462, ext={EN=ArticleExt(id=1319236585325970237, articleId=1319236585116255036, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Na⁺-Doped γ-Ce₂S₃ Bright Red Pigment Coated with Mullite, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=

γ-Ce₂S₃ is a kind of non-toxic environmental protection red inorganic pigment due to its bright color, intense hiding power and superior ultraviolet resistance. However, its antioxidant temperature is 350 ℃. To improve the oxidation resistance temperature of γ-Ce₂S₃, a mullite coated Na⁺ ion-doped γ-Ce₂S₃ (i.e., γ-[Na]-Ce₂S₃@mullite) was synthesized by a sol-gel method and a subsequent sulfuration-heating process. The synthetic conditions of mullite as well as the effect of pre-firing temperature on the morphology of precursor and chromaticity value of the coated pigments were investigated, and the thermal stability of the coated pigments was also analyzed. The results show that short rod-like and spheroidal mullite crystals can be synthesized at 1 300 ℃ for 3 h as n_Al∶n_Si=3.2∶2.0, and the optimum chromaticity value (i.e., L^*=36.24, a^*=41.86, b^*=36.26) of the coated pigment can be obtained when the pre-firing temperature is 400 ℃. The pigment has a good chromaticity value (i.e., L^*=29.84, a^*=20.83, b^*=18.17) when being in air at 800 ℃ for 10 min. This study indicates that γ-[Na]-Ce₂S₃@mullite can increase the antioxidant temperature of γ-Ce₂S₃ from 350 ℃ to 800 ℃.

, authors=Dewei REN, Yueming LI, Zhumei WANG, Kai LI, Yi SUN, Fusheng SONG, authorsList=Dewei REN, Yueming LI, Zhumei WANG, Kai LI, Yi SUN, Fusheng SONG, authorCompany=null, correspAuthors=Yueming LI, authorNote=, correspAuthorsNote=, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1319236585623765822, articleId=1319236585116255036, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=莫来石包裹Na⁺掺杂型γ-Ce₂S₃大红色料, columnId=1263922770220560512, journalTitle=硅酸盐学报, columnName=研究论文, runingTitle=null, highlight=null, articleAbstract=

γ-Ce₂S₃是一种无毒环保型大红无机色料，色泽鲜艳、遮盖力强、具有优异的抗紫外能力，但其抗氧化温度为350 ℃。为提升γ-Ce₂S₃大红色料的抗氧化温度，采用溶胶-凝胶法结合硫化升温工艺，合成了莫来石包裹的Na⁺掺杂型γ-Ce₂S₃大红色料（记为γ-[Na]-Ce₂S₃@mullite），研究了莫来石的合成条件、不同预烧温度对包裹色料前驱体形貌以及色度的影响，并分析了包裹色料的温度稳定性。结果表明：当烧结温度为1 300 ℃保温3 h、n（Al）∶n（Si）=3.2∶2.0（n为摩尔）时，可合成短棒状和类球状的莫来石晶体；当预烧温度为400 ℃，可获得最佳色度值的包裹色料：L^*=36.24、a^*=41.86、b^*=36.26，该色料在空气气氛下800 ℃保温10 min仍具有良好的色度值：L^*=29.84、a^*=20.83、b^*=18.17，表明γ-[Na]-Ce₂S₃@mullite可使γ-Ce₂S₃的温度稳定性从350 ℃提升至800 ℃。

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REN Dewei (1996-), male, Master candidate. E-mail: 920515910@qq.com

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REN Dewei (1996-), male, Master candidate. E-mail: 920515910@qq.com

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任德威（1996—），男，硕士研究生。

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任德威（1996—），男，硕士研究生。

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