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Article(id=1319236468401353313, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319236433387303232, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20210765, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1630512000000, receivedDateStr=2021-09-02, revisedDate=1631808000000, revisedDateStr=2021-09-17, acceptedDate=null, acceptedDateStr=null, onlineDate=1792460084295, onlineDateStr=2026-10-20, pubDate=1660924800000, pubDateStr=2022-08-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792460084295, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792460084295, creator=13701087609, updateTime=1792460084295, updator=13701087609, issue=Issue{id=1319236433387303232, tenantId=1146029695717560320, journalId=1263187385517883426, year='2022', volume='50', issue='8', pageStart='2067', pageEnd='2350', issueExtLink='null', onlineDate='null', pubDate='1660924800000', pubDateStr='2022-08-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1792460075946, creator='13701087609', updateTime=1792460621958, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319238723569569958, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319236433387303232, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319238723569569959, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319236433387303232, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=2230, endPage=2238, ext={EN=ArticleExt(id=1319236468594291298, articleId=1319236468401353313, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Effect of Tetrasodium Hydroxyethylidene Diphosphonate on Fresh and Hardening Properties of Alkali-Activated Slag Materials, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=

The effect of tetrasodium hydroxyethylidene diphosphonate (HEDP.Na4) on the fresh and hardening properties of alkali-activated slag materials (AASM) was investigated. Compared with the control group, the initial and final setting time of AASM made with HEDP.Na4 are delayed by 43.8% and 25.0%, respectively. The mini slump of AASM with HEDP.Na4 is increased by 15% and its yield stress is decreased from 57.2 Pa to 26.6 Pa, as compared with AASM without HEDP.Na4. In addition, the compressive and flexural strengths at 3 days of AASM with HEDP.Na4 are reduced, but those at 28 days are increased by 15% and 11.6%, compared with AASM without HEDP.Na4. HEDP.Na4 can reduce the early hydration heat, modify the pore structure, and reduce the total porosity of AASM matrix. Comprehensively, HEDP.Na4 effectively improves the early working performance of AASM and the later hardening performance slightly. This research can provide a guidance for the application of AASM in construction engineering.

, authors=Wujian LONG1, 2, 3, Xuanhan ZHANG1, 2, 3, Zhuorui WU1, 2, 3, Chenyu WANG1, 2, 3, Biqin DONG1, 2, 3, Jingjie WEI1, 3, 4, authorsList=Wujian LONG, Xuanhan ZHANG, Zhuorui WU, Chenyu WANG, Biqin DONG, Jingjie WEI, authorCompany=null, correspAuthors=null, authorNote=

LONG Wujian (1977-), male, Ph.D., Professor. E-mail:

, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1319236468812395107, articleId=1319236468401353313, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=羟基乙叉二膦酸四钠对碱激发矿渣复合材料的新拌及硬化性能影响, columnId=1263922770220560512, journalTitle=硅酸盐学报, columnName=研究论文, runingTitle=null, highlight=null, articleAbstract=

研究了羟基乙叉二膦酸四钠（HEDP.Na4）对碱激发矿渣复合材料（AASM）的新拌性能以及硬化性能的影响。结果表明：与空白对照组相比，掺入HEDP.Na4可延迟AASM浆体的初凝和终凝时间，最大分别延迟了43.8%和25.0%；与空白对照组相比，AASM浆体的微型坍落扩展度最大增加了20%，并且其屈服应力从57.2 Pa下降到26.6 Pa。另外，掺入HEDP.Na4的AASM基体在3 d龄期的抗压及抗弯强度均有所下降，而AASM的抗压和抗弯强度在28 d龄期分别提升了15.0%和11.6%。HEDP.Na4可降低AASM的早期水化热，细化AASM的孔径和降低基体的总孔隙率。综合可知，HEDP.Na4有效改善了AASM早期工作性能，且对后期硬化性能也有一定提升。因此，本研究可为AASM在建筑工程中的应用提供一定的指导方向。

, authors=龙武剑1, 2, 3, 张轩翰1, 2, 3, 吴卓锐1, 2, 3, 王晨宇1, 2, 3, 董必钦1, 2, 3, 韦经杰1, 3, 4, authorsList=龙武剑, 张轩翰, 吴卓锐, 王晨宇, 董必钦, 韦经杰, authorCompany=null, correspAuthors=null, authorNote=

龙武剑（1977—），男，博士，教授。

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LONG Wujian (1977-), male, Ph.D., Professor. E-mail:

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龙武剑（1977—），男，博士，教授。

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羟基乙叉二膦酸四钠对碱激发矿渣复合材料的新拌及硬化性能影响
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龙武剑 1, 2, 3 , 张轩翰 1, 2, 3 , 吴卓锐 1, 2, 3 , 王晨宇 1, 2, 3 , 董必钦 1, 2, 3 , 韦经杰 1, 3, 4
硅酸盐学报 | 研究论文 2022,50(8): 2230-2238
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硅酸盐学报 |研究论文 2022 , 50 (8) : 2230 -2238
羟基乙叉二膦酸四钠对碱激发矿渣复合材料的新拌及硬化性能影响
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龙武剑1, 2, 3 , 张轩翰1, 2, 3, 吴卓锐1, 2, 3, 王晨宇1, 2, 3, 董必钦1, 2, 3, 韦经杰1, 3, 4
作者信息
  • 1．深圳大学广东省滨海土木工程耐久性重点实验室，中国 广东 深圳 518060
  • 2．深圳大学滨海城市韧性基础设施教育部重点实验室，中国 广东 深圳 518060
  • 3．深圳大学土木与交通工程学院，中国 广东 深圳 518060
  • 4．密苏里科技大学土木建筑和环境工程学院，美国 密苏里州罗拉 65409
作者简介:

龙武剑（1977—），男，博士，教授。

Effect of Tetrasodium Hydroxyethylidene Diphosphonate on Fresh and Hardening Properties of Alkali-Activated Slag Materials
Wujian LONG1, 2, 3 , Xuanhan ZHANG1, 2, 3, Zhuorui WU1, 2, 3, Chenyu WANG1, 2, 3, Biqin DONG1, 2, 3, Jingjie WEI1, 3, 4
Affiliations
  • 1.Guangdong Provincial Key Laboratory of Durability for Marine Civil Engineering, Shenzhen 518060, Guangdong, China
  • 2.Key Lab of Coastal Urban Resilient Infrastructure, MOE, Shenzhen University, Shenzhen 518060, Guangdong, China
  • 3.College of Civil and Transportation Engineering Shenzhen University, Shenzhen 518060, Guangdong, China
  • 4.Department of Civil, Architectural, and Environmental Engineering, Missouri University of Science and Technology, Rolla, MO 65409, USA

    • LONG Wujian (1977-), male, Ph.D., Professor. E-mail:

出版时间: 2022-08-20 doi: 10.14062/j.issn.0454-5648.20210765
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研究了羟基乙叉二膦酸四钠（HEDP.Na4）对碱激发矿渣复合材料（AASM）的新拌性能以及硬化性能的影响。结果表明：与空白对照组相比，掺入HEDP.Na4可延迟AASM浆体的初凝和终凝时间，最大分别延迟了43.8%和25.0%；与空白对照组相比，AASM浆体的微型坍落扩展度最大增加了20%，并且其屈服应力从57.2 Pa下降到26.6 Pa。另外，掺入HEDP.Na4的AASM基体在3 d龄期的抗压及抗弯强度均有所下降，而AASM的抗压和抗弯强度在28 d龄期分别提升了15.0%和11.6%。HEDP.Na4可降低AASM的早期水化热，细化AASM的孔径和降低基体的总孔隙率。综合可知，HEDP.Na4有效改善了AASM早期工作性能，且对后期硬化性能也有一定提升。因此，本研究可为AASM在建筑工程中的应用提供一定的指导方向。

碱激发  /  矿渣复合材料  /  流变性能  /  力学性能  /  显微结构

The effect of tetrasodium hydroxyethylidene diphosphonate (HEDP.Na4) on the fresh and hardening properties of alkali-activated slag materials (AASM) was investigated. Compared with the control group, the initial and final setting time of AASM made with HEDP.Na4 are delayed by 43.8% and 25.0%, respectively. The mini slump of AASM with HEDP.Na4 is increased by 15% and its yield stress is decreased from 57.2 Pa to 26.6 Pa, as compared with AASM without HEDP.Na4. In addition, the compressive and flexural strengths at 3 days of AASM with HEDP.Na4 are reduced, but those at 28 days are increased by 15% and 11.6%, compared with AASM without HEDP.Na4. HEDP.Na4 can reduce the early hydration heat, modify the pore structure, and reduce the total porosity of AASM matrix. Comprehensively, HEDP.Na4 effectively improves the early working performance of AASM and the later hardening performance slightly. This research can provide a guidance for the application of AASM in construction engineering.

alkali-activated  /  slag composites  /  rheology properties  /  mechanical properties  /  microstructure
龙武剑, 张轩翰, 吴卓锐, 王晨宇, 董必钦, 韦经杰. 羟基乙叉二膦酸四钠对碱激发矿渣复合材料的新拌及硬化性能影响. 硅酸盐学报, 2022 , 50 (8) : 2230 -2238 . DOI: 10.14062/j.issn.0454-5648.20210765
Wujian LONG, Xuanhan ZHANG, Zhuorui WU, Chenyu WANG, Biqin DONG, Jingjie WEI. Effect of Tetrasodium Hydroxyethylidene Diphosphonate on Fresh and Hardening Properties of Alkali-Activated Slag Materials[J]. Journal of the Chinese Ceramic Society, 2022 , 50 (8) : 2230 -2238 . DOI: 10.14062/j.issn.0454-5648.20210765
基金
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  • 国家自然科学基金-山东联合基金(U2006223)
  • 深圳市科技计划项目(JCYJ20190808151011502)
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doi: 10.14062/j.issn.0454-5648.20210765
  • 接收时间：2021-09-02
  • 首发时间：2026-10-20
  • 出版时间：2022-08-20
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  • 收稿日期：2021-09-02
  • 修回日期：2021-09-17
基金
国家自然科学基金-山东联合基金(U2006223)
深圳市科技计划项目(JCYJ20190808151011502)
作者信息
    1．深圳大学广东省滨海土木工程耐久性重点实验室，中国 广东 深圳 518060
    2．深圳大学滨海城市韧性基础设施教育部重点实验室，中国 广东 深圳 518060
    3．深圳大学土木与交通工程学院，中国 广东 深圳 518060
    4．密苏里科技大学土木建筑和环境工程学院，美国 密苏里州罗拉 65409
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2种不同金属材料的力学参数
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Family		 属数
Number of
genus		 种数
Number of
species		 占总种数比例
Percentage of
total species (%)		 属
Genus		 种数
Number of
species		 占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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