Article(id=1319236440748314746, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319236433387303232, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20220112, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1644595200000, receivedDateStr=2022-02-12, revisedDate=1645977600000, revisedDateStr=2022-02-28, acceptedDate=null, acceptedDateStr=null, onlineDate=1792460077701, onlineDateStr=2026-10-20, pubDate=1660924800000, pubDateStr=2022-08-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792460077701, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792460077701, creator=13701087609, updateTime=1792460077701, updator=13701087609, issue=Issue{id=1319236433387303232, tenantId=1146029695717560320, journalId=1263187385517883426, year='2022', volume='50', issue='8', pageStart='2067', pageEnd='2350', issueExtLink='null', onlineDate='null', pubDate='1660924800000', pubDateStr='2022-08-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1792460075946, creator='13701087609', updateTime=1792460621958, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319238723569569958, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319236433387303232, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319238723569569959, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319236433387303232, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=2104, endPage=2109, ext={EN=ArticleExt(id=1319236440941252731, articleId=1319236440748314746, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Effect of High-Temperature Oxidation on Phase Structure and Flexural Strength of Si3N4-SiC Ceramics, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=

Si3N4-SiC ceramics were prepared via reaction sintering with SiC, silicon powder and SiO2 as main raw materials, and the ceramics were oxidized at a high temperature. The structure and properties of ceramics before and after high-temperature oxidation were investigated. The results show that the main crystalline phases of the samples before high-temperature oxidation are SiC, α-Si3N4/β-Si3N4 and a small amount of silicon powder, Si2N2O and triclinic-SiO2, while the silicon powder disappears after high-temperature oxidation and forms tetragonal-SiO2. The mass fraction of β-Si3N4 remains constant, and the mass fraction of α-Si3N4 decreases from 11.3% before high-temperature oxidation to 6.8% after high-temperature oxidation, while the mass fraction of Si2N2O and SiO2 increases, indicating that α-Si3N4 can be decomposed into Si2N2O and SiO2 more easily than β-Si3N4. After high-temperature oxidation, the flexural strength of samples decreases from (68.55±6.36) MPa to (49.80±4.96) MPa mainly due to the decomposition of α-Si3N4 into Si2N2O and SiO2.

, authors=Wei ZHOU1, Jun MA2, Xiaoqi GAO1, Huan Liu1, Zhihang SHAN1, Wanchun FENG2, 3, Boping ZHANG1, authorsList=Wei ZHOU, Jun MA, Xiaoqi GAO, Huan Liu, Zhihang SHAN, Wanchun FENG, Boping ZHANG, authorCompany=null, correspAuthors=Jun MA, Wanchun FENG, Boping ZHANG, authorNote=

ZHOU Wei (1996-), male, Master candidate. E-mail:

, correspAuthorsNote=
MA Jun (1972-), male, Vice Chief Engineer; E-mail:
FENG Wanchun (1962-), male, Senior Engineer;
ZHANG Boping (1964-), female, Professor.
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1319236441318740092, articleId=1319236440748314746, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=高温氧化对Si3N4结合SiC陶瓷相结构和抗折强度的影响, columnId=1263922770220560512, journalTitle=硅酸盐学报, columnName=研究论文, runingTitle=null, highlight=null, articleAbstract=

以SiC、硅粉、SiO2等为原料,通过反应烧结制备Si3N4-SiC陶瓷样品,并进行高温氧化,研究了高温氧化前后的结构与力学性能。结果表明:高温氧化前后样品中均存在SiC、α-Si3N4/β-Si3N4主晶相和少量单质Si、Si2N2O、方石英三斜SiO2,高温氧化后单质Si相消失,方石英四方SiO2出现。高温氧化前后β-Si3N4质量分数维持不变,而α-Si3N4质量分数由11.3%下降至6.8%,并伴随Si2N2O和SiO2质量分数的提升,表明α-Si3N4较β-Si3N4更容易氧化分解为Si2N2O和SiO2。高温氧化导致平均抗折强度由(68.55±6.36)MPa下降至(49.80±4.96)MPa,主要与氧化导致α-Si3N4质量分数下降有关。

, authors=周炜1, 马俊2, 高小琦1, 刘欢1, 单帜航1, 冯万春2, 3, 张波萍1, authorsList=周炜, 马俊, 高小琦, 刘欢, 单帜航, 冯万春, 张波萍, authorCompany=null, correspAuthors=马俊, 冯万春, 张波萍, authorNote=

周炜(1996—),男,硕士研究生。

, correspAuthorsNote=
马俊(1972—),男,副总工程师;
冯万春(1962—),男,高级工程师;
张波萍(1964—),女,教授。
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ZHOU Wei (1996-), male, Master candidate. E-mail:

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周炜(1996—),男,硕士研究生。

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周炜(1996—),男,硕士研究生。

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高温氧化对Si3N4结合SiC陶瓷相结构和抗折强度的影响
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周炜 1 , 马俊 2 , 高小琦 1 , 刘欢 1 , 单帜航 1 , 冯万春 2, 3 , 张波萍 1
硅酸盐学报 | 研究论文 2022,50(8): 2104-2109
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硅酸盐学报 |研究论文 2022 , 50 (8) : 2104 -2109
高温氧化对Si3N4结合SiC陶瓷相结构和抗折强度的影响
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周炜(1996—),男,硕士研究生。

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周炜1 , 马俊2 , 高小琦1, 刘欢1, 单帜航1, 冯万春2, 3 , 张波萍1
作者信息
  • 1.北京科技大学材料科学与工程学院,北京 100083
  • 2.葫芦岛市华能工业陶瓷有限公司,辽宁 葫芦岛 125000
  • 3.北京奥利通联科技有限公司,北京 100081
通讯作者:
马俊(1972—),男,副总工程师;
冯万春(1962—),男,高级工程师;
张波萍(1964—),女,教授。
作者简介:

周炜(1996—),男,硕士研究生。

Effect of High-Temperature Oxidation on Phase Structure and Flexural Strength of Si3N4-SiC Ceramics
Wei ZHOU1 , Jun MA2 , Xiaoqi GAO1, Huan Liu1, Zhihang SHAN1, Wanchun FENG2, 3 , Boping ZHANG1
Affiliations
  • 1.School of Material Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China
  • 2.Huludao Huaneng Industrial Ceramics Co., Ltd., Huludao 125000, Liaoning, China
  • 3.Beijing Ollie Tonglian Technology Co., Ltd., Beijing 100081, China
  • Corresponding Author:
    MA Jun (1972-), male, Vice Chief Engineer; E-mail:
    FENG Wanchun (1962-), male, Senior Engineer;
    ZHANG Boping (1964-), female, Professor.

    ZHOU Wei (1996-), male, Master candidate. E-mail:

出版时间: 2022-08-20 doi: 10.14062/j.issn.0454-5648.20220112
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以SiC、硅粉、SiO2等为原料,通过反应烧结制备Si3N4-SiC陶瓷样品,并进行高温氧化,研究了高温氧化前后的结构与力学性能。结果表明:高温氧化前后样品中均存在SiC、α-Si3N4/β-Si3N4主晶相和少量单质Si、Si2N2O、方石英三斜SiO2,高温氧化后单质Si相消失,方石英四方SiO2出现。高温氧化前后β-Si3N4质量分数维持不变,而α-Si3N4质量分数由11.3%下降至6.8%,并伴随Si2N2O和SiO2质量分数的提升,表明α-Si3N4较β-Si3N4更容易氧化分解为Si2N2O和SiO2。高温氧化导致平均抗折强度由(68.55±6.36)MPa下降至(49.80±4.96)MPa,主要与氧化导致α-Si3N4质量分数下降有关。

氮化硅  /  碳化硅  /  高温氧化  /  抗折强度

Si3N4-SiC ceramics were prepared via reaction sintering with SiC, silicon powder and SiO2 as main raw materials, and the ceramics were oxidized at a high temperature. The structure and properties of ceramics before and after high-temperature oxidation were investigated. The results show that the main crystalline phases of the samples before high-temperature oxidation are SiC, α-Si3N4/β-Si3N4 and a small amount of silicon powder, Si2N2O and triclinic-SiO2, while the silicon powder disappears after high-temperature oxidation and forms tetragonal-SiO2. The mass fraction of β-Si3N4 remains constant, and the mass fraction of α-Si3N4 decreases from 11.3% before high-temperature oxidation to 6.8% after high-temperature oxidation, while the mass fraction of Si2N2O and SiO2 increases, indicating that α-Si3N4 can be decomposed into Si2N2O and SiO2 more easily than β-Si3N4. After high-temperature oxidation, the flexural strength of samples decreases from (68.55±6.36) MPa to (49.80±4.96) MPa mainly due to the decomposition of α-Si3N4 into Si2N2O and SiO2.

silicon nitride  /  silicon carbide  /  high-temperature oxidation  /  flexural strength
周炜, 马俊, 高小琦, 刘欢, 单帜航, 冯万春, 张波萍. 高温氧化对Si3N4结合SiC陶瓷相结构和抗折强度的影响. 硅酸盐学报, 2022 , 50 (8) : 2104 -2109 . DOI: 10.14062/j.issn.0454-5648.20220112
Wei ZHOU, Jun MA, Xiaoqi GAO, Huan Liu, Zhihang SHAN, Wanchun FENG, Boping ZHANG. Effect of High-Temperature Oxidation on Phase Structure and Flexural Strength of Si3N4-SiC Ceramics[J]. Journal of the Chinese Ceramic Society, 2022 , 50 (8) : 2104 -2109 . DOI: 10.14062/j.issn.0454-5648.20220112
  • 国家自然科学基金项目(52072028)
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doi: 10.14062/j.issn.0454-5648.20220112
  • 接收时间:2022-02-12
  • 首发时间:2026-10-20
  • 出版时间:2022-08-20
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  • 收稿日期:2022-02-12
  • 修回日期:2022-02-28
基金
国家自然科学基金项目(52072028)
作者信息
    1.北京科技大学材料科学与工程学院,北京 100083
    2.葫芦岛市华能工业陶瓷有限公司,辽宁 葫芦岛 125000
    3.北京奥利通联科技有限公司,北京 100081

通讯作者:

马俊(1972—),男,副总工程师;
冯万春(1962—),男,高级工程师;
张波萍(1964—),女,教授。
参考文献
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2种不同金属材料的力学参数
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属数
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genus
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species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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