Article(id=1319232614494490652, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319232566922695375, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20210999, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1637683200000, receivedDateStr=2021-11-24, revisedDate=1640620800000, revisedDateStr=2021-12-28, acceptedDate=null, acceptedDateStr=null, onlineDate=1792459165451, onlineDateStr=2026-10-20, pubDate=1658246400000, pubDateStr=2022-07-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792459165451, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792459165451, creator=13701087609, updateTime=1792459165451, updator=13701087609, issue=Issue{id=1319232566922695375, tenantId=1146029695717560320, journalId=1263187385517883426, year='2022', volume='50', issue='7', pageStart='1775', pageEnd='2066', issueExtLink='null', onlineDate='null', pubDate='1658246400000', pubDateStr='2022-07-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1792459154109, creator='13701087609', updateTime=1792460038980, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319236278420357264, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319232566922695375, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319236278420357265, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319232566922695375, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1909, endPage=1918, ext={EN=ArticleExt(id=1319232614737760285, articleId=1319232614494490652, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Fabrication and Supercapacitor Behavior of Flexible Polyaniline/Titanium Nitride Nanowire, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=

High-conductivity titanium nitride nanowire can be used as a growth substrate of polyaniline to reduce the charge transfer resistance of the electrode material and improve the supercapacitor behavior of polyaniline. A polyaniline/titanium nitride nanowire (PANI/TiN) was synthesized as a supercapacitor electrode material via seed-assisted hydrothermal process and high-temperature calcinations with flexible carbon fiber as a substrate. PANI/TiN nanowires have a highly ordered coaxial core-shell nanowire structure, and the nanowires split each other to favor the ion diffusion and electron transportation and improve the energy storage performance. PANI/TiN exhibits a higher specific capacitance of 403 F/g at 1 A/g and a higher capacitance retention of 53.4% when the current density increases from 0.5 A/g to 10.0 A/g. The capacitance retention rate of PANI/TiN is 79.1% after 1 000 cycles of charging and discharging at 5 A/g. Compared with PANI, PANI/TiN has the improved electrochemical energy storage properties. The flexible all-solid-state symmetric supercapacitor (i.e., PANI/TiN supercapacitor) was assembled by using PANI/TiN as an electrode. PANI/TiN//PANI/TiN supercapacitor has the specific capacitance of 100.2 F/g at 1 A/g, and there is little attenuation of the specific capacitance after bending at different angles. PANI/TiN//PANI/TiN supercapacitor can obtain an energy density of 50.1 W·h/kg at a power density of 500 W/kg. Red light emitting diode (a rated voltage of 1.8 V) can be lighted up by one unit of the supercapacitor, indicating a promising potential application for energy storage.

, authors=Lu LU¹, Xiaohong ZHOU¹, Lyu XU¹, Leping YU¹, Xin ZHANG², authorsList=Lu LU, Xiaohong ZHOU, Lyu XU, Leping YU, Xin ZHANG, authorCompany=null, correspAuthors=null, authorNote=, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1319232615043944478, articleId=1319232614494490652, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=柔性聚苯胺/氮化钛纳米线电极材料的制备与储能性能, columnId=1263922770220560512, journalTitle=硅酸盐学报, columnName=研究论文, runingTitle=null, highlight=null, articleAbstract=

利用高导电性的氮化钛纳米线作为聚苯胺的生长基质，有效减少电极材料的电荷传输电阻，提升聚苯胺的超级电容储能性能。以碳纤维作为柔性基底，采用晶种辅助水热结合电化学聚合法制备了柔性聚苯胺/氮化钛纳米线电极材料（PANI/TiN），电极材料呈现高度有序的同轴核壳纳米线结构，且纳米线之间彼此分离，有利于电解液离子的传输，提升储能性能。电流密度为1 A/g时，比电容为403 F/g；电流密度从0.5 A/g增加到10.0 A/g时，比电容保持率为初始容量的53.4%，电流密度为5 A/g时，循环充放电1000次后PANI/TiN的电容保持率为79.1%，与PANI相比均有较大提升，表明PANI/TiN具有较好的电化学储能性质。以PANI/TiN电极材料为电极构建柔性全固态对称型超级电容器（PANI/TiN//PANI/TiN）考察其应用性。PANI/TiN//PANI/TiN柔性超级电容器在电流密度为1 A/g时，比电容可达100.2 F/g，且在不同角度弯曲后比电容无明显衰减。当功率密度为500 W/kg时，能量密度可达50.1 W·h/kg，且1个单元的该超级电容器可驱动红色（1.8 V）发光二极管，具有较为广阔的应用前景。

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