Article(id=1319222801265971773, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222668956643677, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20220686, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1661184000000, receivedDateStr=2022-08-23, revisedDate=1662739200000, revisedDateStr=2022-09-10, acceptedDate=null, acceptedDateStr=null, onlineDate=1792456825796, onlineDateStr=2026-10-20, pubDate=1684512000000, pubDateStr=2023-05-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792456825796, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792456825796, creator=13701087609, updateTime=1792456825796, updator=13701087609, issue=Issue{id=1319222668956643677, tenantId=1146029695717560320, journalId=1263187385517883426, year='2023', volume='51', issue='5', pageStart='1091', pageEnd='1372', issueExtLink='null', onlineDate='null', pubDate='1684512000000', pubDateStr='2023-05-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792456794251, creator='13701087609', updateTime=1792456976356, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319223432827490920, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222668956643677, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319223432827490921, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222668956643677, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1311, endPage=1322, ext={EN=ArticleExt(id=1319222801526018622, articleId=1319222801265971773, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Binding Mechanism and Capacity for AFm and C3AH6 on Premixed and Ingress Chlorides, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=

To investigate the binding capacity and mechanism of AFm and C3AH6 with Cl- ions, high purity AFm and C3AH6 were synthesized with C3A. The mineralogy and morphology of the products after reaction of AFm or C3AH6 with premixed and ingress Cl- ions, and the corresponding binding capacities were characterized. The results show that C3AH6 has a higher Cl- ions binding ability (i.e., up to 75%) with premixed Cl- ions than AFm (i.e., 17%), especially at a relatively low content of premixed Cl- ions. A reaction between Cl- ions and C3AH6 is faster than that between Cl- ions and AFm. The binding product generated by C3AH6 is Friedel's salt, while those by AFm are Hc, Kuzel's salt, Friedel's salt and AFt, which depends on Cl- ions concentration and its introduced manners, via premixed or ingress Cl- ions.

, authors=Lili SUI1, 2, Jiansheng HUANG1, Weiwen LI1, 2, Zhilv JIANG3, Chenxi SU1, Xuelei JIANG1, Yaocheng WANG1, 2, authorsList=Lili SUI, Jiansheng HUANG, Weiwen LI, Zhilv JIANG, Chenxi SU, Xuelei JIANG, Yaocheng WANG, authorCompany=null, correspAuthors=Yaocheng WANG, authorNote=

SUI Lili (1964-), female, Ph.D., Professor. E-mail:

, correspAuthorsNote=
WANG Yaocheng (1984-), male, Ph.D., Associate Professor. E-mail:
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为研究单硫型水化硫铝酸钙(AFm)和水化铝酸钙(C3AH6)的Cl-固结能力和机理,通过人工合成的方法采用C3A制备了高纯AFm与C3AH6,并研究了内掺、外渗Cl-条件下2种物质固结Cl-后的产物类型、微观形貌、Cl-固结量和固结率。结果表明:C3AH6对内掺Cl-的固结能力(最高可达75%)远高于AFm(稳定约为17%),该差异在内掺Cl-含量相对较低的情况下尤为显著;对比AFm,Cl-与C3AH6的反应更迅速且更为彻底;C3AH6的固氯产物一致为Friedel盐,AFm则根据Cl-浓度及其不同引入方式分为Hc、Kuzel盐、Friedel盐以及高硫型水化硫铝酸钙(Aft)。

, authors=隋莉莉1, 2, 黄健胜1, 李伟文1, 2, 蒋志律3, 苏晨曦1, 江雪雷1, 王耀城1, 2, authorsList=隋莉莉, 黄健胜, 李伟文, 蒋志律, 苏晨曦, 江雪雷, 王耀城, authorCompany=null, correspAuthors=王耀城, authorNote=

隋莉莉(1964—),女,博士,教授。

, correspAuthorsNote=
王耀城(1984—),男,博士,副教授。
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水化硫铝酸钙和水化铝酸钙对内掺、外渗氯离子的固结机理及能力
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隋莉莉 1, 2 , 黄健胜 1 , 李伟文 1, 2 , 蒋志律 3 , 苏晨曦 1 , 江雪雷 1 , 王耀城 1, 2
硅酸盐学报 | 研究论文 2023,51(5): 1311-1322
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硅酸盐学报 |研究论文 2023 , 51 (5) : 1311 -1322
水化硫铝酸钙和水化铝酸钙对内掺、外渗氯离子的固结机理及能力
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隋莉莉1, 2 , 黄健胜1, 李伟文1, 2, 蒋志律3, 苏晨曦1, 江雪雷1, 王耀城1, 2
作者信息
  • 1.深圳大学土木与交通工程学院,广东 深圳 518060
  • 2.广东省滨海土木工程耐久性重点实验室,广东 深圳 518060
  • 3.浙江工业大学土木工程学院,杭州 310014
通讯作者:
王耀城(1984—),男,博士,副教授。
作者简介:

隋莉莉(1964—),女,博士,教授。

Binding Mechanism and Capacity for AFm and C3AH6 on Premixed and Ingress Chlorides
Lili SUI1, 2 , Jiansheng HUANG1, Weiwen LI1, 2, Zhilv JIANG3, Chenxi SU1, Xuelei JIANG1, Yaocheng WANG1, 2
Affiliations
  • 1.College of Civil and Transportation Engineering, Shenzhen University, Shenzhen 518060, Guangdong, China
  • 2.Guangdong Provincial Key Laboratory of Durability for Marine Civil Engineering, Shenzhen 518060, Guangdong, China
  • 3.College of Civil Engineering, Zhejiang University of Technology, Hangzhou 310014, China
  • Corresponding Author:
    WANG Yaocheng (1984-), male, Ph.D., Associate Professor. E-mail:

    SUI Lili (1964-), female, Ph.D., Professor. E-mail:

出版时间: 2023-05-20 doi: 10.14062/j.issn.0454-5648.20220686
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为研究单硫型水化硫铝酸钙(AFm)和水化铝酸钙(C3AH6)的Cl-固结能力和机理,通过人工合成的方法采用C3A制备了高纯AFm与C3AH6,并研究了内掺、外渗Cl-条件下2种物质固结Cl-后的产物类型、微观形貌、Cl-固结量和固结率。结果表明:C3AH6对内掺Cl-的固结能力(最高可达75%)远高于AFm(稳定约为17%),该差异在内掺Cl-含量相对较低的情况下尤为显著;对比AFm,Cl-与C3AH6的反应更迅速且更为彻底;C3AH6的固氯产物一致为Friedel盐,AFm则根据Cl-浓度及其不同引入方式分为Hc、Kuzel盐、Friedel盐以及高硫型水化硫铝酸钙(Aft)。

单硫型水化硫铝酸钙  /  水化铝酸钙  /  氯离子  /  固结能力  /  固结机理

To investigate the binding capacity and mechanism of AFm and C3AH6 with Cl- ions, high purity AFm and C3AH6 were synthesized with C3A. The mineralogy and morphology of the products after reaction of AFm or C3AH6 with premixed and ingress Cl- ions, and the corresponding binding capacities were characterized. The results show that C3AH6 has a higher Cl- ions binding ability (i.e., up to 75%) with premixed Cl- ions than AFm (i.e., 17%), especially at a relatively low content of premixed Cl- ions. A reaction between Cl- ions and C3AH6 is faster than that between Cl- ions and AFm. The binding product generated by C3AH6 is Friedel's salt, while those by AFm are Hc, Kuzel's salt, Friedel's salt and AFt, which depends on Cl- ions concentration and its introduced manners, via premixed or ingress Cl- ions.

monosulfate calcium silicate hydrated  /  calcium aluminate hydrate  /  chlorides  /  binding capacity  /  binding mechanism
隋莉莉, 黄健胜, 李伟文, 蒋志律, 苏晨曦, 江雪雷, 王耀城. 水化硫铝酸钙和水化铝酸钙对内掺、外渗氯离子的固结机理及能力. 硅酸盐学报, 2023 , 51 (5) : 1311 -1322 . DOI: 10.14062/j.issn.0454-5648.20220686
Lili SUI, Jiansheng HUANG, Weiwen LI, Zhilv JIANG, Chenxi SU, Xuelei JIANG, Yaocheng WANG. Binding Mechanism and Capacity for AFm and C3AH6 on Premixed and Ingress Chlorides[J]. Journal of the Chinese Ceramic Society, 2023 , 51 (5) : 1311 -1322 . DOI: 10.14062/j.issn.0454-5648.20220686
  • 国家自然科学基金(51878415; 52078301)
  • 广东省自然科学基金(2019A1515012014)
  • 深圳市基础研究项目(JCYJ20170818100641730)
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2023年第51卷第5期
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doi: 10.14062/j.issn.0454-5648.20220686
  • 接收时间:2022-08-23
  • 首发时间:2026-10-20
  • 出版时间:2023-05-20
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  • 收稿日期:2022-08-23
  • 修回日期:2022-09-10
基金
国家自然科学基金(51878415; 52078301)
广东省自然科学基金(2019A1515012014)
深圳市基础研究项目(JCYJ20170818100641730)
作者信息
    1.深圳大学土木与交通工程学院,广东 深圳 518060
    2.广东省滨海土木工程耐久性重点实验室,广东 深圳 518060
    3.浙江工业大学土木工程学院,杭州 310014

通讯作者:

王耀城(1984—),男,博士,副教授。
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2种不同金属材料的力学参数
科
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属数
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genus
种数
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species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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