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Article(id=1319222771721294102, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222668956643677, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20220761, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1663171200000, receivedDateStr=2022-09-15, revisedDate=1665244800000, revisedDateStr=2022-10-09, acceptedDate=null, acceptedDateStr=null, onlineDate=1792456818752, onlineDateStr=2026-10-20, pubDate=1684512000000, pubDateStr=2023-05-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792456818752, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792456818752, creator=13701087609, updateTime=1792456818752, updator=13701087609, issue=Issue{id=1319222668956643677, tenantId=1146029695717560320, journalId=1263187385517883426, year='2023', volume='51', issue='5', pageStart='1091', pageEnd='1372', issueExtLink='null', onlineDate='null', pubDate='1684512000000', pubDateStr='2023-05-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792456794251, creator='13701087609', updateTime=1792456976356, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319223432827490920, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222668956643677, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319223432827490921, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222668956643677, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1181, endPage=1190, ext={EN=ArticleExt(id=1319222771951980823, articleId=1319222771721294102, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Composition Design and Properties of Blended Cementitious Material Based on Resistance to Chloride Ingress, columnId=1321891041012200067, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Progress on Cement-Based Materials—Research Articles, runingTitle=null, highlight=null, articleAbstract=

The chloride resistance of blended cementitious materials can be improved by incorporating a high volume of supplementary cementitious materials (SCMs), thereby improving the durability and service life of concrete structures. However, their mechanical properties decrease significantly, especially at early age. To improve the early-age mechanical properties and chloride resistance, the type and addition of cementitious materials in the fine, mid-size, and coarse fractions were optimized based on particle close-packing and pore fillability during hydration. The blended cement pastes with greater chloride binding capacity and pore tortuosity are obtained due to the pore refinement of fine particles and efficient hydration of both clinker and SCMs. In addition, a blended cementitious material with 3-day compressive strength of 27.3 MPa and 28-day chloride diffusion coefficient of 0.36×10-12 m2/s was prepared using only 59% clinker with a size range of 4-55 μm. The results provide a deeper insight in the microstructural optimization and durability improvement of cement-based materials.

, authors=Yiqun GUO1, Tongsheng ZHANG1, 2, Jiahao LI1, Zejia XING1, Ruguang LI1, Jiangxiong Wei1, 2, Qijun YU1, 2, 3, authorsList=Yiqun GUO, Tongsheng ZHANG, Jiahao LI, Zejia XING, Ruguang LI, Jiangxiong Wei, Qijun YU, authorCompany=null, correspAuthors=Tongsheng ZHANG, authorNote=

GUO Yiqun (1992-), male, Ph.D., Assistant Professor. E-mail:

, correspAuthorsNote=
ZHANG Tongsheng (1983-), male, Ph.D., Professor. E-mail:
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通常采用大量掺加辅助性胶凝材料的方式提高胶凝材料的抗Cl-渗透性能，进而提升混凝土结构的耐久性和服役寿命，但会显著降低早期力学性能。为提高早期强度和抗Cl-渗透性能，基于初始浆体密堆积与水化过程孔隙有效填充，设计细、中、粗粒度区间胶凝材料的种类和掺量，提高浆体的初始堆积密度和水化产物固氯能力，从而细化孔径并增大孔隙曲折度，采用59%的水泥熟料（粒径范围4~55 μm），成功制备了3 d抗压强度27.3 MPa、28 d Cl-扩散系数低至0.36×10-12 m2/s的高抗渗透复合胶凝材料，为水泥基材料微结构调控和抗渗性能提升奠定基础。

, authors=郭奕群1, 张同生1, 2, 李嘉豪1, 幸泽佳1, 李儒光1, 韦江雄1, 2, 余其俊1, 2, 3, authorsList=郭奕群, 张同生, 李嘉豪, 幸泽佳, 李儒光, 韦江雄, 余其俊, authorCompany=null, correspAuthors=张同生, authorNote=

郭奕群（1992—），男，博士，助理研究员。

, correspAuthorsNote=
张同生（1983—），男，博士，研究员。
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GUO Yiqun (1992-), male, Ph.D., Assistant Professor. E-mail:

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GUO Yiqun (1992-), male, Ph.D., Assistant Professor. E-mail:

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郭奕群（1992—），男，博士，助理研究员。

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郭奕群（1992—），男，博士，助理研究员。

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基于抗氯离子渗透性的复合胶凝材料组成设计与性能
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郭奕群 1 , 张同生 1, 2 , 李嘉豪 1 , 幸泽佳 1 , 李儒光 1 , 韦江雄 1, 2 , 余其俊 1, 2, 3
硅酸盐学报 | 水泥基材料研究新进展—研究论文 2023,51(5): 1181-1190
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硅酸盐学报 |水泥基材料研究新进展—研究论文 2023 , 51 (5) : 1181 -1190
基于抗氯离子渗透性的复合胶凝材料组成设计与性能
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郭奕群1 , 张同生1, 2 , 李嘉豪1, 幸泽佳1, 李儒光1, 韦江雄1, 2, 余其俊1, 2, 3
作者信息
  • 1．华南理工大学材料科学与工程学院，广州 510640
  • 2．广东省建筑材料低碳技术工程技术研究中心，广州 510640
  • 3．合肥工业大学土木与水利工程学院，合肥 230009
通讯作者:
张同生（1983—），男，博士，研究员。
作者简介:

郭奕群（1992—），男，博士，助理研究员。

Composition Design and Properties of Blended Cementitious Material Based on Resistance to Chloride Ingress
Yiqun GUO1 , Tongsheng ZHANG1, 2 , Jiahao LI1, Zejia XING1, Ruguang LI1, Jiangxiong Wei1, 2, Qijun YU1, 2, 3
Affiliations
  • 1.School of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, China
  • 2.Guangdong Low Carbon Technology Engineering Center for Building Materials, Guangzhou 510640, China
  • 3.College of Civil Engineering, Hefei University of Technology, Hefei 230009, China
    • Corresponding Author:
    ZHANG Tongsheng (1983-), male, Ph.D., Professor. E-mail:

    GUO Yiqun (1992-), male, Ph.D., Assistant Professor. E-mail:

出版时间: 2023-05-20 doi: 10.14062/j.issn.0454-5648.20220761
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通常采用大量掺加辅助性胶凝材料的方式提高胶凝材料的抗Cl-渗透性能，进而提升混凝土结构的耐久性和服役寿命，但会显著降低早期力学性能。为提高早期强度和抗Cl-渗透性能，基于初始浆体密堆积与水化过程孔隙有效填充，设计细、中、粗粒度区间胶凝材料的种类和掺量，提高浆体的初始堆积密度和水化产物固氯能力，从而细化孔径并增大孔隙曲折度，采用59%的水泥熟料（粒径范围4~55 μm），成功制备了3 d抗压强度27.3 MPa、28 d Cl-扩散系数低至0.36×10-12 m2/s的高抗渗透复合胶凝材料，为水泥基材料微结构调控和抗渗性能提升奠定基础。

抗氯离子渗透  /  复合胶凝材料  /  颗粒级配  /  水化产物  /  氯离子固化

The chloride resistance of blended cementitious materials can be improved by incorporating a high volume of supplementary cementitious materials (SCMs), thereby improving the durability and service life of concrete structures. However, their mechanical properties decrease significantly, especially at early age. To improve the early-age mechanical properties and chloride resistance, the type and addition of cementitious materials in the fine, mid-size, and coarse fractions were optimized based on particle close-packing and pore fillability during hydration. The blended cement pastes with greater chloride binding capacity and pore tortuosity are obtained due to the pore refinement of fine particles and efficient hydration of both clinker and SCMs. In addition, a blended cementitious material with 3-day compressive strength of 27.3 MPa and 28-day chloride diffusion coefficient of 0.36×10-12 m2/s was prepared using only 59% clinker with a size range of 4-55 μm. The results provide a deeper insight in the microstructural optimization and durability improvement of cement-based materials.

chloride resistance  /  blended cementitious materials  /  particle size distribution  /  hydration products  /  chloride binding
郭奕群, 张同生, 李嘉豪, 幸泽佳, 李儒光, 韦江雄, 余其俊. 基于抗氯离子渗透性的复合胶凝材料组成设计与性能. 硅酸盐学报, 2023 , 51 (5) : 1181 -1190 . DOI: 10.14062/j.issn.0454-5648.20220761
Yiqun GUO, Tongsheng ZHANG, Jiahao LI, Zejia XING, Ruguang LI, Jiangxiong Wei, Qijun YU. Composition Design and Properties of Blended Cementitious Material Based on Resistance to Chloride Ingress[J]. Journal of the Chinese Ceramic Society, 2023 , 51 (5) : 1181 -1190 . DOI: 10.14062/j.issn.0454-5648.20220761
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  • 国家重点研发计划项目(2020YFC1909903)
  • 宁夏回族自治区重点研发计划项目(2022BDE02002)
  • 国家自然科学基金(52122201)
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2023年第51卷第5期
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doi: 10.14062/j.issn.0454-5648.20220761
  • 接收时间：2022-09-15
  • 首发时间：2026-10-20
  • 出版时间：2023-05-20
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  • 收稿日期：2022-09-15
  • 修回日期：2022-10-09
基金
国家重点研发计划项目(2020YFC1909903)
宁夏回族自治区重点研发计划项目(2022BDE02002)
国家自然科学基金(52122201)
作者信息
    1．华南理工大学材料科学与工程学院，广州 510640
    2．广东省建筑材料低碳技术工程技术研究中心，广州 510640
    3．合肥工业大学土木与水利工程学院，合肥 230009

通讯作者:

张同生（1983—），男，博士，研究员。
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https://castjournals.cast.org.cn/joweb/gsyxb/CN/10.14062/j.issn.0454-5648.20220761
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2种不同金属材料的力学参数
科
Family		 属数
Number of
genus		 种数
Number of
species		 占总种数比例
Percentage of
total species (%)		 属
Genus		 种数
Number of
species		 占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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