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Article(id=1319222752628822109, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222668956643677, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20220821, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1664467200000, receivedDateStr=2022-09-30, revisedDate=1665158400000, revisedDateStr=2022-10-08, acceptedDate=null, acceptedDateStr=null, onlineDate=1792456814200, onlineDateStr=2026-10-20, pubDate=1684512000000, pubDateStr=2023-05-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792456814200, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792456814200, creator=13701087609, updateTime=1792456814200, updator=13701087609, issue=Issue{id=1319222668956643677, tenantId=1146029695717560320, journalId=1263187385517883426, year='2023', volume='51', issue='5', pageStart='1091', pageEnd='1372', issueExtLink='null', onlineDate='null', pubDate='1684512000000', pubDateStr='2023-05-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792456794251, creator='13701087609', updateTime=1792456976356, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319223432827490920, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222668956643677, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319223432827490921, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222668956643677, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1126, endPage=1135, ext={EN=ArticleExt(id=1319222752830148702, articleId=1319222752628822109, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Effect of Preferential Adsorption on Dispersing Performance of Phosphate-Containing Superplasticizer in Cement-Microcline Powder Paste, columnId=1321891041012200067, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Progress on Cement-Based Materials—Research Articles, runingTitle=null, highlight=null, articleAbstract=

The performance of polycarboxylate (PCE) superplasticizer in concrete with machine-made sand greatly depends on the adsorption behavior on stone powder, which is concerned with the lithology and specific surface area. The workability can be improved via enhancing the adsorption of PCE on stone powder. In this regard, the rheological behavior of cement paste and cement/microcline paste with conventional PCE superplasticizer and phosphate-containing PCE superplasticizer was tested. The incorporation of phosphate group can enhance the adsorption of PCE molecule on the surface of microcline, thus improving the packing density of cement/microcline mixture. The average particle separation distance increases. Therefore, the dispersing performance of PCE superplasticizer in the mixture is obviously improved. The apparent viscosity of paste is reduced. The performance of phosphate-containing superplasticizer is even better when incorporating high content of microcline.

, authors=Xin SHU1, Yonglin MAO1, Qianqian ZHANG1, Yong YANG1, Dongliang ZHOU1, Tao WANG1, Qianping RAN2, authorsList=Xin SHU, Yonglin MAO, Qianqian ZHANG, Yong YANG, Dongliang ZHOU, Tao WANG, Qianping RAN, authorCompany=null, correspAuthors=Qianping RAN, authorNote=

SHU Xin (1987-), male, Ph. D., Professor. E-mail:

, correspAuthorsNote=
RAN Qianping (1973-), male, Ph. D., Professor. E-mail:
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石粉岩性和表面积对聚羧酸减水剂吸附行为的影响是决定减水剂在机制砂混凝土中分散性能的关键因子。基于增强石粉界面减水剂吸附、改善浆体流动性的基本思路，对比研究了常规聚羧酸减水剂和引入磷酸基的减水剂对水泥-微斜长石粉浆体流变行为的影响。引入磷酸基可以提高减水剂在微斜长石粉表面的吸附，改善混合体系的堆积密实度，同时增加固体颗粒表面平均间距，提高了减水剂在水泥-微斜长石粉浆体中的分散性能，有效降低了浆体表观粘度。体系中微斜长石粉含量增加，含磷酸基减水剂相比仅含羧基的减水剂性能更优异。

, authors=舒鑫1, 毛永琳1, 张倩倩1, 杨勇1, 周栋梁1, 王涛1, 冉千平2, authorsList=舒鑫, 毛永琳, 张倩倩, 杨勇, 周栋梁, 王涛, 冉千平, authorCompany=null, correspAuthors=冉千平, authorNote=

舒鑫（1987—），男，博士，教授级高级工程师。

, correspAuthorsNote=
冉千平（1973—），男，博士，教授。
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SHU Xin (1987-), male, Ph. D., Professor. E-mail:

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舒鑫（1987—），男，博士，教授级高级工程师。

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选择性吸附对含磷酸基减水剂在水泥-微斜长石粉浆体中分散性能的影响
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舒鑫 1 , 毛永琳 1 , 张倩倩 1 , 杨勇 1 , 周栋梁 1 , 王涛 1 , 冉千平 2
硅酸盐学报 | 水泥基材料研究新进展—研究论文 2023,51(5): 1126-1135
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硅酸盐学报 |水泥基材料研究新进展—研究论文 2023 , 51 (5) : 1126 -1135
选择性吸附对含磷酸基减水剂在水泥-微斜长石粉浆体中分散性能的影响
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舒鑫（1987—），男，博士，教授级高级工程师。

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舒鑫1 , 毛永琳1, 张倩倩1, 杨勇1, 周栋梁1, 王涛1, 冉千平2
作者信息
  • 1．高性能土木工程材料国家重点实验室，江苏苏博特新材料股份有限公司，南京 211103
  • 2．东南大学材料科学与工程学院，南京 211189
通讯作者:
冉千平（1973—），男，博士，教授。
作者简介:

舒鑫（1987—），男，博士，教授级高级工程师。

Effect of Preferential Adsorption on Dispersing Performance of Phosphate-Containing Superplasticizer in Cement-Microcline Powder Paste
Xin SHU1 , Yonglin MAO1, Qianqian ZHANG1, Yong YANG1, Dongliang ZHOU1, Tao WANG1, Qianping RAN2
Affiliations
  • 1.State Key Laboratory of High-Performance Civil Engineering Materials, Jiangsu Sobute New Materials Co., Ltd., Nanjing 211103, China
  • 2.School of Materials Science and Engineering, Southeast University, Nanjing 211189, China
    • Corresponding Author:
    RAN Qianping (1973-), male, Ph. D., Professor. E-mail:

    SHU Xin (1987-), male, Ph. D., Professor. E-mail:

出版时间: 2023-05-20 doi: 10.14062/j.issn.0454-5648.20220821
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石粉岩性和表面积对聚羧酸减水剂吸附行为的影响是决定减水剂在机制砂混凝土中分散性能的关键因子。基于增强石粉界面减水剂吸附、改善浆体流动性的基本思路，对比研究了常规聚羧酸减水剂和引入磷酸基的减水剂对水泥-微斜长石粉浆体流变行为的影响。引入磷酸基可以提高减水剂在微斜长石粉表面的吸附，改善混合体系的堆积密实度，同时增加固体颗粒表面平均间距，提高了减水剂在水泥-微斜长石粉浆体中的分散性能，有效降低了浆体表观粘度。体系中微斜长石粉含量增加，含磷酸基减水剂相比仅含羧基的减水剂性能更优异。

含磷酸基减水剂  /  选择性吸附  /  微斜长石粉  /  水泥浆料  /  流变

The performance of polycarboxylate (PCE) superplasticizer in concrete with machine-made sand greatly depends on the adsorption behavior on stone powder, which is concerned with the lithology and specific surface area. The workability can be improved via enhancing the adsorption of PCE on stone powder. In this regard, the rheological behavior of cement paste and cement/microcline paste with conventional PCE superplasticizer and phosphate-containing PCE superplasticizer was tested. The incorporation of phosphate group can enhance the adsorption of PCE molecule on the surface of microcline, thus improving the packing density of cement/microcline mixture. The average particle separation distance increases. Therefore, the dispersing performance of PCE superplasticizer in the mixture is obviously improved. The apparent viscosity of paste is reduced. The performance of phosphate-containing superplasticizer is even better when incorporating high content of microcline.

preferential adsorption  /  phosphate-containing superplasticizer  /  microcline powder  /  cement paste  /  dispersing
舒鑫, 毛永琳, 张倩倩, 杨勇, 周栋梁, 王涛, 冉千平. 选择性吸附对含磷酸基减水剂在水泥-微斜长石粉浆体中分散性能的影响. 硅酸盐学报, 2023 , 51 (5) : 1126 -1135 . DOI: 10.14062/j.issn.0454-5648.20220821
Xin SHU, Yonglin MAO, Qianqian ZHANG, Yong YANG, Dongliang ZHOU, Tao WANG, Qianping RAN. Effect of Preferential Adsorption on Dispersing Performance of Phosphate-Containing Superplasticizer in Cement-Microcline Powder Paste[J]. Journal of the Chinese Ceramic Society, 2023 , 51 (5) : 1126 -1135 . DOI: 10.14062/j.issn.0454-5648.20220821
基金
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  • 国家自然科学基金(52178215)
  • 江苏省自然科学基金(BK20 201075)
  • 南京市科技计划项目(202002027)
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2023年第51卷第5期
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doi: 10.14062/j.issn.0454-5648.20220821
  • 接收时间：2022-09-30
  • 首发时间：2026-10-20
  • 出版时间：2023-05-20
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  • 收稿日期：2022-09-30
  • 修回日期：2022-10-08
基金
国家自然科学基金(52178215)
江苏省自然科学基金(BK20 201075)
南京市科技计划项目(202002027)
作者信息
    1．高性能土木工程材料国家重点实验室，江苏苏博特新材料股份有限公司，南京 211103
    2．东南大学材料科学与工程学院，南京 211189

通讯作者:

冉千平（1973—），男，博士，教授。
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https://castjournals.cast.org.cn/joweb/gsyxb/CN/10.14062/j.issn.0454-5648.20220821
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2种不同金属材料的力学参数
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Family		 属数
Number of
genus		 种数
Number of
species		 占总种数比例
Percentage of
total species (%)		 属
Genus		 种数
Number of
species		 占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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