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Article(id=1319222752146473119, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222716851405704, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20221084, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1671206400000, receivedDateStr=2022-12-17, revisedDate=1673280000000, revisedDateStr=2023-01-10, acceptedDate=null, acceptedDateStr=null, onlineDate=1792456814084, onlineDateStr=2026-10-20, pubDate=1687190400000, pubDateStr=2023-06-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792456814084, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792456814084, creator=13701087609, updateTime=1792456814084, updator=13701087609, issue=Issue{id=1319222716851405704, tenantId=1146029695717560320, journalId=1263187385517883426, year='2023', volume='51', issue='6', pageStart='1373', pageEnd='1648', issueExtLink='null', onlineDate='null', pubDate='1687190400000', pubDateStr='2023-06-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792456805669, creator='13701087609', updateTime=1792456995739, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319223514108903801, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222716851405704, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319223514108903802, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222716851405704, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1626, endPage=1639, ext={EN=ArticleExt(id=1319222752368771232, articleId=1319222752146473119, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Progress and Prospect of Energy Storage of Metal Phosphide-Rich, columnId=1263922772401635899, journalTitle=Journal of the Chinese Ceramic Society, columnName=Review, runingTitle=null, highlight=null, articleAbstract=

Phosphorus-based anode materials have a high theoretical capacity and a medium redox potential, and the related raw materials have some advantages in reserves and costs, thus having promising application prospects in sodium and lithium-ion battery anode materials. However, red phosphorus has a fast decay rate of electrochemical activity and a poor cycling performance due to the extremely low electronic conductivity and excessive volume expansion, while black phosphorus conductivity can reach 105 S/m, and its dense structure leads to a poor intrinsic rate performance, thus restricting the practical application of elemental phosphorus as an anode material. A unique metal phosphorus-rich phosphides MPx (x≥2) can be formed by introducing a small amount of metal elements into elemental phosphorus. The electronic conductivity of metal phosphorus-rich phosphides MPx can be greatly improved via metal element electron injection, and a relatively empty crystal structure can be formed to provide faster reaction kinetics and effectively inhibit volume expansion. Therefore, metal phosphorus-rich phosphides MPx with a high capacity and superior electron/ion transport characteristics is a potential sodium and lithium-ion battery anode material. This review mainly represented the composition and structural characteristics of metal phosphorus-rich phosphides, focusing on the latest progress in the energy storage mechanism and modification strategy of metal phosphorus-rich phosphides.

, authors=Wen CHEN1, Keyan HU1, Wujie DONG2, Fuqiang HUANG1, 2, authorsList=Wen CHEN, Keyan HU, Wujie DONG, Fuqiang HUANG, authorCompany=null, correspAuthors=Wujie DONG, Fuqiang HUANG, authorNote=

CHEN Wen (1999-), female, Master Candidate. E-mail:

, correspAuthorsNote=
DONG Wujie(1991-), male, Ph.D., Assistant Research Fellow. E-mail:
HUANG Fuqiang (1968-), male, Ph.D., Professor.
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磷基负极材料具有较高的理论容量和中等的氧化还原电位，且原料在储量和成本方面有极大的优势，因此其在钠、锂离子电池负极材料方面具有重要的应用前景。但红磷由于极低的电子电导率和过大的体积膨胀导致电化学活性衰减速度快，循环性能差，而黑磷导电性可达105 S/m，结构致密导致其本征倍率性能较差，两者的缺点限制了单质磷作为负极材料的实际应用。通过向单质磷中引入少量金属元素可以形成性质独特的金属富磷化物MPx（x≥2），一方面可以通过金属元素电子注入实现金属富磷化物电子导电性的跨越式提升，另一方面还可以形成较为空旷的晶体结构提供更快的反应动力学并有效地抑制体积膨胀，因此兼具高容量和优异电子/离子输运特性的金属富磷化物MPx是极具潜力的钠、锂离子电池负极材料。主要综述了金属富磷化物材料的组成结构特点，重点阐述金属富磷化物在储能机理和改性策略方面的最新进展。

, authors=陈文1, 胡克艳1, 董武杰2, 黄富强1, 2, authorsList=陈文, 胡克艳, 董武杰, 黄富强, authorCompany=null, correspAuthors=董武杰, 黄富强, authorNote=

陈文（1999—），女，硕士研究生。

, correspAuthorsNote=
董武杰（1991—），男，博士，助理研究员。
黄富强（1968—），男，博士，教授。
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金属富磷化物储能研究进展与展望
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陈文 1 , 胡克艳 1 , 董武杰 2 , 黄富强 1, 2
硅酸盐学报 | 综合评述 2023,51(6): 1626-1639
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金属富磷化物储能研究进展与展望
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陈文1 , 胡克艳1, 董武杰2 , 黄富强1, 2
作者信息
  • 1．景德镇陶瓷大学，江西 景德镇 333403
  • 2．中国科学院上海硅酸盐研究所，高性能陶瓷与超细微结构国家重点实验室，上海 200050
通讯作者:
董武杰（1991—），男，博士，助理研究员。
黄富强（1968—），男，博士，教授。
作者简介:

陈文（1999—），女，硕士研究生。

Progress and Prospect of Energy Storage of Metal Phosphide-Rich
Wen CHEN1 , Keyan HU1, Wujie DONG2 , Fuqiang HUANG1, 2
Affiliations
  • 1.School of Mechanical and Electrical Engineering, Jingdezhen Ceramic University, Jingdezhen 333403, Jiangxi, China
  • 2.State Key Laboratory of High Performance Ceramics and Superfine Microstructures, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
    • Corresponding Author:
    DONG Wujie(1991-), male, Ph.D., Assistant Research Fellow. E-mail:
    HUANG Fuqiang (1968-), male, Ph.D., Professor.

    CHEN Wen (1999-), female, Master Candidate. E-mail:

出版时间: 2023-06-20 doi: 10.14062/j.issn.0454-5648.20221084
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磷基负极材料具有较高的理论容量和中等的氧化还原电位，且原料在储量和成本方面有极大的优势，因此其在钠、锂离子电池负极材料方面具有重要的应用前景。但红磷由于极低的电子电导率和过大的体积膨胀导致电化学活性衰减速度快，循环性能差，而黑磷导电性可达105 S/m，结构致密导致其本征倍率性能较差，两者的缺点限制了单质磷作为负极材料的实际应用。通过向单质磷中引入少量金属元素可以形成性质独特的金属富磷化物MPx（x≥2），一方面可以通过金属元素电子注入实现金属富磷化物电子导电性的跨越式提升，另一方面还可以形成较为空旷的晶体结构提供更快的反应动力学并有效地抑制体积膨胀，因此兼具高容量和优异电子/离子输运特性的金属富磷化物MPx是极具潜力的钠、锂离子电池负极材料。主要综述了金属富磷化物材料的组成结构特点，重点阐述金属富磷化物在储能机理和改性策略方面的最新进展。

金属富磷化物  /  负极材料  /  锂离子电池  /  钠离子电池

Phosphorus-based anode materials have a high theoretical capacity and a medium redox potential, and the related raw materials have some advantages in reserves and costs, thus having promising application prospects in sodium and lithium-ion battery anode materials. However, red phosphorus has a fast decay rate of electrochemical activity and a poor cycling performance due to the extremely low electronic conductivity and excessive volume expansion, while black phosphorus conductivity can reach 105 S/m, and its dense structure leads to a poor intrinsic rate performance, thus restricting the practical application of elemental phosphorus as an anode material. A unique metal phosphorus-rich phosphides MPx (x≥2) can be formed by introducing a small amount of metal elements into elemental phosphorus. The electronic conductivity of metal phosphorus-rich phosphides MPx can be greatly improved via metal element electron injection, and a relatively empty crystal structure can be formed to provide faster reaction kinetics and effectively inhibit volume expansion. Therefore, metal phosphorus-rich phosphides MPx with a high capacity and superior electron/ion transport characteristics is a potential sodium and lithium-ion battery anode material. This review mainly represented the composition and structural characteristics of metal phosphorus-rich phosphides, focusing on the latest progress in the energy storage mechanism and modification strategy of metal phosphorus-rich phosphides.

metal phosphorus-rich phosphides  /  anode materials  /  lithium ion batteries  /  sodium ion batteries
陈文, 胡克艳, 董武杰, 黄富强. 金属富磷化物储能研究进展与展望. 硅酸盐学报, 2023 , 51 (6) : 1626 -1639 . DOI: 10.14062/j.issn.0454-5648.20221084
Wen CHEN, Keyan HU, Wujie DONG, Fuqiang HUANG. Progress and Prospect of Energy Storage of Metal Phosphide-Rich[J]. Journal of the Chinese Ceramic Society, 2023 , 51 (6) : 1626 -1639 . DOI: 10.14062/j.issn.0454-5648.20221084
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  • 江西省自然科学基金(GJJ211320)
  • 江西省自然科学基金(20224BAB204002)
  • 上海市自然科学基金项目(22ZR1471300)
  • 国家自然科学基金项目(52202327)
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2023年第51卷第6期
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doi: 10.14062/j.issn.0454-5648.20221084
  • 接收时间：2022-12-17
  • 首发时间：2026-10-20
  • 出版时间：2023-06-20
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  • 收稿日期：2022-12-17
  • 修回日期：2023-01-10
基金
江西省自然科学基金(GJJ211320)
江西省自然科学基金(20224BAB204002)
上海市自然科学基金项目(22ZR1471300)
国家自然科学基金项目(52202327)
作者信息
    1．景德镇陶瓷大学，江西 景德镇 333403
    2．中国科学院上海硅酸盐研究所，高性能陶瓷与超细微结构国家重点实验室，上海 200050

通讯作者:

董武杰（1991—），男，博士，助理研究员。
黄富强（1968—），男，博士，教授。
参考文献
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https://castjournals.cast.org.cn/joweb/gsyxb/CN/10.14062/j.issn.0454-5648.20221084
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2种不同金属材料的力学参数
科
Family		 属数
Number of
genus		 种数
Number of
species		 占总种数比例
Percentage of
total species (%)		 属
Genus		 种数
Number of
species		 占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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