Article(id=1319222740398224077, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222716851405704, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20220860, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1665417600000, receivedDateStr=2022-10-11, revisedDate=1667404800000, revisedDateStr=2022-11-03, acceptedDate=null, acceptedDateStr=null, onlineDate=1792456811284, onlineDateStr=2026-10-20, pubDate=1687190400000, pubDateStr=2023-06-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792456811284, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792456811284, creator=13701087609, updateTime=1792456811284, updator=13701087609, issue=Issue{id=1319222716851405704, tenantId=1146029695717560320, journalId=1263187385517883426, year='2023', volume='51', issue='6', pageStart='1373', pageEnd='1648', issueExtLink='null', onlineDate='null', pubDate='1687190400000', pubDateStr='2023-06-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792456805669, creator='13701087609', updateTime=1792456995739, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319223514108903801, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222716851405704, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319223514108903802, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222716851405704, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1555, endPage=1564, ext={EN=ArticleExt(id=1319222740599550670, articleId=1319222740398224077, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Design and Preparation of Y3Al5O12-Al4SiC4 Composite Refractory, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=

Y3Al5O12-Al4SiC4 composite refractory was prepared via pressureless sintering with Al4SiC4 as a raw material and Y2O3 as an additive. The effect of Y2O3 addition (i.e., 0-5% in mass fraction) on the phase composition, microstructure and mechanical properties of the composite was investigated, and the effect of Y3+ ions on the surface energy of Al4SiC4 different crystal faces was calculated via the DFT simulation. The results show that the addition of Y2O3 can form an eutectic liquid phase with anintrinsic oxide layer on the surface of Al4SiC4 at a high temperature, Y3Al5O12 and a small amount of Y2SiO5 appear at the grain boundary of the composite.The addition of Y2O3 promotes the growth of Al4SiC4 grains along the two-dimensional plane and the transformation from irregular to hexagonal flakes due to the reduction of surface energy of different crystal faces of Al4SiC4 by Y3+ in the additive, according to the DFT results. The flexural strength of the composite first increases and then decreases with the increase of Y2O3 addition. At theY2O3 addition of 3%, the hexagonal lamellar Al4SiC4 grains with a uniform size form a staggered skeleton structure, and Y3Al5O12 dispersesat the grain boundary of Al4SiC4, which is conducive to the improvement of the mechanical properties of Y3Al5O12-Al4SiC4 composite. The bulk density, apparent porosity and flexural strength of the composite are 2.44 g·cm-3, 20.15% and 52.7 MPa, respectively.

, authors=Xiaobing DENG1, Chengji DENG1, Guangchao XING1, Jun DING1, Zhoufu WANG1, Beiyue MA2, Hongxi ZHU1, Chao YU1, authorsList=Xiaobing DENG, Chengji DENG, Guangchao XING, Jun DING, Zhoufu WANG, Beiyue MA, Hongxi ZHU, Chao YU, authorCompany=null, correspAuthors=Chao YU, authorNote=

DENG Xiaobing (1997-), male, Master candidate. E-mail:

, correspAuthorsNote=
YU Chao (1986-), male, Ph.D., Associate Professor. E-mail:
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1319222740956066511, articleId=1319222740398224077, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=Y3Al5O12-Al4SiC4复合耐火材料的设计与制备, columnId=1263922770220560512, journalTitle=硅酸盐学报, columnName=研究论文, runingTitle=null, highlight=null, articleAbstract=

以Al4SiC4为原料、Y2O3为添加剂,采用无压烧结制备Y3Al5O12-Al4SiC4复合耐火材料,研究Y2O3添加量[0~5%(质量分数)]对复合材料物相组成、微观形貌与力学性能的影响,并通过DFT模拟计算Y3+对Al4SiC4不同晶面表面能的影响。结果表明:高温下Y2O3与Al4SiC4表面固有氧化层形成共晶液相,在复合材料晶界处生成Y3Al5O12和少量Y2SiO5。Y2O3的添加促使Al4SiC4晶粒沿二维平面生长,由不规则状向六方片状转变,这是由于添加剂中Y3+降低了晶面的表面能。复合材料的抗折强度随Y2O3添加量增加呈现先增大后降低趋势,当Y2O3添加量为3%时,尺寸均一的六方片状Al4SiC4晶粒交错生长构筑成骨架结构,Y3Al5O12弥散分布于Al4SiC4晶界处,Y3Al5O12-Al4SiC4复合材料力学性能得到提升,复合材料体积密度、显气孔率和抗折强度分别为2.44 g·cm-3、20.15%和52.7 MPa。

, authors=邓孝兵1, 邓承继1, 邢广超1, 丁军1, 王周福1, 马北越2, 祝洪喜1, 余超1, authorsList=邓孝兵, 邓承继, 邢广超, 丁军, 王周福, 马北越, 祝洪喜, 余超, authorCompany=null, correspAuthors=余超, authorNote=

邓孝兵(1997—),男,硕士研究生。

, correspAuthorsNote=
余超(1986—),男,博士,副教授。
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DENG Xiaobing (1997-), male, Master candidate. E-mail:

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Y3Al5O12-Al4SiC4复合耐火材料的设计与制备
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邓孝兵 1 , 邓承继 1 , 邢广超 1 , 丁军 1 , 王周福 1 , 马北越 2 , 祝洪喜 1 , 余超 1
硅酸盐学报 | 研究论文 2023,51(6): 1555-1564
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硅酸盐学报 |研究论文 2023 , 51 (6) : 1555 -1564
Y3Al5O12-Al4SiC4复合耐火材料的设计与制备
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邓孝兵1 , 邓承继1, 邢广超1, 丁军1, 王周福1, 马北越2, 祝洪喜1, 余超1
作者信息
  • 1.武汉科技大学,省部共建耐火材料与冶金国家重点实验室,武汉 430081
  • 2.东北大学冶金学院,沈阳 110819
通讯作者:
余超(1986—),男,博士,副教授。
作者简介:

邓孝兵(1997—),男,硕士研究生。

Design and Preparation of Y3Al5O12-Al4SiC4 Composite Refractory
Xiaobing DENG1 , Chengji DENG1, Guangchao XING1, Jun DING1, Zhoufu WANG1, Beiyue MA2, Hongxi ZHU1, Chao YU1
Affiliations
  • 1.The State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan 430081, China
  • 2.School of Metallurgy, Northeastern University, Shenyang 110819, China
  • Corresponding Author:
    YU Chao (1986-), male, Ph.D., Associate Professor. E-mail:

    DENG Xiaobing (1997-), male, Master candidate. E-mail:

出版时间: 2023-06-20 doi: 10.14062/j.issn.0454-5648.20220860
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以Al4SiC4为原料、Y2O3为添加剂,采用无压烧结制备Y3Al5O12-Al4SiC4复合耐火材料,研究Y2O3添加量[0~5%(质量分数)]对复合材料物相组成、微观形貌与力学性能的影响,并通过DFT模拟计算Y3+对Al4SiC4不同晶面表面能的影响。结果表明:高温下Y2O3与Al4SiC4表面固有氧化层形成共晶液相,在复合材料晶界处生成Y3Al5O12和少量Y2SiO5。Y2O3的添加促使Al4SiC4晶粒沿二维平面生长,由不规则状向六方片状转变,这是由于添加剂中Y3+降低了晶面的表面能。复合材料的抗折强度随Y2O3添加量增加呈现先增大后降低趋势,当Y2O3添加量为3%时,尺寸均一的六方片状Al4SiC4晶粒交错生长构筑成骨架结构,Y3Al5O12弥散分布于Al4SiC4晶界处,Y3Al5O12-Al4SiC4复合材料力学性能得到提升,复合材料体积密度、显气孔率和抗折强度分别为2.44 g·cm-3、20.15%和52.7 MPa。

碳硅化铝  /  钇铝石榴石  /  复合材料  /  耐火材料  /  力学性能

Y3Al5O12-Al4SiC4 composite refractory was prepared via pressureless sintering with Al4SiC4 as a raw material and Y2O3 as an additive. The effect of Y2O3 addition (i.e., 0-5% in mass fraction) on the phase composition, microstructure and mechanical properties of the composite was investigated, and the effect of Y3+ ions on the surface energy of Al4SiC4 different crystal faces was calculated via the DFT simulation. The results show that the addition of Y2O3 can form an eutectic liquid phase with anintrinsic oxide layer on the surface of Al4SiC4 at a high temperature, Y3Al5O12 and a small amount of Y2SiO5 appear at the grain boundary of the composite.The addition of Y2O3 promotes the growth of Al4SiC4 grains along the two-dimensional plane and the transformation from irregular to hexagonal flakes due to the reduction of surface energy of different crystal faces of Al4SiC4 by Y3+ in the additive, according to the DFT results. The flexural strength of the composite first increases and then decreases with the increase of Y2O3 addition. At theY2O3 addition of 3%, the hexagonal lamellar Al4SiC4 grains with a uniform size form a staggered skeleton structure, and Y3Al5O12 dispersesat the grain boundary of Al4SiC4, which is conducive to the improvement of the mechanical properties of Y3Al5O12-Al4SiC4 composite. The bulk density, apparent porosity and flexural strength of the composite are 2.44 g·cm-3, 20.15% and 52.7 MPa, respectively.

aluminium silicon carbide  /  yttrium aluminium garnet  /  composite  /  refectory  /  mechanical properties
邓孝兵, 邓承继, 邢广超, 丁军, 王周福, 马北越, 祝洪喜, 余超. Y3Al5O12-Al4SiC4复合耐火材料的设计与制备. 硅酸盐学报, 2023 , 51 (6) : 1555 -1564 . DOI: 10.14062/j.issn.0454-5648.20220860
Xiaobing DENG, Chengji DENG, Guangchao XING, Jun DING, Zhoufu WANG, Beiyue MA, Hongxi ZHU, Chao YU. Design and Preparation of Y3Al5O12-Al4SiC4 Composite Refractory[J]. Journal of the Chinese Ceramic Society, 2023 , 51 (6) : 1555 -1564 . DOI: 10.14062/j.issn.0454-5648.20220860
  • 国家自然科学基金(U21A2057)
  • 湖北省重点研发计划项目(2022BAA032)
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2023年第51卷第6期
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doi: 10.14062/j.issn.0454-5648.20220860
  • 接收时间:2022-10-11
  • 首发时间:2026-10-20
  • 出版时间:2023-06-20
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  • 收稿日期:2022-10-11
  • 修回日期:2022-11-03
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国家自然科学基金(U21A2057)
湖北省重点研发计划项目(2022BAA032)
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    1.武汉科技大学,省部共建耐火材料与冶金国家重点实验室,武汉 430081
    2.东北大学冶金学院,沈阳 110819

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余超(1986—),男,博士,副教授。
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2种不同金属材料的力学参数
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鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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