Article(id=1319222730260599773, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222668956643677, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20220751, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1662998400000, receivedDateStr=2022-09-13, revisedDate=1664985600000, revisedDateStr=2022-10-06, acceptedDate=null, acceptedDateStr=null, onlineDate=1792456808867, onlineDateStr=2026-10-20, pubDate=1684512000000, pubDateStr=2023-05-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792456808867, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792456808867, creator=13701087609, updateTime=1792456808867, updator=13701087609, issue=Issue{id=1319222668956643677, tenantId=1146029695717560320, journalId=1263187385517883426, year='2023', volume='51', issue='5', pageStart='1091', pageEnd='1372', issueExtLink='null', onlineDate='null', pubDate='1684512000000', pubDateStr='2023-05-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792456794251, creator='13701087609', updateTime=1792456976356, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319223432827490920, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222668956643677, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319223432827490921, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222668956643677, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1093, endPage=1103, ext={EN=ArticleExt(id=1319222731112043486, articleId=1319222730260599773, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Effects of in-situ Polymerization on Mechanical Properties of 3D Printing Mortars and Its Mechanism, columnId=1321891041012200067, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Progress on Cement-Based Materials—Research Articles, runingTitle=null, highlight=null, articleAbstract=

Acrylamide was selected as a monomer to generate polyacrylamide network in 3D printing mortars via in-situ polymerization, and the effect of in-situ polymerization on the mechanical properties of 3D printing mortars was investigated. The influence mechanism was analyzed by Fourier transform infrared spectroscopy, scanning electron microscopy, mercury intrusion porosimetry, and X-ray computed tomography. The results show that the in-situ polymerization of AM can enhance the fluidity of 3D printing mortars, reduce the generation of macroscopic defects, and improve the printing quality. After AM monomers are polymerized, a "rigid-flexible" composite network structure is formed, in which the organic network and the cement hydration products are intertwined. This structure greatly enhances the flexural strength and relative bonding strength of the 3D printed specimen. The 28 d flexural strength and the relative interfacial bonding strength can be increased by 52.4% and 78.1%, respectively.

, authors=Pan FENG1, Zhaolong LIU1, Lijing SHAO1, Wei WANG2, 3, Jinxiang HONG2, 3, Changwen MIAO1, 2, authorsList=Pan FENG, Zhaolong LIU, Lijing SHAO, Wei WANG, Jinxiang HONG, Changwen MIAO, authorCompany=null, correspAuthors=Changwen MIAO, authorNote=

FENG Pan (1988-), female, Ph.D., Professor. E-mail:

, correspAuthorsNote=
MIAO Changwen (1957-), male, Ph.D., Professor. E-mail:
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为了实现3D打印砂浆力学性能的提升,选用丙烯酰胺为单体,以原位聚合的方式在3D打印砂浆中生成聚丙烯酰胺网络,探究原位聚合对3D打印砂浆力学性能的影响,并通过Fourier变换红外光谱、扫描电子显微镜、压汞仪测试和X射线计算机断层成像等手段对其影响机理进行探究。结果表明:AM原位聚合体系可以提高3D打印砂浆的流动性,减少宏观缺陷的产生,提高打印质量。AM单体聚合后会形成有机网络与水泥水化产物相互交错连接形成的“刚-柔”复合网络结构。这种结构极大的增强了3D打印试件的抗折强度和界面粘接强度,最高可使其28 d抗折强度提高52.4%,28 d相对界面粘接强度提高78.1%。

, authors=冯攀1, 刘钊龙1, 邵丽静1, 王伟2, 3, 洪锦祥2, 3, 缪昌文1, 2, authorsList=冯攀, 刘钊龙, 邵丽静, 王伟, 洪锦祥, 缪昌文, authorCompany=null, correspAuthors=缪昌文, authorNote=

冯攀(1988—),女,博士,教授。

, correspAuthorsNote=
缪昌文(1957—),男,博士,教授。
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原位聚合对3D打印砂浆力学性能的影响及机理
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冯攀 1 , 刘钊龙 1 , 邵丽静 1 , 王伟 2, 3 , 洪锦祥 2, 3 , 缪昌文 1, 2
硅酸盐学报 | 水泥基材料研究新进展—研究论文 2023,51(5): 1093-1103
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硅酸盐学报 |水泥基材料研究新进展—研究论文 2023 , 51 (5) : 1093 -1103
原位聚合对3D打印砂浆力学性能的影响及机理
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冯攀(1988—),女,博士,教授。

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冯攀1 , 刘钊龙1, 邵丽静1, 王伟2, 3, 洪锦祥2, 3, 缪昌文1, 2
作者信息
  • 1.东南大学材料科学与工程学院,江苏省土木工程材料重点实验室,南京 211189
  • 2.高性能土木工程材料国家重点实验室,南京 210008
  • 3.江苏苏博特新材料股份有限公司,南京 211103
通讯作者:
缪昌文(1957—),男,博士,教授。
作者简介:

冯攀(1988—),女,博士,教授。

Effects of in-situ Polymerization on Mechanical Properties of 3D Printing Mortars and Its Mechanism
Pan FENG1 , Zhaolong LIU1, Lijing SHAO1, Wei WANG2, 3, Jinxiang HONG2, 3, Changwen MIAO1, 2
Affiliations
  • 1.School of Materials Science and Engineering, Southeast University, Jiangsu Key Laboratory of Construction Materials, Nanjing 211189, China
  • 2.State Key Laboratory of High Performance Civil Engineering Materials, Nanjing 210008, China
  • 3.Jiangsu Sobute New Materials Co., Ltd., Nanjing 211103, China
  • Corresponding Author:
    MIAO Changwen (1957-), male, Ph.D., Professor. E-mail:

    FENG Pan (1988-), female, Ph.D., Professor. E-mail:

出版时间: 2023-05-20 doi: 10.14062/j.issn.0454-5648.20220751
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为了实现3D打印砂浆力学性能的提升,选用丙烯酰胺为单体,以原位聚合的方式在3D打印砂浆中生成聚丙烯酰胺网络,探究原位聚合对3D打印砂浆力学性能的影响,并通过Fourier变换红外光谱、扫描电子显微镜、压汞仪测试和X射线计算机断层成像等手段对其影响机理进行探究。结果表明:AM原位聚合体系可以提高3D打印砂浆的流动性,减少宏观缺陷的产生,提高打印质量。AM单体聚合后会形成有机网络与水泥水化产物相互交错连接形成的“刚-柔”复合网络结构。这种结构极大的增强了3D打印试件的抗折强度和界面粘接强度,最高可使其28 d抗折强度提高52.4%,28 d相对界面粘接强度提高78.1%。

3D打印砂浆  /  原位聚合  /  丙烯酰胺  /  力学性能

Acrylamide was selected as a monomer to generate polyacrylamide network in 3D printing mortars via in-situ polymerization, and the effect of in-situ polymerization on the mechanical properties of 3D printing mortars was investigated. The influence mechanism was analyzed by Fourier transform infrared spectroscopy, scanning electron microscopy, mercury intrusion porosimetry, and X-ray computed tomography. The results show that the in-situ polymerization of AM can enhance the fluidity of 3D printing mortars, reduce the generation of macroscopic defects, and improve the printing quality. After AM monomers are polymerized, a "rigid-flexible" composite network structure is formed, in which the organic network and the cement hydration products are intertwined. This structure greatly enhances the flexural strength and relative bonding strength of the 3D printed specimen. The 28 d flexural strength and the relative interfacial bonding strength can be increased by 52.4% and 78.1%, respectively.

3D printing mortar  /  in-situ polymerization  /  acrylamide  /  mechanical properties
冯攀, 刘钊龙, 邵丽静, 王伟, 洪锦祥, 缪昌文. 原位聚合对3D打印砂浆力学性能的影响及机理. 硅酸盐学报, 2023 , 51 (5) : 1093 -1103 . DOI: 10.14062/j.issn.0454-5648.20220751
Pan FENG, Zhaolong LIU, Lijing SHAO, Wei WANG, Jinxiang HONG, Changwen MIAO. Effects of in-situ Polymerization on Mechanical Properties of 3D Printing Mortars and Its Mechanism[J]. Journal of the Chinese Ceramic Society, 2023 , 51 (5) : 1093 -1103 . DOI: 10.14062/j.issn.0454-5648.20220751
  • 国家自然科学基金(51890904; 52122802; 52078126)
  • 江苏省创新支撑计划(BZ2022036)
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2023年第51卷第5期
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doi: 10.14062/j.issn.0454-5648.20220751
  • 接收时间:2022-09-13
  • 首发时间:2026-10-20
  • 出版时间:2023-05-20
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  • 收稿日期:2022-09-13
  • 修回日期:2022-10-06
基金
国家自然科学基金(51890904; 52122802; 52078126)
江苏省创新支撑计划(BZ2022036)
作者信息
    1.东南大学材料科学与工程学院,江苏省土木工程材料重点实验室,南京 211189
    2.高性能土木工程材料国家重点实验室,南京 210008
    3.江苏苏博特新材料股份有限公司,南京 211103

通讯作者:

缪昌文(1957—),男,博士,教授。
参考文献
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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