Article(id=1319222727496544851, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222716851405704, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20230077, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1676563200000, receivedDateStr=2023-02-17, revisedDate=1677859200000, revisedDateStr=2023-03-04, acceptedDate=null, acceptedDateStr=null, onlineDate=1792456808208, onlineDateStr=2026-10-20, pubDate=1687190400000, pubDateStr=2023-06-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792456808208, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792456808208, creator=13701087609, updateTime=1792456808208, updator=13701087609, issue=Issue{id=1319222716851405704, tenantId=1146029695717560320, journalId=1263187385517883426, year='2023', volume='51', issue='6', pageStart='1373', pageEnd='1648', issueExtLink='null', onlineDate='null', pubDate='1687190400000', pubDateStr='2023-06-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792456805669, creator='13701087609', updateTime=1792456995739, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319223514108903801, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222716851405704, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319223514108903802, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222716851405704, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1510, endPage=1518, ext={EN=ArticleExt(id=1319222727702065748, articleId=1319222727496544851, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Effect of B-Site Doping on Mechanical Properties of BaCeO3-δ Proton Conducting Electrolyte, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=

The electrolyte of the proton conducting solid oxide fuel cell is the key component affecting both the performance and the stability. In this study, B-site cation-doped BaCe0.9M0.1O3-δ (BCM, M=Sc, Y, Zr, Nb) proton conducting ceramics are prepared via solid-state reaction approach. The effect of B-site doping on its sintering characteristics and mechanical properties are examined by material characterization and nanoindentation test. The results show that trivalent ion doping can promote the particle growth during sintering, while high-valent ion doping can inhibit the particle growth. In terms of mechanical properties, the Young's modulus of the doped BCM decreases with the increase of the ionic radius of the trivalent doping elements (Sc and Y), and decreases with the increase of the valence state of the different valent doping elements (Y, Zr, and Nb).

, authors=Yi RU, Jianli ZHOU, Jin KE, Jinjie GUO, Jin ZHANG, Zehua PAN, Zheng ZHONG, authorsList=Yi RU, Jianli ZHOU, Jin KE, Jinjie GUO, Jin ZHANG, Zehua PAN, Zheng ZHONG, authorCompany=null, correspAuthors=Zehua PAN, authorNote=

RU Yi (1998-), female, Master candidate. E-mail:

, correspAuthorsNote=
PAN Zehua (1990-), male, Ph.D., Lecturer. E-mail:
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1319222729644028501, articleId=1319222727496544851, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=B位掺杂对BaCeO3-δ基质子导体陶瓷力学特性的影响, columnId=1263922770220560512, journalTitle=硅酸盐学报, columnName=研究论文, runingTitle=null, highlight=null, articleAbstract=

质子导体固体氧化物燃料电池中的电解质是影响其性能和稳定性的关键。通过固相反应法制备了B位阳离子掺杂的BaCe0.9M0.1O3-δ(BCM,M=Sc、Y、Zr、Nb)质子导体陶瓷,通过材料表征和纳米压痕测试探究了B位掺杂对烧结特性和力学特性的影响规律。结果表明,三价离子掺杂会促进BCM烧结过程中颗粒的生长而高价离子掺杂则会抑制颗粒生长。在力学特性上,掺杂后的BCM的弹性模量随着同稳定价态掺杂元素(Sc和Y)的离子半径的增大而减小,随着不同稳定价态掺杂元素(Y、Zr和Nb)的价态的增加而减小。

, authors=茹意, 周建力, 柯金, 郭瑾洁, 张进, 潘泽华, 仲政, authorsList=茹意, 周建力, 柯金, 郭瑾洁, 张进, 潘泽华, 仲政, authorCompany=null, correspAuthors=潘泽华, authorNote=

茹意(1998—),女,硕士研究生。

, correspAuthorsNote=
潘泽华(1990—),男,博士,讲师。
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茹意(1998—),女,硕士研究生。

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B位掺杂对BaCeO3-δ基质子导体陶瓷力学特性的影响
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茹意 , 周建力 , 柯金 , 郭瑾洁 , 张进 , 潘泽华 , 仲政
硅酸盐学报 | 研究论文 2023,51(6): 1510-1518
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硅酸盐学报 |研究论文 2023 , 51 (6) : 1510 -1518
B位掺杂对BaCeO3-δ基质子导体陶瓷力学特性的影响
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茹意 , 周建力, 柯金, 郭瑾洁, 张进, 潘泽华 , 仲政
作者信息
  • 哈尔滨工业大学(深圳)理学院,广东 深圳 518055
通讯作者:
潘泽华(1990—),男,博士,讲师。
作者简介:

茹意(1998—),女,硕士研究生。

Effect of B-Site Doping on Mechanical Properties of BaCeO3-δ Proton Conducting Electrolyte
Yi RU , Jianli ZHOU, Jin KE, Jinjie GUO, Jin ZHANG, Zehua PAN , Zheng ZHONG
Affiliations
  • College of Science, Harbin Institute of Technology, Shenzhen 518055, Guangdong, China
  • Corresponding Author:
    PAN Zehua (1990-), male, Ph.D., Lecturer. E-mail:

    RU Yi (1998-), female, Master candidate. E-mail:

出版时间: 2023-06-20 doi: 10.14062/j.issn.0454-5648.20230077
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质子导体固体氧化物燃料电池中的电解质是影响其性能和稳定性的关键。通过固相反应法制备了B位阳离子掺杂的BaCe0.9M0.1O3-δ(BCM,M=Sc、Y、Zr、Nb)质子导体陶瓷,通过材料表征和纳米压痕测试探究了B位掺杂对烧结特性和力学特性的影响规律。结果表明,三价离子掺杂会促进BCM烧结过程中颗粒的生长而高价离子掺杂则会抑制颗粒生长。在力学特性上,掺杂后的BCM的弹性模量随着同稳定价态掺杂元素(Sc和Y)的离子半径的增大而减小,随着不同稳定价态掺杂元素(Y、Zr和Nb)的价态的增加而减小。

固体氧化物燃料电池  /  质子导体电解质  /  力学特性  /  烧结特性  /  铈酸钡

The electrolyte of the proton conducting solid oxide fuel cell is the key component affecting both the performance and the stability. In this study, B-site cation-doped BaCe0.9M0.1O3-δ (BCM, M=Sc, Y, Zr, Nb) proton conducting ceramics are prepared via solid-state reaction approach. The effect of B-site doping on its sintering characteristics and mechanical properties are examined by material characterization and nanoindentation test. The results show that trivalent ion doping can promote the particle growth during sintering, while high-valent ion doping can inhibit the particle growth. In terms of mechanical properties, the Young's modulus of the doped BCM decreases with the increase of the ionic radius of the trivalent doping elements (Sc and Y), and decreases with the increase of the valence state of the different valent doping elements (Y, Zr, and Nb).

solid oxide fuel cell  /  proton conducting electrolyte  /  mechanical properties  /  sintering characteristic  /  barium ceriate
茹意, 周建力, 柯金, 郭瑾洁, 张进, 潘泽华, 仲政. B位掺杂对BaCeO3-δ基质子导体陶瓷力学特性的影响. 硅酸盐学报, 2023 , 51 (6) : 1510 -1518 . DOI: 10.14062/j.issn.0454-5648.20230077
Yi RU, Jianli ZHOU, Jin KE, Jinjie GUO, Jin ZHANG, Zehua PAN, Zheng ZHONG. Effect of B-Site Doping on Mechanical Properties of BaCeO3-δ Proton Conducting Electrolyte[J]. Journal of the Chinese Ceramic Society, 2023 , 51 (6) : 1510 -1518 . DOI: 10.14062/j.issn.0454-5648.20230077
  • 国家自然科学基金(52102226; 11932005)
  • 广东省自然科学基金(2023A1515010723)
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2023年第51卷第6期
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doi: 10.14062/j.issn.0454-5648.20230077
  • 接收时间:2023-02-17
  • 首发时间:2026-10-20
  • 出版时间:2023-06-20
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  • 收稿日期:2023-02-17
  • 修回日期:2023-03-04
基金
国家自然科学基金(52102226; 11932005)
广东省自然科学基金(2023A1515010723)
作者信息
    哈尔滨工业大学(深圳)理学院,广东 深圳 518055

通讯作者:

潘泽华(1990—),男,博士,讲师。
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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