Article(id=1319222704570487639, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222618356559896, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20221073, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1670774400000, receivedDateStr=2022-12-12, revisedDate=1672070400000, revisedDateStr=2022-12-27, acceptedDate=null, acceptedDateStr=null, onlineDate=1792456802742, onlineDateStr=2026-10-20, pubDate=1681920000000, pubDateStr=2023-04-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792456802742, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792456802742, creator=13701087609, updateTime=1792456802742, updator=13701087609, issue=Issue{id=1319222618356559896, tenantId=1146029695717560320, journalId=1263187385517883426, year='2023', volume='51', issue='4', pageStart='831', pageEnd='1090', issueExtLink='null', onlineDate='null', pubDate='1681920000000', pubDateStr='2023-04-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792456782187, creator='13701087609', updateTime=1792456947953, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319223313692472320, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222618356559896, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319223313692472321, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222618356559896, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1000, endPage=1006, ext={EN=ArticleExt(id=1319222704838923096, articleId=1319222704570487639, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=
In-situ Hydrothermal Growth of Dense Ceria Based Barrier Layer for Solid Oxide Fuel Cells, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=
A novel fabrication method of dense ceria-based barrier layer was proposed to fulfil the low-cost fabrication and long-term operation of solid oxide fuel cell (SOFC). A Y2O3 stabilized ZrO2 (YSZ) electrolyte of anode supported half-cell was immersed in a solution of gadolinium nitrate and cerium nitrate, and treated at 180 ℃ for 36 h, then yielding a dense Gd2O3 doped CeO2 (GDC) thin film. The GDC thin film was co-sintered with screen printed La0.6Sr0.4Co0.2Fe0.8O3-δ cathode at 1075 ℃, thus obtaining an anode supported single cell. The results show that the hydrothermal grown GDC barrier layer is continuous and dense, with a chemical composition of Gd0.044Ce0.956O2-δ and a thickness of 0.23 μm. The Ohmic resistance of anode supported a single cell at 750 ℃ is 0.101 Ω·cm2, which is 38% lower than that of the cell with a conventional screen printed GDC barrier layer. The maximum power density using a wet hydrogen fuel reaches 1.038 W/cm2 with a decent long-term operation durability. This hydrothermal in-situ growth method can satisfy the low-cost and large-scale fabrication of dense and thin-film barrier layers for SOFC with multi-configurations and dimensions, showing a promising application prospect.
, authors=Haoyu ZHAO, Qiuqiu LYU, Liya CHENG, Shenglong WU, Tenglong ZHU, Qin ZHONG, authorsList=Haoyu ZHAO, Qiuqiu LYU, Liya CHENG, Shenglong WU, Tenglong ZHU, Qin ZHONG, authorCompany=null, correspAuthors=Tenglong ZHU, authorNote=
, correspAuthorsNote=
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面向高性能固体氧化物燃料电池(SOFC)低成本制备及长寿命运行需求,提出了一种致密氧化铈基隔离层的制备方法。将阳极支撑半电池的Y2O3稳定ZrO2(YSZ)电解质浸没于硝酸钆和硝酸铈水溶液中,并在180 ℃水热条件下处理36 h,获得了原位生长的致密Gd2O3掺杂CeO2(GDC)薄膜;进一步将其与La0.6Sr0.4Co0.2Fe0.8O3-δ阴极在1075 ℃共烧结,得到阳极支撑SOFC单电池。结果表明,水热原位生长制备的GDC隔离层连续且致密,组成约为Gd0.044Ce0.956O2-δ,厚度约为0.23 μm;阳极支撑单电池在750 ℃的欧姆阻抗约为0.101 Ω·cm2,相较于传统丝网印刷GDC隔离层单电池降低了约38%,在室温加湿氢气燃料下的最大功率密度达到了约1.038 W/cm2,表现出较好的长期运行稳定性。报道的水热原位生长法能满足多构型、多尺寸SOFC致密隔离层薄膜的低成本规模化制备,具有工业应用前景。
, authors=赵浩宇, 吕秋秋, 程丽亚, 吴升龙, 朱腾龙, 钟秦, authorsList=赵浩宇, 吕秋秋, 程丽亚, 吴升龙, 朱腾龙, 钟秦, authorCompany=null, correspAuthors=朱腾龙, authorNote=
, correspAuthorsNote=
朱腾龙(1988—),男,博士,副教授。
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ZHAO Haoyu (2000-), female, Master candidate. E-mail: zhaohaoyu@njust.edu.cn
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赵浩宇(2000—),女,硕士研究生。
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赵浩宇(2000—),女,硕士研究生。
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