Article(id=1319222664653296111, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222618356559896, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20220700, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1661616000000, receivedDateStr=2022-08-28, revisedDate=1663776000000, revisedDateStr=2022-09-22, acceptedDate=null, acceptedDateStr=null, onlineDate=1792456793224, onlineDateStr=2026-10-20, pubDate=1681920000000, pubDateStr=2023-04-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792456793224, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792456793224, creator=13701087609, updateTime=1792456793224, updator=13701087609, issue=Issue{id=1319222618356559896, tenantId=1146029695717560320, journalId=1263187385517883426, year='2023', volume='51', issue='4', pageStart='831', pageEnd='1090', issueExtLink='null', onlineDate='null', pubDate='1681920000000', pubDateStr='2023-04-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792456782187, creator='13701087609', updateTime=1792456947953, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319223313692472320, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222618356559896, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319223313692472321, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222618356559896, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=907, endPage=920, ext={EN=ArticleExt(id=1319222664854622704, articleId=1319222664653296111, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Recent Development on Ultra-Low Firing Technologies of Microwave Dielectric Ceramics, columnId=1321891294297829430, journalTitle=Journal of the Chinese Ceramic Society, columnName=Special Issue on 5G/6G Materials—Review, runingTitle=null, highlight=null, articleAbstract=

Microwave dielectric ceramics prepared via a conventional method usually require a high sintering temperature (i.e., >1 000 ℃) and long sintering time, leading to a high energy consumption and a difficulty to realize the integration and co-firing of multiple material system. Continuous innovation and development of wireless communication technology put forward higher requirements for the miniaturization and integration of microwave devices, so that some technologies for preparing low-temperature co-fired ceramic (LTCC) and ultralow-temperature co-fired ceramic (ULTCC) are developed. Developing green sintering technologies with lower sintering temperatures and higher sintering efficiencies becomes one of the research hotspots. Novel sintering technologies (i.e., liquid-phase sintering, hot press sintering, microwave sintering, spark plasma sintering, and flash sintering) promote the development of microwave dielectric ceramics. A novel ultra-low temperature sintering technology called cold sintering process is proposed. The sintering temperature of cold sintering process is rather low (≤300 ℃), which can densify ceramics in a short time, and has some advantages in the phase stability, co-firing of multiple materials and grain boundary manipulation, thus providing an opportunity for the development of ultra-low temperature sintering technology and microwave dielectric material system.

, authors=Xiaomeng LI1, Xian XUE1, Hong WANG1, 2, Jing GUO1, authorsList=Xiaomeng LI, Xian XUE, Hong WANG, Jing GUO, authorCompany=null, correspAuthors=Jing GUO, authorNote=

LI Xiaomeng (1999-), female, Doctoral candidate. E-mail:

, correspAuthorsNote=
GUO Jing (1986-), male, Ph.D., Associate Professor. E-mail:
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传统方法制备微波介质陶瓷通常需要1000 ℃以上高温,不仅工艺周期长、能量消耗高,而且难以实现多种材料体系的集成共烧。如今,无线通讯技术的不断革新和蓬勃发展对微波器件小型化、集成化提出了更高要求,低温共烧陶瓷/超低温共烧陶瓷技术被开发和广泛应用。研究烧结温度更低、烧结效率更高,且微波介电性能优异的节能环保型绿色制备工艺,已经成为全球范围内研究热点之一。液相烧结、热压烧结、微波烧结、放电等离子体烧结、闪烧等烧结工艺的提出促进了低温烧结微波介质陶瓷的发展。最近,又出现了一种新的超低温烧结工艺—冷烧结技术。冷烧结具有极低的烧结温度(一般≤300 ℃)、可在短时间内实现陶瓷高致密化,且在物相稳定性、复合共烧以及晶界控制等方面有着优势,为超低温烧结工艺以及微波介质材料体系的开发提供了新的契机。

, authors=李晓萌1, 薛仙1, 汪宏1, 2, 郭靖1, authorsList=李晓萌, 薛仙, 汪宏, 郭靖, authorCompany=null, correspAuthors=郭靖, authorNote=

李晓萌(1999—),女,博士。

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郭靖(1986—),男,博士,副教授。
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超低温烧结微波介质陶瓷制备工艺的研究进展
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李晓萌 1 , 薛仙 1 , 汪宏 1, 2 , 郭靖 1
硅酸盐学报 | 5G/6G材料专题—综合评述 2023,51(4): 907-920
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硅酸盐学报 |5G/6G材料专题—综合评述 2023 , 51 (4) : 907 -920
超低温烧结微波介质陶瓷制备工艺的研究进展
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李晓萌1 , 薛仙1, 汪宏1, 2, 郭靖1
作者信息
  • 1.西安交通大学材料科学与工程学院,金属材料强度国家重点实验室,西安 710049
  • 2.南方科技大学材料科学与工程系,广东 深圳 518055
通讯作者:
郭靖(1986—),男,博士,副教授。
作者简介:

李晓萌(1999—),女,博士。

Recent Development on Ultra-Low Firing Technologies of Microwave Dielectric Ceramics
Xiaomeng LI1 , Xian XUE1, Hong WANG1, 2, Jing GUO1
Affiliations
  • 1.State Key Laboratory for Mechanical Behavior of Materials, School of Materials Science and Engineering, Xi'an Jiaotong University, Xi'an 710049, China
  • 2.Department of Materials Science and Engineering, Southern University of Science and Technology, Shenzhen 518055, Guangdong, China
  • Corresponding Author:
    GUO Jing (1986-), male, Ph.D., Associate Professor. E-mail:

    LI Xiaomeng (1999-), female, Doctoral candidate. E-mail:

出版时间: 2023-04-20 doi: 10.14062/j.issn.0454-5648.20220700
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传统方法制备微波介质陶瓷通常需要1000 ℃以上高温,不仅工艺周期长、能量消耗高,而且难以实现多种材料体系的集成共烧。如今,无线通讯技术的不断革新和蓬勃发展对微波器件小型化、集成化提出了更高要求,低温共烧陶瓷/超低温共烧陶瓷技术被开发和广泛应用。研究烧结温度更低、烧结效率更高,且微波介电性能优异的节能环保型绿色制备工艺,已经成为全球范围内研究热点之一。液相烧结、热压烧结、微波烧结、放电等离子体烧结、闪烧等烧结工艺的提出促进了低温烧结微波介质陶瓷的发展。最近,又出现了一种新的超低温烧结工艺—冷烧结技术。冷烧结具有极低的烧结温度(一般≤300 ℃)、可在短时间内实现陶瓷高致密化,且在物相稳定性、复合共烧以及晶界控制等方面有着优势,为超低温烧结工艺以及微波介质材料体系的开发提供了新的契机。

微波介质  /  陶瓷  /  低温共烧陶瓷  /  超低温共烧陶瓷  /  超低温烧结工艺  /  冷烧结

Microwave dielectric ceramics prepared via a conventional method usually require a high sintering temperature (i.e., >1 000 ℃) and long sintering time, leading to a high energy consumption and a difficulty to realize the integration and co-firing of multiple material system. Continuous innovation and development of wireless communication technology put forward higher requirements for the miniaturization and integration of microwave devices, so that some technologies for preparing low-temperature co-fired ceramic (LTCC) and ultralow-temperature co-fired ceramic (ULTCC) are developed. Developing green sintering technologies with lower sintering temperatures and higher sintering efficiencies becomes one of the research hotspots. Novel sintering technologies (i.e., liquid-phase sintering, hot press sintering, microwave sintering, spark plasma sintering, and flash sintering) promote the development of microwave dielectric ceramics. A novel ultra-low temperature sintering technology called cold sintering process is proposed. The sintering temperature of cold sintering process is rather low (≤300 ℃), which can densify ceramics in a short time, and has some advantages in the phase stability, co-firing of multiple materials and grain boundary manipulation, thus providing an opportunity for the development of ultra-low temperature sintering technology and microwave dielectric material system.

microwave dielectric  /  ceramic  /  low temperature co-fired ceramic  /  ultra-low temperature co-fired ceramic  /  ultra-low sintering temperature technology  /  cold sintering process
李晓萌, 薛仙, 汪宏, 郭靖. 超低温烧结微波介质陶瓷制备工艺的研究进展. 硅酸盐学报, 2023 , 51 (4) : 907 -920 . DOI: 10.14062/j.issn.0454-5648.20220700
Xiaomeng LI, Xian XUE, Hong WANG, Jing GUO. Recent Development on Ultra-Low Firing Technologies of Microwave Dielectric Ceramics[J]. Journal of the Chinese Ceramic Society, 2023 , 51 (4) : 907 -920 . DOI: 10.14062/j.issn.0454-5648.20220700
  • 国家自然科学基金(51902245)
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doi: 10.14062/j.issn.0454-5648.20220700
  • 接收时间:2022-08-28
  • 首发时间:2026-10-20
  • 出版时间:2023-04-20
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  • 收稿日期:2022-08-28
  • 修回日期:2022-09-22
基金
国家自然科学基金(51902245)
作者信息
    1.西安交通大学材料科学与工程学院,金属材料强度国家重点实验室,西安 710049
    2.南方科技大学材料科学与工程系,广东 深圳 518055

通讯作者:

郭靖(1986—),男,博士,副教授。
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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