Article(id=1319222602422403871, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222570398888648, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20220870, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1665590400000, receivedDateStr=2022-10-13, revisedDate=1667059200000, revisedDateStr=2022-10-30, acceptedDate=null, acceptedDateStr=null, onlineDate=1792456778387, onlineDateStr=2026-10-20, pubDate=1679241600000, pubDateStr=2023-03-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792456778387, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792456778387, creator=13701087609, updateTime=1792456778387, updator=13701087609, issue=Issue{id=1319222570398888648, tenantId=1146029695717560320, journalId=1263187385517883426, year='2023', volume='51', issue='3', pageStart='561', pageEnd='830', issueExtLink='null', onlineDate='null', pubDate='1679241600000', pubDateStr='2023-03-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792456770752, creator='13701087609', updateTime=1792456924637, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319223215889699377, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222570398888648, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319223215889699378, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222570398888648, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=641, endPage=648, ext={EN=ArticleExt(id=1319222602632119072, articleId=1319222602422403871, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Interaction Behavior of Periclase-Hercynite Material with Cement Clinker, columnId=1321891096775472081, journalTitle=Journal of the Chinese Ceramic Society, columnName=Special Issue on Advances in Basic Research on Refractories Related—Research Articles, runingTitle=null, highlight=null, articleAbstract=

Periclase-hercynite refractories are used in the firing zone of the cement rotary kiln, which is inextricably linked to their reaction behavior with cement clinker at high temperatures. In this paper, the corrosion behavior of magnesia aggregate and hercynite aggregate as well as periclase-hercynite refractory with cement clinker at high temperatures was investigated by scanning electron microscopy, X-ray diffraction, and Factsage simulation, respectively. The results show that magnesia particles have a superior corrosion-resistance to cement clinker, and the reaction of hercynite with cement clinker produces massive high-temperature liquid phase, which is gradually corroded. The periclase phase and hercynite particles have a synergistic effect on resisting the cement clinker corrosion in periclase-hercynite bricks at high temperatures. The periclase matrix as a major crystalline phase reacts with cement to generate a high melting point phase, forming a skeletal structure in the grain boundary phase, improving the grain boundary phase's high-temperature viscosity, and promoting the combination of clinker and refractory. Also, ion exchange between hercynite and magnesia promotes the combination of hercynite and matrix, while inhibiting the formation of low melting point feldspar phases at high temperatures. Furthermore, the high-temperature stability of hercynite is improved, which benefits the kiln coating stability when using the refractory in the firing zone.

, authors=Yuchi LIU, Hongfeng YIN, Yalou XIN, Yun TANG, Bin ZUO, Hudie YUAN, authorsList=Yuchi LIU, Hongfeng YIN, Yalou XIN, Yun TANG, Bin ZUO, Hudie YUAN, authorCompany=null, correspAuthors=Hongfeng YIN, authorNote=

LIU Yuchi (1997-), male, Doctorial Candidate. E-mail:

, correspAuthorsNote=
YIN Hongfeng (1965-), male, Ph.D., Professor. E-mail:
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方镁石-铁铝尖晶石耐火材料在水泥回转窑烧成带取得良好使用效果,这与其高温下同水泥熟料之间的反应行为密不可分。利用扫描电子显微镜、X射线衍射仪与Factsage模拟等手段研究了镁砂和铁铝尖晶石颗粒以及方镁石-铁铝尖晶石砖高温下与水泥熟料的作用行为。结果表明:镁砂具有优异的抗水泥熟料侵蚀性能,铁铝尖晶石与水泥熟料高温反应生成大量高温液相,并逐渐被蚕蚀。对于方镁石-铁铝尖晶石砖,方镁石物相和铁铝尖晶石颗粒高温下抵抗水泥熟料侵蚀表现出协同作用。以方镁石为主晶相的基质与水泥物料反应生成高熔点物相,在晶界相内形成骨架结构,提高了晶界相的高温粘度,促进了水泥熟料与耐火材料的结合。同时,铁铝尖晶石与方镁石之间的离子交换促进了铁铝尖晶石颗粒与方镁石基质的结合,抑制了高温下与水泥物料反应时长石类低熔点相的产生,提高了铁铝尖晶石的高温稳定性,有利于该类耐火砖在烧成带使用时窑皮的稳定。

, authors=刘宇驰, 尹洪峰, 辛亚楼, 汤云, 左斌, 袁蝴蝶, authorsList=刘宇驰, 尹洪峰, 辛亚楼, 汤云, 左斌, 袁蝴蝶, authorCompany=null, correspAuthors=尹洪峰, authorNote=

刘宇驰(1997—),男,博士研究生。

, correspAuthorsNote=
尹洪峰(1965—),男,博士,教授。
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方镁石-铁铝尖晶石材料与水泥熟料间的作用行为
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刘宇驰 , 尹洪峰 , 辛亚楼 , 汤云 , 左斌 , 袁蝴蝶
硅酸盐学报 | 耐火材料相关基础研究进展专题—研究论文 2023,51(3): 641-648
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硅酸盐学报 |耐火材料相关基础研究进展专题—研究论文 2023 , 51 (3) : 641 -648
方镁石-铁铝尖晶石材料与水泥熟料间的作用行为
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刘宇驰 , 尹洪峰 , 辛亚楼, 汤云, 左斌, 袁蝴蝶
作者信息
  • 西安建筑科技大学材料科学与工程学院,西安 710055
通讯作者:
尹洪峰(1965—),男,博士,教授。
作者简介:

刘宇驰(1997—),男,博士研究生。

Interaction Behavior of Periclase-Hercynite Material with Cement Clinker
Yuchi LIU , Hongfeng YIN , Yalou XIN, Yun TANG, Bin ZUO, Hudie YUAN
Affiliations
  • College of Materials Science and Engineering, Xi'an University of Architecture &Technology, Xi'an 710055, China
  • Corresponding Author:
    YIN Hongfeng (1965-), male, Ph.D., Professor. E-mail:

    LIU Yuchi (1997-), male, Doctorial Candidate. E-mail:

出版时间: 2023-03-20 doi: 10.14062/j.issn.0454-5648.20220870
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方镁石-铁铝尖晶石耐火材料在水泥回转窑烧成带取得良好使用效果,这与其高温下同水泥熟料之间的反应行为密不可分。利用扫描电子显微镜、X射线衍射仪与Factsage模拟等手段研究了镁砂和铁铝尖晶石颗粒以及方镁石-铁铝尖晶石砖高温下与水泥熟料的作用行为。结果表明:镁砂具有优异的抗水泥熟料侵蚀性能,铁铝尖晶石与水泥熟料高温反应生成大量高温液相,并逐渐被蚕蚀。对于方镁石-铁铝尖晶石砖,方镁石物相和铁铝尖晶石颗粒高温下抵抗水泥熟料侵蚀表现出协同作用。以方镁石为主晶相的基质与水泥物料反应生成高熔点物相,在晶界相内形成骨架结构,提高了晶界相的高温粘度,促进了水泥熟料与耐火材料的结合。同时,铁铝尖晶石与方镁石之间的离子交换促进了铁铝尖晶石颗粒与方镁石基质的结合,抑制了高温下与水泥物料反应时长石类低熔点相的产生,提高了铁铝尖晶石的高温稳定性,有利于该类耐火砖在烧成带使用时窑皮的稳定。

方镁石-铁铝尖晶石耐火材料  /  抗侵蚀性能  /  水泥熟料  /  窑皮

Periclase-hercynite refractories are used in the firing zone of the cement rotary kiln, which is inextricably linked to their reaction behavior with cement clinker at high temperatures. In this paper, the corrosion behavior of magnesia aggregate and hercynite aggregate as well as periclase-hercynite refractory with cement clinker at high temperatures was investigated by scanning electron microscopy, X-ray diffraction, and Factsage simulation, respectively. The results show that magnesia particles have a superior corrosion-resistance to cement clinker, and the reaction of hercynite with cement clinker produces massive high-temperature liquid phase, which is gradually corroded. The periclase phase and hercynite particles have a synergistic effect on resisting the cement clinker corrosion in periclase-hercynite bricks at high temperatures. The periclase matrix as a major crystalline phase reacts with cement to generate a high melting point phase, forming a skeletal structure in the grain boundary phase, improving the grain boundary phase's high-temperature viscosity, and promoting the combination of clinker and refractory. Also, ion exchange between hercynite and magnesia promotes the combination of hercynite and matrix, while inhibiting the formation of low melting point feldspar phases at high temperatures. Furthermore, the high-temperature stability of hercynite is improved, which benefits the kiln coating stability when using the refractory in the firing zone.

periclase-hercynite refractory  /  corrosion resistance  /  cement clinker  /  kiln coating
刘宇驰, 尹洪峰, 辛亚楼, 汤云, 左斌, 袁蝴蝶. 方镁石-铁铝尖晶石材料与水泥熟料间的作用行为. 硅酸盐学报, 2023 , 51 (3) : 641 -648 . DOI: 10.14062/j.issn.0454-5648.20220870
Yuchi LIU, Hongfeng YIN, Yalou XIN, Yun TANG, Bin ZUO, Hudie YUAN. Interaction Behavior of Periclase-Hercynite Material with Cement Clinker[J]. Journal of the Chinese Ceramic Society, 2023 , 51 (3) : 641 -648 . DOI: 10.14062/j.issn.0454-5648.20220870
  • 国家自然科学基金(51572213)
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2023年第51卷第3期
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doi: 10.14062/j.issn.0454-5648.20220870
  • 接收时间:2022-10-13
  • 首发时间:2026-10-20
  • 出版时间:2023-03-20
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  • 收稿日期:2022-10-13
  • 修回日期:2022-10-30
基金
国家自然科学基金(51572213)
作者信息
    西安建筑科技大学材料科学与工程学院,西安 710055

通讯作者:

尹洪峰(1965—),男,博士,教授。
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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