Article(id=1319222594436453259, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222570398888648, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20220864, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1665504000000, receivedDateStr=2022-10-12, revisedDate=1667836800000, revisedDateStr=2022-11-08, acceptedDate=null, acceptedDateStr=null, onlineDate=1792456776484, onlineDateStr=2026-10-20, pubDate=1679241600000, pubDateStr=2023-03-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792456776484, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792456776484, creator=13701087609, updateTime=1792456776484, updator=13701087609, issue=Issue{id=1319222570398888648, tenantId=1146029695717560320, journalId=1263187385517883426, year='2023', volume='51', issue='3', pageStart='561', pageEnd='830', issueExtLink='null', onlineDate='null', pubDate='1679241600000', pubDateStr='2023-03-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792456770752, creator='13701087609', updateTime=1792456924637, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319223215889699377, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222570398888648, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319223215889699378, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222570398888648, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=610, endPage=618, ext={EN=ArticleExt(id=1319222596126757772, articleId=1319222594436453259, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Dissolution Behavior of Fused Magnesia in CaO-Al2O3-SiO2 Slags, columnId=1321891096775472081, journalTitle=Journal of the Chinese Ceramic Society, columnName=Special Issue on Advances in Basic Research on Refractories Related—Research Articles, runingTitle=null, highlight=null, articleAbstract=

As an important raw material of magnesia based refractories, the dissolution of the fused magnesia in the CaO-Al2O3-SiO2 slags for refining a low density and high strength steel is an important factor affecting the service life of furnace lining and the quality of steel. In this paper, the dissolution behavior of fused magnesia in the slag at 1 600 ℃ was investigated by a high-temperature laser confocal microscopy system. The effects of the shape and mass of magnesia particles and the mass fraction ratio of CaO to SiO2(C/S) on the dissolution behavior were investigated. The results show that the shape of fused magnesia particles has little effect on its dissolution rate. The dissolution rate decreases linearly with the increase of mass, and it decreases firstly and then increases with the increase of C/S ratio. The dissolution curve of magnesia particles is affected by the mass, and the n values of the dissolution model can correspond to 1/2, 2/3 and 3/5, respectively. This work provides a guidance for understanding the slag corrosion behavior of magnesia based refractories, improving the quality and optimizing the performance of magnesia based refractories.

, authors=Xinyu CHEN, Ao HUANG, Shenghao LI, Huazhi GU, Lvping FU, authorsList=Xinyu CHEN, Ao HUANG, Shenghao LI, Huazhi GU, Lvping FU, authorCompany=null, correspAuthors=Ao HUANG, authorNote=

CHEN Xinyu (1999-), female, Master candidate. E-mail:

, correspAuthorsNote=
HUANG Ao (1982-), male, Ph.D., Professor. E-mail:
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1319222596365833101, articleId=1319222594436453259, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=电熔镁砂在CaO-Al2O3-SiO2熔渣中的溶解行为, columnId=1321891096976798674, journalTitle=硅酸盐学报, columnName=耐火材料相关基础研究进展专题—研究论文, runingTitle=null, highlight=null, articleAbstract=

作为镁质耐火材料的重要原料,电熔镁砂在低密度高强钢精炼用CaO-Al2O3-SiO2系熔渣中的溶解是影响炉衬使用寿命及钢质量的重要因素。本工作采用高温激光共聚焦显微观测系统研究了1600 ℃下镁砂在该熔渣中的溶解行为,探究了镁砂颗粒的形状、质量及熔渣CaO和SiO2质量分数比(即C/S)对其溶解行为的影响。结果表明:镁砂主要形状对其溶解速率影响较小;溶解速率随质量增大呈近线性下降,随C/S的增加而先降低后增加;镁砂颗粒的溶解曲线受质量影响更大,其溶解模型n值分别对应1/2、2/3、3/5,这为深入理解镁质耐火材料的渣蚀行为和提质优化提供指导。

, authors=陈欣雨, 黄奥, 李昇昊, 顾华志, 付绿平, authorsList=陈欣雨, 黄奥, 李昇昊, 顾华志, 付绿平, authorCompany=null, correspAuthors=黄奥, authorNote=

陈欣雨(1999—),女,硕士研究生。

, correspAuthorsNote=
黄奥(1982—),男,博士,教授。
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CHEN Xinyu (1999-), female, Master candidate. E-mail:

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陈欣雨(1999—),女,硕士研究生。

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陈欣雨(1999—),女,硕士研究生。

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电熔镁砂在CaO-Al2O3-SiO2熔渣中的溶解行为
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陈欣雨 , 黄奥 , 李昇昊 , 顾华志 , 付绿平
硅酸盐学报 | 耐火材料相关基础研究进展专题—研究论文 2023,51(3): 610-618
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硅酸盐学报 |耐火材料相关基础研究进展专题—研究论文 2023 , 51 (3) : 610 -618
电熔镁砂在CaO-Al2O3-SiO2熔渣中的溶解行为
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陈欣雨 , 黄奥 , 李昇昊, 顾华志, 付绿平
作者信息
  • 武汉科技大学,省部共建耐火材料与冶金国家重点实验室,武汉 430081
通讯作者:
黄奥(1982—),男,博士,教授。
作者简介:

陈欣雨(1999—),女,硕士研究生。

Dissolution Behavior of Fused Magnesia in CaO-Al2O3-SiO2 Slags
Xinyu CHEN , Ao HUANG , Shenghao LI, Huazhi GU, Lvping FU
Affiliations
  • The State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan 430081, China
  • Corresponding Author:
    HUANG Ao (1982-), male, Ph.D., Professor. E-mail:

    CHEN Xinyu (1999-), female, Master candidate. E-mail:

出版时间: 2023-03-20 doi: 10.14062/j.issn.0454-5648.20220864
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作为镁质耐火材料的重要原料,电熔镁砂在低密度高强钢精炼用CaO-Al2O3-SiO2系熔渣中的溶解是影响炉衬使用寿命及钢质量的重要因素。本工作采用高温激光共聚焦显微观测系统研究了1600 ℃下镁砂在该熔渣中的溶解行为,探究了镁砂颗粒的形状、质量及熔渣CaO和SiO2质量分数比(即C/S)对其溶解行为的影响。结果表明:镁砂主要形状对其溶解速率影响较小;溶解速率随质量增大呈近线性下降,随C/S的增加而先降低后增加;镁砂颗粒的溶解曲线受质量影响更大,其溶解模型n值分别对应1/2、2/3、3/5,这为深入理解镁质耐火材料的渣蚀行为和提质优化提供指导。

电熔镁砂  /  耐火材料  /  溶解速率  /  氧化钙-氧化铝-二氧化硅系熔渣  /  溶解模型

As an important raw material of magnesia based refractories, the dissolution of the fused magnesia in the CaO-Al2O3-SiO2 slags for refining a low density and high strength steel is an important factor affecting the service life of furnace lining and the quality of steel. In this paper, the dissolution behavior of fused magnesia in the slag at 1 600 ℃ was investigated by a high-temperature laser confocal microscopy system. The effects of the shape and mass of magnesia particles and the mass fraction ratio of CaO to SiO2(C/S) on the dissolution behavior were investigated. The results show that the shape of fused magnesia particles has little effect on its dissolution rate. The dissolution rate decreases linearly with the increase of mass, and it decreases firstly and then increases with the increase of C/S ratio. The dissolution curve of magnesia particles is affected by the mass, and the n values of the dissolution model can correspond to 1/2, 2/3 and 3/5, respectively. This work provides a guidance for understanding the slag corrosion behavior of magnesia based refractories, improving the quality and optimizing the performance of magnesia based refractories.

fused magnesia  /  refractory  /  dissolution rate  /  calcium oxide-alumina-silicon dioxide slag  /  dissolution model
陈欣雨, 黄奥, 李昇昊, 顾华志, 付绿平. 电熔镁砂在CaO-Al2O3-SiO2熔渣中的溶解行为. 硅酸盐学报, 2023 , 51 (3) : 610 -618 . DOI: 10.14062/j.issn.0454-5648.20220864
Xinyu CHEN, Ao HUANG, Shenghao LI, Huazhi GU, Lvping FU. Dissolution Behavior of Fused Magnesia in CaO-Al2O3-SiO2 Slags[J]. Journal of the Chinese Ceramic Society, 2023 , 51 (3) : 610 -618 . DOI: 10.14062/j.issn.0454-5648.20220864
  • 国家自然科学基金面上项目(52272022)
  • 湖北省自然科学基金杰出青年项目(2021CFA071)
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2023年第51卷第3期
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doi: 10.14062/j.issn.0454-5648.20220864
  • 接收时间:2022-10-12
  • 首发时间:2026-10-20
  • 出版时间:2023-03-20
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  • 收稿日期:2022-10-12
  • 修回日期:2022-11-08
基金
国家自然科学基金面上项目(52272022)
湖北省自然科学基金杰出青年项目(2021CFA071)
作者信息
    武汉科技大学,省部共建耐火材料与冶金国家重点实验室,武汉 430081

通讯作者:

黄奥(1982—),男,博士,教授。
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https://castjournals.cast.org.cn/joweb/gsyxb/CN/10.14062/j.issn.0454-5648.20220864
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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