Article(id=1319222527126262080, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222524555153701, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20220526, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1656432000000, receivedDateStr=2022-06-29, revisedDate=1658678400000, revisedDateStr=2022-07-25, acceptedDate=null, acceptedDateStr=null, onlineDate=1792456760435, onlineDateStr=2026-10-20, pubDate=1676822400000, pubDateStr=2023-02-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792456760435, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792456760435, creator=13701087609, updateTime=1792456760435, updator=13701087609, issue=Issue{id=1319222524555153701, tenantId=1146029695717560320, journalId=1263187385517883426, year='2023', volume='51', issue='2', pageStart='283', pageEnd='560', issueExtLink='null', onlineDate='null', pubDate='1676822400000', pubDateStr='2023-02-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792456759823, creator='13701087609', updateTime=1792456885477, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319223051636560419, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222524555153701, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319223051636560420, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222524555153701, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=290, endPage=302, ext={EN=ArticleExt(id=1319222527298228545, articleId=1319222527126262080, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Alkali Metal Doping Influence on Hydration Properties of Ternesite, columnId=1321891673328697650, journalTitle=Journal of the Chinese Ceramic Society, columnName=Special Issue on Inerim Achievement of Key Program of National Natural Science Foundation of China—Research Articles, runingTitle=null, highlight=null, articleAbstract=

Alkali metal ions as some impurity ions in cement raw materials can affect the structure and properties of clinker minerals. The effect of alkali metal ions on the hydration activity and mechanical properties of ternesite was investigated with alkali-doped ternesite synthesized as analytical reagents by isothermal calorimetry, comprehensive thermal analysis, scanning electron microscopy and 29Si solid state nuclear magnetic resonance. The results show that the solid solution of alkali metal ions in the crystal structure of ternesite reduces the crystallinity of formed crystals, forms the crystal defects, effectively improves the early hydration activity of ternesite, and promotes the rapid development of its early mechanical properties. Meanwhile, the addition of alkali metal can change the microstructure and structure of calcium silicate hydrates (C-S-H). Among them, Li2O addition stabilizes the flocculent C-S-H, while Na2O and K2O addition can induce the fibrous growth of C-S-H. The degree of polymerization and mean silicon chain length of C-S-H increase due to the addition of alkali metal.

, authors=Wensheng ZHANG1, Lei LIU1, Xuehong REN1, Hongtao ZHANG1, Jiayuan YE1, Jiangtao ZHANG1, Lixue CAO1, Nan AN1, Jueshi QIAN2, authorsList=Wensheng ZHANG, Lei LIU, Xuehong REN, Hongtao ZHANG, Jiayuan YE, Jiangtao ZHANG, Lixue CAO, Nan AN, Jueshi QIAN, authorCompany=null, correspAuthors=null, authorNote=

ZHANG Wensheng (1969-), male, Ph.D., Professor. E-mail:

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碱金属离子作为水泥原料中常见的杂质离子,其存在会影响熟料矿物结构与性能。采用分析纯试剂合成碱金属掺杂的硫硅酸钙单矿物,借助等温量热仪、综合热分析、扫描电镜和29Si核磁共振等手段,研究了碱金属离子对硫硅酸钙水化活性及力学性能的影响。结果表明:碱金属离子在硫硅酸钙晶体结构中的固溶,能够降低晶体结晶度,形成晶体缺陷,有效提升硫硅酸钙早期水化活性,促进其早期力学性能快速发展。同时,碱金属的掺杂能够改变水化硅酸钙(C-S-H)凝胶等产物的微观形貌及结构。其中,Li2O掺杂能够稳定絮状形态的C-S-H凝胶,而Na2O和K2O掺杂能够诱导C-S-H凝胶纤维状生长。经碱金属掺杂影响,C-S-H凝胶聚合度有所增加,平均硅链长增长。

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张文生(1969—),男,博士,教授。

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ZHANG Wensheng (1969-), male, Ph.D., Professor. E-mail:

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碱金属掺杂对硫硅酸钙水化性能的影响机理
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张文生 1 , 刘垒 1 , 任雪红 1 , 张洪滔 1 , 叶家元 1 , 张江涛 1 , 曹立学 1 , 安楠 1 , 钱觉时 2
硅酸盐学报 | 国家自然科学基金重点项目中期成果专题—研究论文 2023,51(2): 290-302
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硅酸盐学报 |国家自然科学基金重点项目中期成果专题—研究论文 2023 , 51 (2) : 290 -302
碱金属掺杂对硫硅酸钙水化性能的影响机理
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张文生1 , 刘垒1, 任雪红1, 张洪滔1, 叶家元1, 张江涛1, 曹立学1, 安楠1, 钱觉时2
作者信息
  • 1.中国建筑材料科学研究总院有限公司,绿色建筑材料国家重点实验室,北京 100024
  • 2.重庆大学材料科学与工程学院,重庆 400045
作者简介:

张文生(1969—),男,博士,教授。

Alkali Metal Doping Influence on Hydration Properties of Ternesite
Wensheng ZHANG1 , Lei LIU1, Xuehong REN1, Hongtao ZHANG1, Jiayuan YE1, Jiangtao ZHANG1, Lixue CAO1, Nan AN1, Jueshi QIAN2
Affiliations
  • 1.State Key Laboratory of Green Building Materials, China Building Materials Academy, Beijing 100024, China
  • 2.College of Materials Science and Engineering, Chongqing University, Chongqing 400045, China
  • ZHANG Wensheng (1969-), male, Ph.D., Professor. E-mail:

出版时间: 2023-02-20 doi: 10.14062/j.issn.0454-5648.20220526
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碱金属离子作为水泥原料中常见的杂质离子,其存在会影响熟料矿物结构与性能。采用分析纯试剂合成碱金属掺杂的硫硅酸钙单矿物,借助等温量热仪、综合热分析、扫描电镜和29Si核磁共振等手段,研究了碱金属离子对硫硅酸钙水化活性及力学性能的影响。结果表明:碱金属离子在硫硅酸钙晶体结构中的固溶,能够降低晶体结晶度,形成晶体缺陷,有效提升硫硅酸钙早期水化活性,促进其早期力学性能快速发展。同时,碱金属的掺杂能够改变水化硅酸钙(C-S-H)凝胶等产物的微观形貌及结构。其中,Li2O掺杂能够稳定絮状形态的C-S-H凝胶,而Na2O和K2O掺杂能够诱导C-S-H凝胶纤维状生长。经碱金属掺杂影响,C-S-H凝胶聚合度有所增加,平均硅链长增长。

硫硅酸钙  /  碱金属  /  水化活性  /  力学性能  /  水化硅酸钙凝胶  /  微观形貌

Alkali metal ions as some impurity ions in cement raw materials can affect the structure and properties of clinker minerals. The effect of alkali metal ions on the hydration activity and mechanical properties of ternesite was investigated with alkali-doped ternesite synthesized as analytical reagents by isothermal calorimetry, comprehensive thermal analysis, scanning electron microscopy and 29Si solid state nuclear magnetic resonance. The results show that the solid solution of alkali metal ions in the crystal structure of ternesite reduces the crystallinity of formed crystals, forms the crystal defects, effectively improves the early hydration activity of ternesite, and promotes the rapid development of its early mechanical properties. Meanwhile, the addition of alkali metal can change the microstructure and structure of calcium silicate hydrates (C-S-H). Among them, Li2O addition stabilizes the flocculent C-S-H, while Na2O and K2O addition can induce the fibrous growth of C-S-H. The degree of polymerization and mean silicon chain length of C-S-H increase due to the addition of alkali metal.

ternesite  /  alkali metal  /  hydration activity  /  mechanical properties  /  calcium silicate hydrates  /  microstructure
张文生, 刘垒, 任雪红, 张洪滔, 叶家元, 张江涛, 曹立学, 安楠, 钱觉时. 碱金属掺杂对硫硅酸钙水化性能的影响机理. 硅酸盐学报, 2023 , 51 (2) : 290 -302 . DOI: 10.14062/j.issn.0454-5648.20220526
Wensheng ZHANG, Lei LIU, Xuehong REN, Hongtao ZHANG, Jiayuan YE, Jiangtao ZHANG, Lixue CAO, Nan AN, Jueshi QIAN. Alkali Metal Doping Influence on Hydration Properties of Ternesite[J]. Journal of the Chinese Ceramic Society, 2023 , 51 (2) : 290 -302 . DOI: 10.14062/j.issn.0454-5648.20220526
  • 国家自然科学基金重点项目(51832006)
  • 中国建材集团攻关专项资助项目(2021HX0304)
  • 国家自然科学基金面上项目(51772281)
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2023年第51卷第2期
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doi: 10.14062/j.issn.0454-5648.20220526
  • 接收时间:2022-06-29
  • 首发时间:2026-10-20
  • 出版时间:2023-02-20
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  • 收稿日期:2022-06-29
  • 修回日期:2022-07-25
基金
国家自然科学基金重点项目(51832006)
中国建材集团攻关专项资助项目(2021HX0304)
国家自然科学基金面上项目(51772281)
作者信息
    1.中国建筑材料科学研究总院有限公司,绿色建筑材料国家重点实验室,北京 100024
    2.重庆大学材料科学与工程学院,重庆 400045
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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