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Graphdiyne (GD) is one of carbon allotropes with the unique structure and has ideal high strength, excellent light transmittance, electrical conductivity, high carrier mobility, and thermal conductivity. GD with a natural band gap is an intrinsic semiconductor with special charge transport properties. GD shows a band gap in the range of 0.45 to 1.30 eV, compared with graphene without band gap, which has a promising potential for electronic, catalytic, optical and mechanical applications. Also, GD has two different Dirac cones near the top and bottom of the Fermi energy level, indicating that GD is a self-doped semiconductor with charge carriers and does not require additional doping like graphene. GD can be used as a potential and excellent photocatalytic material, and theoretically it is needed to be modified to build active sites for efficient photo-induced reactions.
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石墨炔是一种新型碳的同素异形体,其独特的结构使得该物质具有理想的高强度、导电性、导热性、透光性和高载流子迁移率、热导率等。石墨炔具有天然的带隙,属于本征半导体,具有特别的电荷输运性能。石墨炔与无带隙的石墨烯相比,在0.45~1.30 eV范围内显示出带隙,这使其在电子、催化、光学和机械方面具有强大的应用潜能,为碳材料的基础和应用研究提供新的空间、带来了新的内涵,引起了广泛的关注。此外,石墨炔在Fermi能级上下附近具有2个不同的Dirac锥,这表示石墨炔为自掺杂(self-doped)半导体,原本就具有电荷载流子,不需要像石墨烯一样要通过额外掺杂实现。石墨炔是十分契合的潜在的且卓越的光催化材料,理论上只需修饰构建活性位点即可高效光诱导反应。
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JIN Zhiliang (1966-), male, Ph.D., Professor. E-mail: zl-jin@nun.edu.cn
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JIN Zhiliang (1966-), male, Ph.D., Professor. E-mail: zl-jin@nun.edu.cn
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靳治良(1966—),男,博士,研究员。
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