Article(id=1319222260985082847, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222240177144549, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20220593, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1658246400000, receivedDateStr=2022-07-20, revisedDate=1663084800000, revisedDateStr=2022-09-14, acceptedDate=null, acceptedDateStr=null, onlineDate=1792456696983, onlineDateStr=2026-10-20, pubDate=1674144000000, pubDateStr=2023-01-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792456696983, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792456696983, creator=13701087609, updateTime=1792456696983, updator=13701087609, issue=Issue{id=1319222240177144549, tenantId=1146029695717560320, journalId=1263187385517883426, year='2023', volume='51', issue='1', pageStart='1', pageEnd='282', issueExtLink='null', onlineDate='null', pubDate='1674144000000', pubDateStr='2023-01-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792456692021, creator='13701087609', updateTime=1792456863865, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319222960989262349, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222240177144549, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319222960989262350, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222240177144549, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=117, endPage=123, ext={EN=ArticleExt(id=1319222262478255072, articleId=1319222260985082847, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Regeneration of Lithium Manganate Cathode Material from Malic Acid Leachate of High Manganese Cathode Material of Spent Lithium-ion Batteries, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=
Waste lithium batteries have become a research hotspot due to their extremely high resources and hazards. Hygrometallurgical recycling is the main existing method for processing waste lithium battery cathode materials, and the recovery of valuable metal elements from the leaching solutions is the key to hygrometallurgical recovery of waste cathode materials. In this paper, nickel, cobalt and manganese were precipitated from a malic acid leaching solution of high manganese cathode material of waste lithium battery as raw material via ozone oxidation, and the optimal precipitation conditions were obtained. The results show that the precipitation rates of nickel, cobalt, and manganese are 18.2%, 41.5%, and 85.8%, and the contents of nickel, cobalt, and manganese in the ozone precipitation slag are 0.85%, 1.63%, and 41.3%, respectively under the optimal precipitation conditions. The ozone oxidation precipitation slag is a high manganese-based precursor, and the precursor is regenerated into LiMn2O4 cathode material after supplementing lithium. The first discharge specific capacity of this regenerate cathode material is 95.4 mA·h/g, and the first charge-discharge efficiency is 84%. The discharge specific capacity retention rate is 67.4% at a high rate, and the discharge specific capacity retention rate after 100 cycles is 80%.
, authors=Pengyuan CUI
1, Xiaohua YU
1, Yonggang LI
2, Yan LIN
1, Qingfeng SHEN
1, Lu WANG
1, Zhaoyang ZHANG
1, authorsList=Pengyuan CUI, Xiaohua YU, Yonggang LI, Yan LIN, Qingfeng SHEN, Lu WANG, Zhaoyang ZHANG, authorCompany=null, correspAuthors=Xiaohua YU, authorNote=
, correspAuthorsNote=
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废旧锂电池因其具有极高的资源性和危害性成为研究的热点,湿法回收是目前处理废旧锂电正极材料的主要方法,而从废旧正极材料浸出液中回收有价金属元素已成为湿法回收的关键。因此,以废旧锂电池高锰正极材料苹果酸浸出液为原料,通过臭氧氧化沉淀镍、钴、锰得到最佳沉淀条件,并制备出高锰基前驱体。研究发现:在最佳沉淀条件下,镍、钴、锰的沉淀率分别为18.2%、41.5%、85.8%;臭氧沉淀渣中的镍、钴、锰含量分别为0.85%、1.63%、41.30%。可以看出,该臭氧氧化沉淀渣为高锰基前驱体,前驱体经补锂再生为LiMn2O4正极材料,该正极材料的首次放电比容量为95.4 mA·h/g,首次充放电效率为84%,高倍率下的放电比容量保持率为67.4%,100次循环后的放电比容量保持率为80%。
, authors=崔鹏媛
1, 俞小花
1, 李永刚
2, 林艳
1, 沈庆峰
1, 王露
1, 张钊洋
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, correspAuthorsNote=
俞小花(1978—),女,副教授。
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CUI Pengyuan (1995-), male, Master candidate. E-mail: 2543629892@qq.com
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CUI Pengyuan (1995-), male, Master candidate. E-mail: 2543629892@qq.com
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1.昆明理工大学冶金与能源工程学院,昆明 650093, bio={"content":"
崔鹏媛(1995—),男,硕士研究生。
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崔鹏媛(1995—),男,硕士研究生。
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