Article(id=1319222247429100289, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222240177144549, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20220356, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1658160000000, receivedDateStr=2022-07-19, revisedDate=1659628800000, revisedDateStr=2022-08-05, acceptedDate=null, acceptedDateStr=null, onlineDate=1792456693750, onlineDateStr=2026-10-20, pubDate=1674144000000, pubDateStr=2023-01-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792456693750, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792456693750, creator=13701087609, updateTime=1792456693750, updator=13701087609, issue=Issue{id=1319222240177144549, tenantId=1146029695717560320, journalId=1263187385517883426, year='2023', volume='51', issue='1', pageStart='1', pageEnd='282', issueExtLink='null', onlineDate='null', pubDate='1674144000000', pubDateStr='2023-01-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792456692021, creator='13701087609', updateTime=1792456863865, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319222960989262349, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222240177144549, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319222960989262350, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222240177144549, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=58, endPage=63, ext={EN=ArticleExt(id=1319222248884523780, articleId=1319222247429100289, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Preparation and Photocatalytic Activity of Ce-Doped ZnFe₂O₄ Multilayer Hollow Microspheres, columnId=1321891568328487649, journalTitle=Journal of the Chinese Ceramic Society, columnName=Special Issue on Photocatalytic Materials—Research Articles, runingTitle=null, highlight=null, articleAbstract=

To eradicate antibiotics from aqueous solution, cerium(Ce) doped ZnFe₂O₄ microspheres with different Ce mass ratios were prepared by a hydrothermal method and applied for the photocatalytic decomposition of tetracycline antibiotic. The results reveal that the introduction of Ce improves the charge separation for the photogenerated electron-hole pairs, which can be confirmed form the photocurrent spectra. The optimized sample ZnFe_1.96Ce_0.04O₄ shows a decomposition rate of 56.6% under simulated solar light within 40 min. The trapping experiments show that hydroxyl radical and superoxide radical are the main degrading species, directly involving in the decomposition of antibiotics. Moreover, the rate of hydrogen produced from water splitting photocatalyzed by ZnFe_1.96Ce_0.04O₄ reaches 230.4 μmol/(g·h) under simulated solar light irradiation.

, authors=Xiangbin YIN, Yitong HAO, Ruidan WANG, Ying LIU, Kezhen QI, authorsList=Xiangbin YIN, Yitong HAO, Ruidan WANG, Ying LIU, Kezhen QI, authorCompany=null, correspAuthors=Ying LIU, Kezhen QI, authorNote=, correspAuthorsNote=, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1319222249157153541, articleId=1319222247429100289, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=铈掺杂ZnFe₂O₄多层空心微球的制备及其光催化活性, columnId=1321891568521425634, journalTitle=硅酸盐学报, columnName=光催化材料专题—研究论文, runingTitle=null, highlight=null, articleAbstract=

为了消除水中的有害抗生素，在水热条件下制备了不同质量分数比的铈（Ce）掺杂ZnFe₂O₄光催化材料。优化后的样品ZnFe_1.96Ce_0.04O₄在模拟太阳光照射下，40 min内对盐酸四环素的降解率为56.6%。样品的光电流信号响应研究证实，Ce的引入有助于提升ZnFe₂O₄中光生电荷对的分离。捕获剂测试实验表明，羟基自由基和超氧自由基是最主要的活性氧物种，直接参与了抗生素的光降解过程。此外，在模拟太阳光照射下，ZnFe_1.96Ce_0.04O₄的光解水产氢速率达到了230.4 μmol/（g·h）。

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YIN Xiangbin (1998-), male, Master candidate. E-mail: 1057985820@qq.com

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YIN Xiangbin (1998-), male, Master candidate. E-mail: 1057985820@qq.com

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尹相镔（1998—），男，硕士研究生。

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尹相镔（1998—），男，硕士研究生。

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