Article(id=1318979402243887740, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318979383570837667, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20230319, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1683734400000, receivedDateStr=2023-05-11, revisedDate=1684857600000, revisedDateStr=2023-05-24, acceptedDate=null, acceptedDateStr=null, onlineDate=1792398794946, onlineDateStr=2026-10-19, pubDate=1700409600000, pubDateStr=2023-11-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792398794946, onlineIssueDateStr=2026-10-19, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792398794946, creator=13701087609, updateTime=1792398794946, updator=13701087609, issue=Issue{id=1318979383570837667, tenantId=1146029695717560320, journalId=1263187385517883426, year='2023', volume='51', issue='11', pageStart='2739', pageEnd='3038', issueExtLink='null', onlineDate='null', pubDate='1700409600000', pubDateStr='2023-11-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1792398790495, creator='13701087609', updateTime=1792399377667, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1318981846411629158, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318979383570837667, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1318981846411629159, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318979383570837667, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=2924, endPage=2930, ext={EN=ArticleExt(id=1318979402441020029, articleId=1318979402243887740, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Decalcification Behavior of Calcium Silicate Hydrate with Different Ca/Si Ratios, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=

This paper was to synthesize C-S-H with different Ca/Si ratios by a hydrothermal synthesis method, and decalcify it using 6 mol/L NH₄Cl solutions. The chemical composition, chain structure and microstructure were analyzed. The results show that C-S-H is a gel structure formed by irregular aggregates. The content of dimer and chain end groups in C-S-H increases, while the average degree of polymerization and average chain length decreases with the increase of Ca/Si ratio. The change of C-S-H structure includes decreased interlayer distance, cross-linked silicate chains, and amorphous silica gels formed after decalcification, resulting in the loss of C-S-H cohesion.

, authors=Ziwei ZHANG, Zhentao LIU, Guoxin LI, authorsList=Ziwei ZHANG, Zhentao LIU, Guoxin LI, authorCompany=null, correspAuthors=Guoxin LI, authorNote=, correspAuthorsNote=, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1318979402671706750, articleId=1318979402243887740, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=钙硅比对水化硅酸钙脱钙过程的影响及机理, columnId=1263922770220560512, journalTitle=硅酸盐学报, columnName=研究论文, runingTitle=null, highlight=null, articleAbstract=

通过水热合成法制备了不同Ca/Si比的水化硅酸钙（C-S-H），并在6 mol/L NH₄Cl溶液中加速脱钙，对不同Ca/Si比C-S-H脱钙前后的化学成分、链结构和微观结构进行分析。结果表明：C-S-H为不规则团聚体形成的凝胶结构。随着Ca/Si比增加，C-S-H中的二聚体和链端基团含量增加，平均聚合度和平均链长减小。脱钙后，C-S-H结构发生解体，硅酸盐链相互交联形成三维网状结构的硅胶，导致C-S-H失去其胶凝性能。

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ZHANG Ziwei (1995-), female, Doctoral candidate. E-mail: zziwei@xauat.edu.cn

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ZHANG Ziwei (1995-), female, Doctoral candidate. E-mail: zziwei@xauat.edu.cn

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张紫薇（1995—），女，博士研究生。

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张紫薇（1995—），女，博士研究生。

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