Article(id=1318977243339150025, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318977205884014990, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20230485, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1688745600000, receivedDateStr=2023-07-08, revisedDate=1690128000000, revisedDateStr=2023-07-24, acceptedDate=null, acceptedDateStr=null, onlineDate=1792398280223, onlineDateStr=2026-10-19, pubDate=1694361600000, pubDateStr=2023-09-11, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792398280223, onlineIssueDateStr=2026-10-19, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792398280223, creator=13701087609, updateTime=1792398280223, updator=13701087609, issue=Issue{id=1318977205884014990, tenantId=1146029695717560320, journalId=1263187385517883426, year='2023', volume='51', issue='12', pageStart='3039', pageEnd='3250', issueExtLink='null', onlineDate='null', pubDate='1703001600000', pubDateStr='2023-12-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1792398271294, creator='13701087609', updateTime=1792399409679, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1318981980671295626, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318977205884014990, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1318981980671295627, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318977205884014990, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=3189, endPage=3195, ext={EN=ArticleExt(id=1318977245184643786, articleId=1318977243339150025, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Preparation and Color Regulation Mechanism of Nb₂O₅ Amorphous Photonic Structural Color Glaze, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=

The blue and cyan amorphous photonic color glazes were prepared with the addition of 2%-7% niobium pentoxide to Na₂O-K₂O-MgO-CaO-Al₂O₃-SiO₂ ceramic glaze. The effect of Nb₂O₅ addition on the glaze color, phase-separated structure and elemental distribution was investigated by UV-Vis reflection spectroscopy, Fourier transform infrared spectroscopy, scanning electron microscope, transmission electron microscope, and the regulation mechanism on the structural color of amorphous photonic was analyzed. The results indicate that the [NbO₄] tetrahedra transforms into [NbO₆] octahedra as the content of Nb₂O₅ increases, which exists as network oxides, causing a decreased viscosity of the glaze melt at high temperatures and an increased size of the phase-separated droplets. Also, a large enrichment of Nb₂O₅ improves the refractive index difference between the two phases, leading to the wavelength of amorphous photonic structural coloration moving to the long-wave direction and a transition of the glaze color from blue to cyan.

, authors=Biao ZHANG¹, Xuanliang HE¹, Zhiwei JIN¹, Yichen WU¹, Fen WANG¹, Hongjie LUO^{1, 2}, Jianfeng ZHU¹, Pei SHI¹, authorsList=Biao ZHANG, Xuanliang HE, Zhiwei JIN, Yichen WU, Fen WANG, Hongjie LUO, Jianfeng ZHU, Pei SHI, authorCompany=null, correspAuthors=Pei SHI, authorNote=, correspAuthorsNote=, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1318977245406941899, articleId=1318977243339150025, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=含Nb₂O₅非晶光子结构色釉的制备及其色彩调控机制, columnId=1263922770220560512, journalTitle=硅酸盐学报, columnName=研究论文, runingTitle=null, highlight=null, articleAbstract=

在Na₂O-K₂O-MgO-CaO-Al₂O₃-SiO₂系陶瓷釉中，通过引入2%~7%（质量分数）的Nb₂O₅，制备出蓝、青色的非晶光子结构色釉。采用紫外-可见反射光谱、Fourier变换红外光谱、扫描电子显微镜、透射电子显微镜等研究Nb₂O₅加入量对釉色、分相结构及元素分布的影响，并揭示其对非晶光子结构色的调控机制。结果表明：随着Nb₂O₅加入量的增多，釉中[NbO₄]四面体转变为[NbO₆]八面体，其作为网络修饰体存在于釉中，使得高温下釉熔体的黏度降低，分相液滴长大。并且，富集于分相液滴中的Nb元素提高了其与基相的相对折射率差，促使非晶光子结构色的波长向长波方向移动，釉色由蓝色向青色发展。

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ZHANG Biao (1990-), male, Ph.D., Lecturer. E-mail: zhangbiao@sust.edu.cn

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ZHANG Biao (1990-), male, Ph.D., Lecturer. E-mail: zhangbiao@sust.edu.cn

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张彪（1990—），男，博士，讲师。

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张彪（1990—），男，博士，讲师。

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