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Article(id=1318976936358035651, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318976874252980746, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20230168, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1679068800000, receivedDateStr=2023-03-18, revisedDate=1683388800000, revisedDateStr=2023-05-07, acceptedDate=null, acceptedDateStr=null, onlineDate=1792398207034, onlineDateStr=2026-10-19, pubDate=1695139200000, pubDateStr=2023-09-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792398207034, onlineIssueDateStr=2026-10-19, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792398207034, creator=13701087609, updateTime=1792398207034, updator=13701087609, issue=Issue{id=1318976874252980746, tenantId=1146029695717560320, journalId=1263187385517883426, year='2023', volume='51', issue='9', pageStart='2119', pageEnd='2516', issueExtLink='null', onlineDate='null', pubDate='1695139200000', pubDateStr='2023-09-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1792398192226, creator='13701087609', updateTime=1792399292764, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1318981490315210817, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318976874252980746, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1318981490315210818, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318976874252980746, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=2306, endPage=2321, ext={EN=ArticleExt(id=1318976936563556548, articleId=1318976936358035651, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Research Progress on Modification of Anodic Current Collectors for Sodium Metal Batteries, columnId=1321890862989169402, journalTitle=Journal of the Chinese Ceramic Society, columnName=Special Issue Innovation of Inorganic Non-Metallic Materials and Technologies to Support “Dual-Carbon” Goal—Review, runingTitle=null, highlight=null, articleAbstract=

The sodium metal anode as an ideal candidate material beyond lithium-ion battery technology has a high theoretical specific capacity (i.e., 1 165 mA·h·g-1), a low redox potential (i.e., -2.71 V vs. standard hydrogen electrode), and low cost. However, the practical application of sodium metal anode involves sodium dendrite growth and infinite volume expansion, leading to a low Coulombic efficiency and a short cycle life, and affecting its development. Recent work have dedicated much effort to solving these problems. This review represented some effective strategies in enhancing the cycling stability of sodium metal anodes, i.e., reducing the local current density of sodium metal electrodes, increasing sodium nucleation sites, and creating appropriate pores in current collectors to alleviate volume expansion. This review also discussed the main problems of sodium metal anodes and summarized the modification strategies of current collectors of electrodeposited sodium metal anodes, i.e., three-dimensional current collector design, doping or defect engineering, introduction of crystal seeds, and buffer layer modification. In addition, the future development aspects of high-safety and high-energy-density sodium metal batteries were also prospected.

, authors=Fang TANG1, Congcong LIU1, Hongyang HUANG1, Yu YAO2, Lin LIU1, Xianhong RUI1, Yan YU2, authorsList=Fang TANG, Congcong LIU, Hongyang HUANG, Yu YAO, Lin LIU, Xianhong RUI, Yan YU, authorCompany=null, correspAuthors=Xianhong RUI, Yan YU, authorNote=

TANG Fang (1994-), female, Ph.D. candidate. E-mail:

, correspAuthorsNote=
RUI Xianhong (1985-), male, Ph.D., Professor; E-mail:
YU Yan (1979-), female, Ph.D., Professor.
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1318976936836186309, articleId=1318976936358035651, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=钠金属电池负极集流体改性的研究进展, columnId=1321890863219856123, journalTitle=硅酸盐学报, columnName=无机非金属材料及技术创新助力实现双碳目标专刊—综合评述, runingTitle=null, highlight=null, articleAbstract=

钠金属负极由于其理论比容量高（1 165 mA·h·g-1）、氧化还原电势低（-2.71 V vs.标准氢电极）和成本低，被认为是超越锂离子电池技术的理想候选材料。然而钠金属负极在实际应用中表现出钠枝晶生长和体积膨胀，导致其Coulomb效率低、循环寿命短等问题，这限制了其进一步发展。针对这些问题，研究者进行了大量工作，发现降低钠金属负极局部电流密度、增加钠成核位点、适当构建集流体孔隙缓解体积膨胀等手段，可以有效提高钠金属负极的循环稳定性。为此，本综述讨论了钠金属负极的主要问题；总结归纳了电沉积钠金属负极集流体的改性策略，包括三维集流体设计，掺杂、缺陷工程，晶种引入，缓冲层修饰；最后对高安全、高比能钠金属电池的未来发展提出展望。

, authors=唐芳1, 刘聪聪1, 黄弘扬1, 姚雨2, 刘琳1, 芮先宏1, 余彦2, authorsList=唐芳, 刘聪聪, 黄弘扬, 姚雨, 刘琳, 芮先宏, 余彦, authorCompany=null, correspAuthors=芮先宏, 余彦, authorNote=

唐芳（1994—），女，博士研究生。

, correspAuthorsNote=
芮先宏（1985—），男，博士，教授；
余彦（1979—），女，博士，教授。
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TANG Fang (1994-), female, Ph.D. candidate. E-mail:

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唐芳（1994—），女，博士研究生。

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唐芳（1994—），女，博士研究生。

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钠金属电池负极集流体改性的研究进展
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唐芳 1 , 刘聪聪 1 , 黄弘扬 1 , 姚雨 2 , 刘琳 1 , 芮先宏 1 , 余彦 2
硅酸盐学报 | 无机非金属材料及技术创新助力实现双碳目标专刊—综合评述 2023,51(9): 2306-2321
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硅酸盐学报 |无机非金属材料及技术创新助力实现双碳目标专刊—综合评述 2023 , 51 (9) : 2306 -2321
钠金属电池负极集流体改性的研究进展
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唐芳1 , 刘聪聪1, 黄弘扬1, 姚雨2, 刘琳1, 芮先宏1 , 余彦2
作者信息
  • 1.广东工业大学材料与能源学院，广州 510080
  • 2.中国科学技术大学材料科学与工程系，合肥 230026
通讯作者:
芮先宏（1985—），男，博士，教授；
余彦（1979—），女，博士，教授。
作者简介:

唐芳（1994—），女，博士研究生。

Research Progress on Modification of Anodic Current Collectors for Sodium Metal Batteries
Fang TANG1 , Congcong LIU1, Hongyang HUANG1, Yu YAO2, Lin LIU1, Xianhong RUI1 , Yan YU2
Affiliations
  • 1.School of Materials and Energy, Guangdong University of Technology, Guangzhou 510080, China
  • 2.Department of Materials Science and Engineering, University of Science and Technology of China, Hefei 230026, China
    • Corresponding Author:
    RUI Xianhong (1985-), male, Ph.D., Professor; E-mail:
    YU Yan (1979-), female, Ph.D., Professor.

    TANG Fang (1994-), female, Ph.D. candidate. E-mail:

出版时间: 2023-09-20 doi: 10.14062/j.issn.0454-5648.20230168
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钠金属负极由于其理论比容量高（1 165 mA·h·g-1）、氧化还原电势低（-2.71 V vs.标准氢电极）和成本低，被认为是超越锂离子电池技术的理想候选材料。然而钠金属负极在实际应用中表现出钠枝晶生长和体积膨胀，导致其Coulomb效率低、循环寿命短等问题，这限制了其进一步发展。针对这些问题，研究者进行了大量工作，发现降低钠金属负极局部电流密度、增加钠成核位点、适当构建集流体孔隙缓解体积膨胀等手段，可以有效提高钠金属负极的循环稳定性。为此，本综述讨论了钠金属负极的主要问题；总结归纳了电沉积钠金属负极集流体的改性策略，包括三维集流体设计，掺杂、缺陷工程，晶种引入，缓冲层修饰；最后对高安全、高比能钠金属电池的未来发展提出展望。

钠金属电池  /  钠金属负极  /  集流体

The sodium metal anode as an ideal candidate material beyond lithium-ion battery technology has a high theoretical specific capacity (i.e., 1 165 mA·h·g-1), a low redox potential (i.e., -2.71 V vs. standard hydrogen electrode), and low cost. However, the practical application of sodium metal anode involves sodium dendrite growth and infinite volume expansion, leading to a low Coulombic efficiency and a short cycle life, and affecting its development. Recent work have dedicated much effort to solving these problems. This review represented some effective strategies in enhancing the cycling stability of sodium metal anodes, i.e., reducing the local current density of sodium metal electrodes, increasing sodium nucleation sites, and creating appropriate pores in current collectors to alleviate volume expansion. This review also discussed the main problems of sodium metal anodes and summarized the modification strategies of current collectors of electrodeposited sodium metal anodes, i.e., three-dimensional current collector design, doping or defect engineering, introduction of crystal seeds, and buffer layer modification. In addition, the future development aspects of high-safety and high-energy-density sodium metal batteries were also prospected.

sodium metal battery  /  sodium metal anode  /  current collector
唐芳, 刘聪聪, 黄弘扬, 姚雨, 刘琳, 芮先宏, 余彦. 钠金属电池负极集流体改性的研究进展. 硅酸盐学报, 2023 , 51 (9) : 2306 -2321 . DOI: 10.14062/j.issn.0454-5648.20230168
Fang TANG, Congcong LIU, Hongyang HUANG, Yu YAO, Lin LIU, Xianhong RUI, Yan YU. Research Progress on Modification of Anodic Current Collectors for Sodium Metal Batteries[J]. Journal of the Chinese Ceramic Society, 2023 , 51 (9) : 2306 -2321 . DOI: 10.14062/j.issn.0454-5648.20230168
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  • 国家自然科学基金(52222210; 51925207; U1910210; 52161145101)
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2023年第51卷第9期
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doi: 10.14062/j.issn.0454-5648.20230168
  • 接收时间：2023-03-18
  • 首发时间：2026-10-19
  • 出版时间：2023-09-20
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  • 收稿日期：2023-03-18
  • 修回日期：2023-05-07
基金
国家自然科学基金(52222210; 51925207; U1910210; 52161145101)
作者信息
    1.广东工业大学材料与能源学院，广州 510080
    2.中国科学技术大学材料科学与工程系，合肥 230026

通讯作者:

芮先宏（1985—），男，博士，教授；
余彦（1979—），女，博士，教授。
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https://castjournals.cast.org.cn/joweb/gsyxb/CN/10.14062/j.issn.0454-5648.20230168
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2种不同金属材料的力学参数
科
Family		 属数
Number of
genus		 种数
Number of
species		 占总种数比例
Percentage of
total species (%)		 属
Genus		 种数
Number of
species		 占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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