Article(id=1318976881500729872, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318976874252980746, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20230257, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1681833600000, receivedDateStr=2023-04-19, revisedDate=1682870400000, revisedDateStr=2023-05-01, acceptedDate=null, acceptedDateStr=null, onlineDate=1792398193955, onlineDateStr=2026-10-19, pubDate=1695139200000, pubDateStr=2023-09-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792398193955, onlineIssueDateStr=2026-10-19, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792398193955, creator=13701087609, updateTime=1792398193955, updator=13701087609, issue=Issue{id=1318976874252980746, tenantId=1146029695717560320, journalId=1263187385517883426, year='2023', volume='51', issue='9', pageStart='2119', pageEnd='2516', issueExtLink='null', onlineDate='null', pubDate='1695139200000', pubDateStr='2023-09-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1792398192226, creator='13701087609', updateTime=1792399292764, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1318981490315210817, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318976874252980746, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1318981490315210818, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318976874252980746, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=2214, endPage=2227, ext={EN=ArticleExt(id=1318976881710445073, articleId=1318976881500729872, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Challenges and Strategies for Low Cost Cobalt-Free High-Nickel Cathode Materials, columnId=1321890862989169402, journalTitle=Journal of the Chinese Ceramic Society, columnName=Special Issue Innovation of Inorganic Non-Metallic Materials and Technologies to Support “Dual-Carbon” Goal—Review, runingTitle=null, highlight=null, articleAbstract=

High-nickel cathode materials are one of the most promising candidates for lithium-ion batteries with superior comprehensive performance. These materials can achieve higher energy density than conventional lithium cobalt oxide, and have lower cost and high environmental benignity. To reduce the cost further to meet the growing energy demand, the development of cobalt-free high-nickel cathode materials becomes one of research challengess. This review discussed the feasibility of cobalt removal and the key challenges for cobalt-free high-nickel cathodes. The modification strategies were summarized based on recent related studies. In addition, the future research direction of cobalt-free high-nickel cathodes was also proposed.

, authors=Chenxi SONG, Yang SHEN, authorsList=Chenxi SONG, Yang SHEN, authorCompany=null, correspAuthors=Yang SHEN, authorNote=

SONG Chenxi (1998-), female, Ph.D., candidate. E-mail:

, correspAuthorsNote=
SHEN Yang (1980-), male, Ph.D., Professor. E-mail:
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高镍正极材料是一类综合性能优越的锂离子电池正极材料,它不仅可以达到比传统钴酸锂更高的能量密度,而且成本更低、更加环保,在动力电池市场具有巨大优势。为了进一步降低储能器件成本来适应与日俱增的能源需求,开发无钴高镍正极材料成为新的研究焦点。本文从镍酸锂正极的本征性质出发,论述去钴化的可行性与无钴高镍正极的重点挑战,总结目前学界已有的实现策略,最后对无钴高镍正极的发展方向作出展望。

, authors=宋晨曦, 沈洋, authorsList=宋晨曦, 沈洋, authorCompany=null, correspAuthors=沈洋, authorNote=

宋晨曦(1998—),女,博士研究生。

, correspAuthorsNote=
沈洋(1980—),男,博士,教授。
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SONG Chenxi (1998-), female, Ph.D., candidate. E-mail:

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低成本无钴高镍正极的挑战与策略
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宋晨曦 , 沈洋
硅酸盐学报 | 无机非金属材料及技术创新助力实现双碳目标专刊—综合评述 2023,51(9): 2214-2227
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硅酸盐学报 |无机非金属材料及技术创新助力实现双碳目标专刊—综合评述 2023 , 51 (9) : 2214 -2227
低成本无钴高镍正极的挑战与策略
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宋晨曦 , 沈洋
作者信息
  • 清华大学材料学院,北京 100084
通讯作者:
沈洋(1980—),男,博士,教授。
作者简介:

宋晨曦(1998—),女,博士研究生。

Challenges and Strategies for Low Cost Cobalt-Free High-Nickel Cathode Materials
Chenxi SONG , Yang SHEN
Affiliations
  • School of Materials Science and Engineering, Tsinghua University, Beijing 100084, China
  • Corresponding Author:
    SHEN Yang (1980-), male, Ph.D., Professor. E-mail:

    SONG Chenxi (1998-), female, Ph.D., candidate. E-mail:

出版时间: 2023-09-20 doi: 10.14062/j.issn.0454-5648.20230257
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高镍正极材料是一类综合性能优越的锂离子电池正极材料,它不仅可以达到比传统钴酸锂更高的能量密度,而且成本更低、更加环保,在动力电池市场具有巨大优势。为了进一步降低储能器件成本来适应与日俱增的能源需求,开发无钴高镍正极材料成为新的研究焦点。本文从镍酸锂正极的本征性质出发,论述去钴化的可行性与无钴高镍正极的重点挑战,总结目前学界已有的实现策略,最后对无钴高镍正极的发展方向作出展望。

无钴  /  高镍正极  /  锂离子电池  /  过渡金属氧化物

High-nickel cathode materials are one of the most promising candidates for lithium-ion batteries with superior comprehensive performance. These materials can achieve higher energy density than conventional lithium cobalt oxide, and have lower cost and high environmental benignity. To reduce the cost further to meet the growing energy demand, the development of cobalt-free high-nickel cathode materials becomes one of research challengess. This review discussed the feasibility of cobalt removal and the key challenges for cobalt-free high-nickel cathodes. The modification strategies were summarized based on recent related studies. In addition, the future research direction of cobalt-free high-nickel cathodes was also proposed.

cobalt-free  /  high-nickel cathodes  /  lithium-ion batteries  /  transitional metal oxide
宋晨曦, 沈洋. 低成本无钴高镍正极的挑战与策略. 硅酸盐学报, 2023 , 51 (9) : 2214 -2227 . DOI: 10.14062/j.issn.0454-5648.20230257
Chenxi SONG, Yang SHEN. Challenges and Strategies for Low Cost Cobalt-Free High-Nickel Cathode Materials[J]. Journal of the Chinese Ceramic Society, 2023 , 51 (9) : 2214 -2227 . DOI: 10.14062/j.issn.0454-5648.20230257
  • 国家自然科学基金(52027817)
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2023年第51卷第9期
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doi: 10.14062/j.issn.0454-5648.20230257
  • 接收时间:2023-04-19
  • 首发时间:2026-10-19
  • 出版时间:2023-09-20
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  • 收稿日期:2023-04-19
  • 修回日期:2023-05-01
基金
国家自然科学基金(52027817)
作者信息
    清华大学材料学院,北京 100084

通讯作者:

沈洋(1980—),男,博士,教授。
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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