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Article(id=1318974606959035343, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318974603884606018, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20230160, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1678896000000, receivedDateStr=2023-03-16, revisedDate=1681056000000, revisedDateStr=2023-04-10, acceptedDate=null, acceptedDateStr=null, onlineDate=1792397651661, onlineDateStr=2026-10-19, pubDate=1683561600000, pubDateStr=2023-05-09, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792397651661, onlineIssueDateStr=2026-10-19, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792397651661, creator=13701087609, updateTime=1792397651661, updator=13701087609, issue=Issue{id=1318974603884606018, tenantId=1146029695717560320, journalId=1263187385517883426, year='2023', volume='51', issue='8', pageStart='1883', pageEnd='2118', issueExtLink='null', onlineDate='null', pubDate='1692460800000', pubDateStr='2023-08-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1792397650929, creator='13701087609', updateTime=1792399225992, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1318981210261541260, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318974603884606018, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1318981210261541261, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318974603884606018, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1885, endPage=1897, ext={EN=ArticleExt(id=1318974608603202512, articleId=1318974606959035343, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Effect of Different Types of Converter Steel Slag on Sintering and Properties of High-Ferrite Multi-Phased Clinker, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=

Steel slag multi-phased clinker is a cement clinker directly calcined by granular steel slag, so the physical and chemical characteristics of steel slag are very important to the sintering of multi-phased clinker. In order to explore the influence mechanism of different types of converter steel slag on the sintering and properties of multi-phased clinker, three kinds of multi-phased clinker were prepared by using hot smoldering slag, roller slag and pressurized hot smoldering slag at 1 420 ℃. The results show that the multi-phased clinker minerals with different steel slag were mainly C3S, C2S and C4AF, the higher iron content in steel slag resulted in the Al transformed into ferrite minerals, showing a typical high ferrite (Ferrite content > 18%, mass fraction) characteristic. The differences of chemical composition, mineral composition and particle size distribution among different steel slag had different influences on the formation and development of mineral crystals and properties of multi-phased clinker. The content of water-soluble chromium (VI) in multi-phased clinker was positively correlated with the content of Cr2O3 and alkali in steel slag, and the higher the content of fine particles in steel slag, the more easily Cr was oxidized into water-soluble high valence chromate in the sintering process.

, authors=Deqiang ZHAO1, 2, Weiguo SHEN1, 2, 3, Guiming WANG1, 2, Wensheng ZHANG4, Zhicheng ZHAO1, 2, Zhen YU1, 2, Qinglin ZHAO1, 2, authorsList=Deqiang ZHAO, Weiguo SHEN, Guiming WANG, Wensheng ZHANG, Zhicheng ZHAO, Zhen YU, Qinglin ZHAO, authorCompany=null, correspAuthors=Weiguo SHEN, authorNote=

ZHAO Deqiang (1995-), male, Doctoral candidate. E-mail:

, correspAuthorsNote=
SHEN Weiguo (1971-), male, Ph.D., Professor. E-mail:
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钢渣分相熟料是直接利用粒状钢渣煅烧的水泥熟料，因此钢渣自身的物理化学特性对分相熟料的烧成至关重要。为探究不同种类转炉钢渣对分相熟料烧成与性能的影响机制，采用热焖渣、滚筒渣和有压热焖渣在1 420 ℃制备了3种钢渣分相熟料。结果表明：不同种类转炉钢渣分相熟料矿物以C3S、C2S和C4AF为主，钢渣中的铁质成分含量高，使分相熟料中的Al基本转化为铁铝酸盐矿物（Ferrite），呈现典型的高铁（Ferrite含量>18%，质量分数）特征。不同种类转炉钢渣间化学成分、矿物组成及粒径分布的差异，对分相熟料矿物晶体的形成发育和性能产生了不同的影响。分相熟料中水溶性铬（VI）含量与钢渣中的Cr2O3和碱含量呈正相关，且钢渣中的细颗粒含量越高，Cr越容易在烧成过程中被氧化成水溶性高价铬酸盐。

, authors=赵德强1, 2, 沈卫国1, 2, 3, 王桂明1, 2, 张文生4, 赵志成1, 2, 余震1, 2, 赵青林1, 2, authorsList=赵德强, 沈卫国, 王桂明, 张文生, 赵志成, 余震, 赵青林, authorCompany=null, correspAuthors=沈卫国, authorNote=

赵德强（1995—），男，博士研究生。

, correspAuthorsNote=
沈卫国（1971—），男，博士，教授。
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ZHAO Deqiang (1995-), male, Doctoral candidate. E-mail:

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ZHAO Deqiang (1995-), male, Doctoral candidate. E-mail:

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赵德强（1995—），男，博士研究生。

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不同种类转炉钢渣对高铁分相熟料烧成与性能的影响
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赵德强 1, 2 , 沈卫国 1, 2, 3 , 王桂明 1, 2 , 张文生 4 , 赵志成 1, 2 , 余震 1, 2 , 赵青林 1, 2
硅酸盐学报 | 研究论文 2023,51(8): 1885-1897
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硅酸盐学报 |研究论文 2023 , 51 (8) : 1885 -1897
不同种类转炉钢渣对高铁分相熟料烧成与性能的影响
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赵德强1, 2 , 沈卫国1, 2, 3 , 王桂明1, 2, 张文生4, 赵志成1, 2, 余震1, 2, 赵青林1, 2
作者信息
  • 1.武汉理工大学，硅酸盐建筑材料国家重点实验室，武汉 430070
  • 2.武汉理工大学材料科学与工程学院，武汉 430070
  • 3.大宗固废综合利用与绿色建材襄阳市重点实验室，湖北 襄阳 441022
  • 4.中国建筑材料科学研究总院有限公司，绿色建筑材料国家重点实验室，北京 100024
通讯作者:
沈卫国（1971—），男，博士，教授。
作者简介:

赵德强（1995—），男，博士研究生。

Effect of Different Types of Converter Steel Slag on Sintering and Properties of High-Ferrite Multi-Phased Clinker
Deqiang ZHAO1, 2 , Weiguo SHEN1, 2, 3 , Guiming WANG1, 2, Wensheng ZHANG4, Zhicheng ZHAO1, 2, Zhen YU1, 2, Qinglin ZHAO1, 2
Affiliations
  • 1.State Key Laboratory of Silicate Materials for Architecture, Wuhan University of Technology, Wuhan 430070, China
  • 2.School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, China
  • 3.Key Laboratory of Comprehensive Utilization of Bulk Solid Waste and Green Building Materials, Xiangyang 441022, Hubei, China
  • 4.State Key Laboratory of Green Building Materials, China Building Materials Academy, Beijing 100024, China
    • Corresponding Author:
    SHEN Weiguo (1971-), male, Ph.D., Professor. E-mail:

    ZHAO Deqiang (1995-), male, Doctoral candidate. E-mail:

出版时间: 2023-05-09 doi: 10.14062/j.issn.0454-5648.20230160
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钢渣分相熟料是直接利用粒状钢渣煅烧的水泥熟料，因此钢渣自身的物理化学特性对分相熟料的烧成至关重要。为探究不同种类转炉钢渣对分相熟料烧成与性能的影响机制，采用热焖渣、滚筒渣和有压热焖渣在1 420 ℃制备了3种钢渣分相熟料。结果表明：不同种类转炉钢渣分相熟料矿物以C3S、C2S和C4AF为主，钢渣中的铁质成分含量高，使分相熟料中的Al基本转化为铁铝酸盐矿物（Ferrite），呈现典型的高铁（Ferrite含量>18%，质量分数）特征。不同种类转炉钢渣间化学成分、矿物组成及粒径分布的差异，对分相熟料矿物晶体的形成发育和性能产生了不同的影响。分相熟料中水溶性铬（VI）含量与钢渣中的Cr2O3和碱含量呈正相关，且钢渣中的细颗粒含量越高，Cr越容易在烧成过程中被氧化成水溶性高价铬酸盐。

转炉钢渣  /  高铁  /  分相熟料  /  烧成  /  性能

Steel slag multi-phased clinker is a cement clinker directly calcined by granular steel slag, so the physical and chemical characteristics of steel slag are very important to the sintering of multi-phased clinker. In order to explore the influence mechanism of different types of converter steel slag on the sintering and properties of multi-phased clinker, three kinds of multi-phased clinker were prepared by using hot smoldering slag, roller slag and pressurized hot smoldering slag at 1 420 ℃. The results show that the multi-phased clinker minerals with different steel slag were mainly C3S, C2S and C4AF, the higher iron content in steel slag resulted in the Al transformed into ferrite minerals, showing a typical high ferrite (Ferrite content > 18%, mass fraction) characteristic. The differences of chemical composition, mineral composition and particle size distribution among different steel slag had different influences on the formation and development of mineral crystals and properties of multi-phased clinker. The content of water-soluble chromium (VI) in multi-phased clinker was positively correlated with the content of Cr2O3 and alkali in steel slag, and the higher the content of fine particles in steel slag, the more easily Cr was oxidized into water-soluble high valence chromate in the sintering process.

converter steel slag  /  high-ferrite phase  /  multi-phased clinker  /  sintering  /  properties
赵德强, 沈卫国, 王桂明, 张文生, 赵志成, 余震, 赵青林. 不同种类转炉钢渣对高铁分相熟料烧成与性能的影响. 硅酸盐学报, 2023 , 51 (8) : 1885 -1897 . DOI: 10.14062/j.issn.0454-5648.20230160
Deqiang ZHAO, Weiguo SHEN, Guiming WANG, Wensheng ZHANG, Zhicheng ZHAO, Zhen YU, Qinglin ZHAO. Effect of Different Types of Converter Steel Slag on Sintering and Properties of High-Ferrite Multi-Phased Clinker[J]. Journal of the Chinese Ceramic Society, 2023 , 51 (8) : 1885 -1897 . DOI: 10.14062/j.issn.0454-5648.20230160
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  • 国家自然科学基金面上项目(51972247)
  • 广西重点研发计划(AB18126035)
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2023年第51卷第8期
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doi: 10.14062/j.issn.0454-5648.20230160
  • 接收时间：2023-03-16
  • 首发时间：2026-10-19
  • 出版时间：2023-05-09
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  • 收稿日期：2023-03-16
  • 修回日期：2023-04-10
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国家自然科学基金面上项目(51972247)
广西重点研发计划(AB18126035)
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    1.武汉理工大学，硅酸盐建筑材料国家重点实验室，武汉 430070
    2.武汉理工大学材料科学与工程学院，武汉 430070
    3.大宗固废综合利用与绿色建材襄阳市重点实验室，湖北 襄阳 441022
    4.中国建筑材料科学研究总院有限公司，绿色建筑材料国家重点实验室，北京 100024

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沈卫国（1971—），男，博士，教授。
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2种不同金属材料的力学参数
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Family		 属数
Number of
genus		 种数
Number of
species		 占总种数比例
Percentage of
total species (%)		 属
Genus		 种数
Number of
species		 占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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