Article(id=1318974544405185014, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318974513019207979, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20221089, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1671379200000, receivedDateStr=2022-12-19, revisedDate=1672675200000, revisedDateStr=2023-01-03, acceptedDate=null, acceptedDateStr=null, onlineDate=1792397636748, onlineDateStr=2026-10-19, pubDate=1685289600000, pubDateStr=2023-05-29, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792397636748, onlineIssueDateStr=2026-10-19, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792397636748, creator=13701087609, updateTime=1792397636748, updator=13701087609, issue=Issue{id=1318974513019207979, tenantId=1146029695717560320, journalId=1263187385517883426, year='2023', volume='51', issue='7', pageStart='1649', pageEnd='1882', issueExtLink='null', onlineDate='null', pubDate='1689782400000', pubDateStr='2023-07-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1792397629265, creator='13701087609', updateTime=1792399256269, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1318981337223119779, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318974513019207979, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1318981337223119780, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318974513019207979, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1800, endPage=1810, ext={EN=ArticleExt(id=1318974544862364151, articleId=1318974544405185014, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Phase Structure Regulation and Photocatalytic Degradation Properties of α/β-Bi2O3 Films Prepared by Plasma Spraying-Chemical Vapor Deposition, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=

To obtain easily recycled photocatalyst and improve the reusing practicability for waste water treatment, Bi2O3 films were prepared by a plasma spray-chemical vapor deposition method , and the effects of deposition temperature and heat-treatment temperature on the morphology and phase composition of Bi2O3 films were investigated. The morphology and composition of the films were characterized by field-emission scanning electron microscopy, X-ray diffraction and high-resolution transmission electron microscopy. The band gaps of α/β-Bi2O3 at different heat treatment temperatures were determined by ultraviolet-visable diffuse reflectance spectrometry. The results show that the deposition temperature and heat-treatment temperature affect the microstructure of Bi2O3 films and the proportion of α and β phases, while the influence of deposition temperature is more dominant rather than that of heat-treatment temperature. The proportion of β phase gradually converts to α phase and the band gap of α-Bi2O3 and β-Bi2O3 increases when the heat-treatment temperature increases. The Bi2O3 films exhibit a good photocatalytic degradation performance for Methyl Orange and Bisphenol A.

, authors=Zhenyu WANG, Yancai LIU, Kun CHEN, Jianghao QIAO, Xiaowei LI, authorsList=Zhenyu WANG, Yancai LIU, Kun CHEN, Jianghao QIAO, Xiaowei LI, authorCompany=null, correspAuthors=Jianghao QIAO, authorNote=

WANG Zhenyu (2002-), male, Undergraduate. E-mail:

, correspAuthorsNote=
QIAO Jianghao (1984-), male, Ph.D., Lecturer. E-mail:
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采用等离子喷涂-化学气相沉积法制备Bi2O3薄膜,并研究了沉积温度和热处理温度对于Bi2O3薄膜形貌和成分的影响。用场发射扫描电子显微镜、X射线衍射仪、高分辨率透射电子显微镜对该薄膜形貌和成分进行了表征,通过紫外-可见光漫反射光谱仪研究了不同热处理温度下α/β-Bi2O3禁带宽度的变化。结果表明:沉积温度和热处理温度影响Bi2O3薄膜的微观形貌,同时影响α和β两相的相比例,但沉积温度的影响显著大于热处理温度;随着热处理温度升高,β相转化为α相的比例越来越高,α-Bi2O3和β-Bi2O3的禁带宽度都有所增加;最后,通过对甲基橙和双酚A的降解证明了Bi2O3薄膜具有良好的光催化降解性能。

, authors=王振宇, 刘燕才, 陈琨, 乔江浩, 李晓伟, authorsList=王振宇, 刘燕才, 陈琨, 乔江浩, 李晓伟, authorCompany=null, correspAuthors=乔江浩, authorNote=

王振宇(2002—),男,本科生。

, correspAuthorsNote=
乔江浩(1984—),男,博士,讲师。
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王振宇 , 刘燕才 , 陈琨 , 乔江浩 , 李晓伟
硅酸盐学报 | 研究论文 2023,51(7): 1800-1810
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硅酸盐学报 |研究论文 2023 , 51 (7) : 1800 -1810
等离子喷涂-化学气相沉积制备α/β-Bi2O3薄膜的相结构调控和光催化降解性能
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王振宇 , 刘燕才, 陈琨, 乔江浩 , 李晓伟
作者信息
  • 中国矿业大学材料与物理学院,江苏 徐州 221116
通讯作者:
乔江浩(1984—),男,博士,讲师。
作者简介:

王振宇(2002—),男,本科生。

Phase Structure Regulation and Photocatalytic Degradation Properties of α/β-Bi2O3 Films Prepared by Plasma Spraying-Chemical Vapor Deposition
Zhenyu WANG , Yancai LIU, Kun CHEN, Jianghao QIAO , Xiaowei LI
Affiliations
  • School of Materials Science and Physics, China University of Mining and Technology, Xuzhou 221116, Jiangsu, China
  • Corresponding Author:
    QIAO Jianghao (1984-), male, Ph.D., Lecturer. E-mail:

    WANG Zhenyu (2002-), male, Undergraduate. E-mail:

出版时间: 2023-05-29 doi: 10.14062/j.issn.0454-5648.20221089
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采用等离子喷涂-化学气相沉积法制备Bi2O3薄膜,并研究了沉积温度和热处理温度对于Bi2O3薄膜形貌和成分的影响。用场发射扫描电子显微镜、X射线衍射仪、高分辨率透射电子显微镜对该薄膜形貌和成分进行了表征,通过紫外-可见光漫反射光谱仪研究了不同热处理温度下α/β-Bi2O3禁带宽度的变化。结果表明:沉积温度和热处理温度影响Bi2O3薄膜的微观形貌,同时影响α和β两相的相比例,但沉积温度的影响显著大于热处理温度;随着热处理温度升高,β相转化为α相的比例越来越高,α-Bi2O3和β-Bi2O3的禁带宽度都有所增加;最后,通过对甲基橙和双酚A的降解证明了Bi2O3薄膜具有良好的光催化降解性能。

氧化铋  /  薄膜  /  等离子喷涂  /  化学气相沉积  /  光催化降解

To obtain easily recycled photocatalyst and improve the reusing practicability for waste water treatment, Bi2O3 films were prepared by a plasma spray-chemical vapor deposition method , and the effects of deposition temperature and heat-treatment temperature on the morphology and phase composition of Bi2O3 films were investigated. The morphology and composition of the films were characterized by field-emission scanning electron microscopy, X-ray diffraction and high-resolution transmission electron microscopy. The band gaps of α/β-Bi2O3 at different heat treatment temperatures were determined by ultraviolet-visable diffuse reflectance spectrometry. The results show that the deposition temperature and heat-treatment temperature affect the microstructure of Bi2O3 films and the proportion of α and β phases, while the influence of deposition temperature is more dominant rather than that of heat-treatment temperature. The proportion of β phase gradually converts to α phase and the band gap of α-Bi2O3 and β-Bi2O3 increases when the heat-treatment temperature increases. The Bi2O3 films exhibit a good photocatalytic degradation performance for Methyl Orange and Bisphenol A.

bismuth trioxide  /  film  /  plasma spraying  /  chemical vapor deposition  /  photocatalytic degradation
王振宇, 刘燕才, 陈琨, 乔江浩, 李晓伟. 等离子喷涂-化学气相沉积制备α/β-Bi2O3薄膜的相结构调控和光催化降解性能. 硅酸盐学报, 2023 , 51 (7) : 1800 -1810 . DOI: 10.14062/j.issn.0454-5648.20221089
Zhenyu WANG, Yancai LIU, Kun CHEN, Jianghao QIAO, Xiaowei LI. Phase Structure Regulation and Photocatalytic Degradation Properties of α/β-Bi2O3 Films Prepared by Plasma Spraying-Chemical Vapor Deposition[J]. Journal of the Chinese Ceramic Society, 2023 , 51 (7) : 1800 -1810 . DOI: 10.14062/j.issn.0454-5648.20221089
  • 徐州基础研究计划(KC21015)
  • 国家自然科学基金面上项目(52175204)
  • 江苏省大学生科研创新项目(202210290366H)
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2023年第51卷第7期
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doi: 10.14062/j.issn.0454-5648.20221089
  • 接收时间:2022-12-19
  • 首发时间:2026-10-19
  • 出版时间:2023-05-29
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  • 收稿日期:2022-12-19
  • 修回日期:2023-01-03
基金
徐州基础研究计划(KC21015)
国家自然科学基金面上项目(52175204)
江苏省大学生科研创新项目(202210290366H)
作者信息
    中国矿业大学材料与物理学院,江苏 徐州 221116

通讯作者:

乔江浩(1984—),男,博士,讲师。
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2种不同金属材料的力学参数
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属
Genus
种数
Number of
species
占总种数比例
Percentage of total
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鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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