Article(id=1318974525392404880, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318974513019207979, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20221068, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1670688000000, receivedDateStr=2022-12-11, revisedDate=1677513600000, revisedDateStr=2023-02-28, acceptedDate=null, acceptedDateStr=null, onlineDate=1792397632215, onlineDateStr=2026-10-19, pubDate=1686153600000, pubDateStr=2023-06-08, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792397632215, onlineIssueDateStr=2026-10-19, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792397632215, creator=13701087609, updateTime=1792397632215, updator=13701087609, issue=Issue{id=1318974513019207979, tenantId=1146029695717560320, journalId=1263187385517883426, year='2023', volume='51', issue='7', pageStart='1649', pageEnd='1882', issueExtLink='null', onlineDate='null', pubDate='1689782400000', pubDateStr='2023-07-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1792397629265, creator='13701087609', updateTime=1792399256269, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1318981337223119779, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318974513019207979, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1318981337223119780, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318974513019207979, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1733, endPage=1745, ext={EN=ArticleExt(id=1318974525606314385, articleId=1318974525392404880, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Carbon Nanotubes Interspersed with ZIF-67-Derived Nickel-Cobalt-Manganese-Selenides and Their Electrochemical Properties, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=
Supercapacitors have a wide range of potential applications in new energy storage and electric cars due to their high capacity, high power density, and extended cycle life, and the electrode materials are a key to enhancing the supercapacitor performance. NiCoMnSe electrode materials were prepared by a simple low-temperature hydrothermal reaction method and a heat-treatment selenization method using ZIF-67 as a template. The optimum electrochemical performance was obtained via adding carbon nanotube (CNT) or graphene oxide (GO) to the ZIF-67 template. The results show that the optimum NiCoMnSe/CNT electrode has a specific capacitance of 624.0 F/g at 1 A/g and a multiplicative performance of 90.1% at 10 A/g. The capacity retention rate is 88% at 15 A/g for 1 000 cycles. This superior capacitive performance is attributed to the presence of CNT introducing additional mesopores around NiCoMnSe, thus enhancing the contact between the electrolyte and the active material. The NiCoMnSe/CNT/activated carbon device exhibits a high energy density (43.3 W·h/kg) at a power density of 800 W/kg and a good capacity retention (i.e., 91.4% after 1 000 cycles) due to the asymmetric nature of the supercapacitor.
, authors=Jiahong ZHENG, Xin BAI, authorsList=Jiahong ZHENG, Xin BAI, authorCompany=null, correspAuthors=null, authorNote=
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超级电容器具有容量大、功率密度高、循环寿命长的优点,在新能源存储和电动汽车等领域具有广泛的应用前景,而电极材料是提高超级电容器性能的关键。以ZIF-67为模板,通过简便的低温水热反应法以及热处理硒化法,制备了NiCoMnSe电极材料,并通过往ZIF-67模板中添加碳纳米管(CNT)或者氧化石墨烯(GO)来达到最佳的电化学性能。结果表明:最佳的NiCoMnSe/CNT电极在1 A/g下的比电容为624.0 F/g,在10 A/g时的倍率性能为90.1%。15 A/g下循环1 000次的容量保持率为88%。这种优异的电容性能归功于CNT的存在在NiCoMnSe周围引入了额外的介孔,加强了电解质与活性材料之间的接触。由于超级电容器的非对称性,NiCoMnSe/CNT//活性炭器件在800 W/kg的功率密度下表现出较高的能量密度(43.3 W·h/kg),并具有良好的容量保持率(1 000次循环后保持91.4%)。
, authors=郑佳红, 白昕, authorsList=郑佳红, 白昕, authorCompany=null, correspAuthors=null, authorNote=
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郑佳红(1983—),女,博士,副教授。
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郑佳红(1983—),女,博士,副教授。
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