Article(id=1318974513841291564, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318974513019207979, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20230129, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1677945600000, receivedDateStr=2023-03-05, revisedDate=1679846400000, revisedDateStr=2023-03-27, acceptedDate=null, acceptedDateStr=null, onlineDate=1792397629461, onlineDateStr=2026-10-19, pubDate=1686240000000, pubDateStr=2023-06-09, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792397629461, onlineIssueDateStr=2026-10-19, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792397629461, creator=13701087609, updateTime=1792397629461, updator=13701087609, issue=Issue{id=1318974513019207979, tenantId=1146029695717560320, journalId=1263187385517883426, year='2023', volume='51', issue='7', pageStart='1649', pageEnd='1882', issueExtLink='null', onlineDate='null', pubDate='1689782400000', pubDateStr='2023-07-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1792397629265, creator='13701087609', updateTime=1792399256269, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1318981337223119779, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318974513019207979, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1318981337223119780, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318974513019207979, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1649, endPage=1659, ext={EN=ArticleExt(id=1318974515229606189, articleId=1318974513841291564, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Impact of Acid Ether Ratio of Polycarboxylate Ether on Early Strength Enhancement of Calcium Silicate Hydrate Seed, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=

Adding calcium silicate hydrate seed-polycarboxylate ether (C-S-Hs-PCE) to cement-based materials can effectively improve the early strength. C-S-Hs-PCE can provide nucleation sites for the formation of a hydration product C-S-H gel, effectively promoting the generation of the C-S-H gel, and accelerating the process of cement hydration. The acid-ether ratio is an important structural parameter of comb-type PCE molecules, having an impact on the synthesis and early strength enhancement of C-S-Hs-PCE. This paper investigated the effect of acid-ether ratio on the particle size of C-S-Hs-PCE and the early strength of cement-based materials by using dynamic light scattering (DLS) particle size analysis, total organic carbon analysis, X-ray diffraction, low-field time-domain nuclear magnetic resonance, scanning electronic microscopy, isothermal calorimetry, and compressive strength tests, respectively. The results show that the C-S-Hs-PCE formed at a high acid-ether ratio PCE has a smaller particle size, which is more conducive to promoting the hydration of the silicate phase and the generation of calcium hydroxide and C-S-H gel, thereby accelerating the hydration of the paste, reducing the total porosity of mortar, and improving the early compressive strength of mortar, especially within 24 h.

, authors=Fengzhen LEI^{1, 2, 3}, Lei LEI^{1, 2, 3}, Yangyang KANG^{1, 2, 3}, Caijun SHI^{1, 2, 3}, authorsList=Fengzhen LEI, Lei LEI, Yangyang KANG, Caijun SHI, authorCompany=null, correspAuthors=Caijun SHI, authorNote=, correspAuthorsNote=, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1318974515498041646, articleId=1318974513841291564, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=聚羧酸减水剂的酸醚比对水化硅酸钙晶种早强作用的影响, columnId=1263922770220560512, journalTitle=硅酸盐学报, columnName=研究论文, runingTitle=null, highlight=null, articleAbstract=

在水泥基材料中加入水化硅酸钙晶种-聚羧酸减水剂（C-S-Hs-PCE）可以有效提高早期强度。C-S-Hs-PCE能够为水化产物C-S-H凝胶提供成核位点，促进C-S-H凝胶生成，从而加快水泥水化进程。酸醚比是梳型PCE的一个重要结构参数，对C-S-Hs-PCE的合成和早强作用的影响显著。通过动态光散射分析、总有机碳分析仪、X射线衍射分析、低场时域核磁共振分析仪、扫描电子显微镜、等温量热仪和抗压强度测试研究了酸醚比对C-S-Hs-PCE的粒径及其在水泥基材料中早期效果的影响。结果表明：高酸醚比的PCE形成的C-S-Hs-PCE具有更小的粒径，更有助于促进硅酸盐相水化和氢氧化钙、C-S-H凝胶的生成，从而加速浆体水化，降低砂浆的总孔隙率，提高砂浆的早期抗压强度，尤其是24 h龄期之内的强度。

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LEI Fengzhen (1997-), female, Master candidate. E-mail: leifengzhen@hnu.edu.cn

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