Article(id=1320107649560073005, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1320107605469544753, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20250856, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1763481600000, receivedDateStr=2025-11-19, revisedDate=1766160000000, revisedDateStr=2025-12-20, acceptedDate=null, acceptedDateStr=null, onlineDate=1792667790069, onlineDateStr=2026-10-22, pubDate=1786982400000, pubDateStr=2026-08-18, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792667790069, onlineIssueDateStr=2026-10-22, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792667790069, creator=13701087609, updateTime=1792667790069, updator=13701087609, issue=Issue{id=1320107605469544753, tenantId=1146029695717560320, journalId=1263187385517883426, year='2026', volume='54', issue='9', pageStart='2949', pageEnd='3314', issueExtLink='null', onlineDate='null', pubDate='1789833600000', pubDateStr='2026-09-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1792667779556, creator='13701087609', updateTime=1792737576818, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1320400356446687492, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1320107605469544753, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1320400356446687493, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1320107605469544753, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=3242, endPage=3253, ext={EN=ArticleExt(id=1320107649740428078, articleId=1320107649560073005, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Research Progress on Preparation of Si-O-C Ceramic Composite Microwave-Absorbing Materials
via Precursor Conversion Method, columnId=1263922772401635899, journalTitle=Journal of the Chinese Ceramic Society, columnName=Review, runingTitle=null, highlight=null, articleAbstract=
In recent years, with the rapid development of electronic devices, electromagnetic pollution has become increasingly severe, threatening the normal operation of electronic equipment and posing significant risks to information security. In the field of military radar stealth, the development of high-temperature absorbing materials with "thin, light, wide, and strong" characteristics along with high mechanical strength, heat resistance, corrosion resistance, and oxidation resistance becomes a critical scientific challenge urgently requiring resolution to reduce radar detection capabilities against military equipment and enhance adaptability in complex environments.
However, magnetic materials lose their magnetism in high-temperature environments, thereby reducing their ability to dissipate electromagnetic waves. Conductive loss-type materials, primarily composed of carbon, are prone to oxidation when exposed to air for extended periods, which diminishes their conductivity and consequently weakens their wave-absorbing performance. Si—O—C ceramics are a type of high-temperature ceramic with an open polymeric network structure composed of free carbon phases and amorphous Si—O—C glass phases. These ceramics exhibit some advantages such as high-temperature resistance, oxidation resistance, and excellent mechanical strength, making them a potential candidate for high-temperature wave-absorbing materials. Among the various methods for preparing Si—O—C ceramics, the precursor conversion method is widely used due to its simple process, broad range of matrix composition adjustments, and high conversion efficiency.
This review represents the preparation of particle-reinforced Si—O—C ceramic composite microwave absorbing materials, porous Si-O-C ceramic absorbing materials, and hetero-element modified Si—O—C ceramic absorbing materials via the precursor conversion method. It introduces the fabrication of fiber-reinforced Si—O—C ceramic composite absorbing materials, including Cf/Si—O—C ceramics, SiCf/Si—O—C ceramics, and oxide fiber/Si—O—C ceramics, achieving a structural-functional integration. Compared to single-phase Si—O—C ceramic materials, Si—O—C ceramic composites exhibit superior dielectric properties and balance multiple loss mechanisms and impedance matching, thereby enhancing microwave absorption performance. In addition, the future development directions of Si—O—C ceramic composite absorbing materials are also discussed.
Summary and prospects This review summarizes recent research on the preparation of Si—O—C ceramic composite absorbing materials by a precursor conversion method from multiple aspects. Particle reinforced Si—O—C ceramics suppress the volume shrinkage of sintered products and improve the yield of ceramics. Porous Si—O—C ceramics cause multiple reflections of electromagnetic waves entering the interior of the material, prolonging the propagation path and helping to improve impedance matching. Introducing heterogeneous element M into Si—O—C ceramics can alter the phase separation and crystallization behavior, and improve the thermal stability of Si—O—C ceramics. Fiber reinforced Si—O—C ceramics achieve a structural and functional integration. However, the manufacturing accuracy of complex structures is limited, and traditional mechanical processing is difficult to achieve high-precision forming of complex lattice structures. Porous Si—O—C ceramic composite absorbing materials face a challenge of balancing structure and performance, and the porosity is difficult to accurately control, with pore size, shape, and distribution being disordered. The interface bonding and phase separation problems of heterogeneous element modified Si—O—C ceramics are prominent, and interface defects are easily formed between heterogeneous phases due to significant differences in chemical properties. Fiber reinforced Si—O—C ceramic composite absorbing materials have both structural load-bearing and absorbing functions, but there is a limited research on the effect of external loads on their absorbing performance at high temperatures.
, authors=Donghai DING, Qian LIU, Guoqing XIAO, Yanjie ZHANG, authorsList=Donghai DING, Qian LIU, Guoqing XIAO, Yanjie ZHANG, authorCompany=null, correspAuthors=null, authorNote=
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近年来，随着电子设备的快速发展，电磁污染问题日益严重，Si-O-C陶瓷具有耐高温、抗氧化、机械强度高等优点，已成为一种潜在的高温吸波材料。然而在制备Si-O-C陶瓷的众多方法中，先驱体转化法由于其工艺简单、基体组成调节范围广、转化率高等优点被广泛应用。本文综述了先驱体转化法制备颗粒增强Si-O-C陶瓷复合吸波材料、多孔Si-O-C陶瓷吸波材料及异质元素改性Si-O-C陶瓷吸波材料的研究现状，介绍了先驱体转化法制备纤维增强Si-O-C陶瓷复合吸波材料，包括Cf/Si-O-C陶瓷、SiCf/Si-O-C陶瓷及氧化物纤维/Si-O-C陶瓷，实现了结构功能一体化。相比于单一的Si-O-C陶瓷材料，Si-O-C陶瓷复合材料不仅表现出优异的介电性能，同时能实现多重损耗机制和阻抗匹配的平衡，进而提高吸波性能，最后，展望了Si-O-C陶瓷复合吸波材料未来的发展方向。
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DING Donghai (1983-), male, Ph.D., Professor. E-mail: dingdongxauat@163.com
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丁冬海（1983—），男，博士，教授。
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丁冬海（1983—），男，博士，教授。
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