Article(id=1319973155112866567, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319973069423231598, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20230594, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1691596800000, receivedDateStr=2023-08-10, revisedDate=1698940800000, revisedDateStr=2023-11-03, acceptedDate=null, acceptedDateStr=null, onlineDate=1792635724093, onlineDateStr=2026-10-22, pubDate=1716134400000, pubDateStr=2024-05-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792635724093, onlineIssueDateStr=2026-10-22, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792635724093, creator=13701087609, updateTime=1792635724093, updator=13701087609, issue=Issue{id=1319973069423231598, tenantId=1146029695717560320, journalId=1263187385517883426, year='2024', volume='52', issue='5', pageStart='1477', pageEnd='1788', issueExtLink='null', onlineDate='null', pubDate='1716134400000', pubDateStr='2024-05-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1792635703664, creator='13701087609', updateTime=1792641791199, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319998602462741464, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319973069423231598, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319998602462741465, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319973069423231598, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1656, endPage=1663, ext={EN=ArticleExt(id=1319973155301610248, articleId=1319973155112866567, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Electrical and Photoluminescent Properties of Er
3+-Doped Lead-Free Ferroelectric Ceramics, columnId=1319726165087077079, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Article, runingTitle=null, highlight=null, articleAbstract=
Introduction Ferroelectric materials are widely used in detection, conversion, storage and information processing. The development of energy-saving, environmental protection, multi-functional, miniaturized lead-free multi-functional ceramics becomes inevitable. However, lead-free ferroelectric ceramics as dielectric ceramic capacitors with a low energy storage density and a poor energy storage efficiency seriously hinder their practical application. The development of ceramic capacitors with a high energy storage density and a high energy storage efficiency thus greatly expands the applications of ferroelectric ceramics in the field of energy storage. Doping rare-earth elements is a simple, direct and effective modification method. Rare-earth elements with special electronic structure and stable luminescence properties are expected to give new luminescent properties and improve the electrical properties of ferroelectric ceramics. Ba0.85Ca0.15Ti0.90Zr0.10O3 (BCTZ) lead-free piezoelectric ceramics have a small dielectric loss and superior electrical characteristics. Rare-earth element Er3+ is widely used in laser and lighting due to its excellent green luminous intensity. In this paper, the effect of Er3+ doping amount on the microstructure, ferroelectric, energy storage and photoluminescence properties of BCTZ ceramics and their internal relations was investigated to broaden the applications in photoelectric materials.
Methods Er3+ doped Ba0.85Ca0.15Ti0.90Zr0.10O3 (BCTZ:x%Er3+, x=0.0, 0.2, 0.4, 0.6, 0.8 and 1.0, in mole fraction) ceramics were prepared by a high-temperature solid-state reaction method. CaCO3 (99.9%), ZrO2 (99.9%), TiO2 (99.9%), BaCO3 (99.9%), Er2O3 (99.9%) were used as raw materials. The raw materials were firstly mixed and ground in a ball mill for 12 h, and then pre-burned at 1 100 ℃ for 6 h after drying The pre-burned materials were naturally cooled to room temperature, granulated and pressed. The pressed samples were sintered at 1 300 ℃ for 6 h. The crystal structure of ceramic samples was analyzed by a model D8 ADVANCE X-ray diffractometer (XRD, Germany). The surface morphology of the samples was characterized by a model JEM-7800F scanning electron microscope (SEM, JEOL Co., Japan). The electrical properties of ceramics were tested by a model TF Analyzer 3000E (Germany), and the both sides of the ceramics were plated with silver electrodes before testing. The luminescent properties of ceramics were determined by a model FS5 fluorescent spectrometer (Edinburgh Co., UK).
Results and discussion Rare-earth Er3+ doped BCTZ ceramics all have a well-crystallization with a single perovskite structure and little impurities. The results show that the mean grain size of the ceramics decreases monotonically with the increase of Er3+ doping concentration, from 7.59 μm to 3.82 μm, which is decreased by 49.67%.
All the ceramics exhibit superior ferroelectric properties. The ferroelectric domains are overturned and the density are different because of the lattice distortion and grain size change caused by the addition of different contents of Er3+, resulting in unstable polarization states. Therefore, the Er3+-doped BCTZ ceramics have a larger ΔP(Pmax-Pr) rather than pure BCTZ ceramic. The released energy density (Wrec) and energy storage efficiency (η) of the ceramics are increased by 29.81% and 122.79%, respectively.
The worse the lattice symmetry, the better the photoluminescent (PL) performance. At a great doping amount of Er3+, Er3+ replace the A-position Ba2+ and Ca2+ positions, gradually occupying the gap position or replacing the B-position ions, resulting in more lattice distortion, reducing the lattice symmetry, and significantly enhancing the photoluminescent intensity. When the doping amount is 0.8% (in mole), PL strength reaches the maximum value. As the doping amount is greater than 0.8%, a cross relaxation phenomenon occurs due to the increase of luminescent ions and the decrease of luminescent ion spacing, resulting in fluorescence quenching and a decreased luminous intensity. The relative change in PL strength of BCTZ:0.8%Er3+ ceramic is enhanced by 173%, compared with BCTZ:0.2%Er3+ ceramic.
Conclusions The mean grain size of the lead-free multifunctional ferroelectric ceramics decreased monotonously, and the microstructure became more compact and uniform with the increase of Er3+ doping concentration. All the ceramics had the superior ferroelectric properties. Er3+ doping could destroy the long-range order in BCTZ structure and the interaction between electric domains, so that the released energy density (Wrec) and energy storage efficiency (η) of the ceramics were increased by 29.81% and 122.79%, respectively, as Er3+ doping concentration increased. In addition, BCTZ:x%Er3+ ceramics exhibited an intense green emission at 548 nm under excitation of 487 nm near-ultraviolet light, and the luminous intensity was relatively adjustable up to 173.09%. The rich physical and photoelectric properties of BCTZ:x%Er3+ ceramics could lay a foundation for the development of new multi-functional materials with energy saving, environmental protection and low energy consumption.
, authors=Yixiao ZHANG, Xiaoli WANG, Jian YANG, Pengfei GUAN, Ming ZHENG, authorsList=Yixiao ZHANG, Xiaoli WANG, Jian YANG, Pengfei GUAN, Ming ZHENG, authorCompany=null, correspAuthors=Ming ZHENG, authorNote=
, correspAuthorsNote=
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1319973155578434313, articleId=1319973155112866567, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=Er
3+掺杂无铅铁电陶瓷的电学和光致发光性能, columnId=1263922770220560512, journalTitle=硅酸盐学报, columnName=研究论文, runingTitle=null, highlight=null, articleAbstract=
无铅多功能铁电陶瓷在各类信息的检测、转换、存储及处理中具有广泛的应用，且稀土元素由于其特殊的电子结构和稳定的发光特性，有望赋予铁电陶瓷新的发光性能并改善其电学性能，为设计新型光电器件提供了可能。采用传统的高温固相反应法制备稀土Er3+掺杂Ba0.85Ca0.15Ti0.90Zr0.10O3（BCTZ）无铅多功能铁电陶瓷，系统研究Er3+掺杂浓度对BCTZ铁电陶瓷微观结构、电学性能及光致发光的影响及内在联系。研究表明，陶瓷平均晶粒尺寸随Er3+掺杂浓度的增加单调减小，由7.59 μm减小至3.82 μm，减小约49.67%；陶瓷可释放的能量密度（Wrec）和储能效率（η）可分别提高约29.81%和122.79%。Er3+掺杂BCTZ陶瓷表现出强烈的绿光发射（548 nm）且发光强度相对可调性可达173.09%。Er3+掺杂BCTZ陶瓷优异、特殊的电光性能，在电介质储能电容器和光学器件等领域具有潜在应用前景。
, authors=张怡笑, 王小丽, 杨健, 关朋飞, 郑明, authorsList=张怡笑, 王小丽, 杨健, 关朋飞, 郑明, authorCompany=null, correspAuthors=郑明, authorNote=
, correspAuthorsNote=
郑明（1988—），男，博士，研究员。
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=KZNJlMfN1aEk9mrbzEL2gQ==, magXml=atzh/bSLkH4KfswBmlcpVg==, pdfUrl=null, pdf=raamdVD8yXhda/e71YBhdg==, pdfFileSize=1306993, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=8H4zfLPPjdfKNQEb9Jf+cA==, mapNumber=null, fund=null)}, authors=[Author(id=1319996400855790383, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319973155112866567, orderNo=0, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=ts22180124p31@cumt.edu.cn, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1319996400960647985, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319973155112866567, authorId=1319996400855790383, language=EN, stringName=Yixiao ZHANG, firstName=Yixiao, middleName=null, lastName=ZHANG, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=null, address=School of Materials Science and Physics, China University of Mining and Technology, Xuzhou 221116, Jiangsu, China, bio={"content":"
ZHANG Yixiao (2000-), female, Master candidate. E-mail: ts22180124p31@cumt.edu.cn
"}, bioImg=null, bioContent=
ZHANG Yixiao (2000-), female, Master candidate. E-mail: ts22180124p31@cumt.edu.cn
, aboutCorrespAuthor=null), CN=AuthorExt(id=1319996401040339762, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319973155112866567, authorId=1319996400855790383, language=CN, stringName=张怡笑, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=null, address=中国矿业大学材料与物理学院，江苏 徐州 221116, bio={"content":"
张怡笑（2000—），女，硕士研究生。
"}, bioImg=null, bioContent=
张怡笑（2000—），女，硕士研究生。
, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1319996400759321387, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319973155112866567, xref=null, ext=[AuthorCompanyExt(id=1319996400771904300, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319973155112866567, companyId=1319996400759321387, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=School of Materials Science and Physics, China University of Mining and Technology, Xuzhou 221116, Jiangsu, China), AuthorCompanyExt(id=1319996400780292909, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319973155112866567, companyId=1319996400759321387, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=中国矿业大学材料与物理学院，江苏 徐州 221116)])]), Author(id=1319996401107448628, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319973155112866567, orderNo=1, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=null, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1319996401220694838, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319973155112866567, authorId=1319996401107448628, language=EN, stringName=Xiaoli WANG, firstName=Xiaoli, middleName=null, lastName=WANG, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=null, address=School of Materials Science and Physics, China University of Mining and Technology, Xuzhou 221116, Jiangsu, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1319996401308775223, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319973155112866567, authorId=1319996401107448628, language=CN, stringName=王小丽, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=null, address=中国矿业大学材料与物理学院，江苏 徐州 221116, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1319996400759321387, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319973155112866567, xref=null, ext=[AuthorCompanyExt(id=1319996400771904300, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319973155112866567, companyId=1319996400759321387, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=School of Materials Science and Physics, China University of Mining and Technology, Xuzhou 221116, Jiangsu, China), AuthorCompanyExt(id=1319996400780292909, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319973155112866567, companyId=1319996400759321387, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=中国矿业大学材料与物理学院，江苏 徐州 221116)])]), Author(id=1319996401396855609, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319973155112866567, orderNo=2, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=null, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1319996401472353083, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319973155112866567, authorId=1319996401396855609, language=EN, stringName=Jian YANG, firstName=Jian, middleName=null, lastName=YANG, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=null, address=School of Materials Science and Physics, China University of Mining and Technology, Xuzhou 221116, Jiangsu, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1319996403112325948, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319973155112866567, authorId=1319996401396855609, language=CN, stringName=杨健, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=null, address=中国矿业大学材料与物理学院，江苏 徐州 221116, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1319996400759321387, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319973155112866567, xref=null, ext=[AuthorCompanyExt(id=1319996400771904300, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319973155112866567, companyId=1319996400759321387, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=School of Materials Science and Physics, China University of Mining and Technology, Xuzhou 221116, Jiangsu, China), AuthorCompanyExt(id=1319996400780292909, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319973155112866567, companyId=1319996400759321387, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=中国矿业大学材料与物理学院，江苏 徐州 221116)])]), Author(id=1319996403179434814, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319973155112866567, orderNo=3, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=null, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1319996403263320896, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319973155112866567, authorId=1319996403179434814, language=EN, stringName=Pengfei GUAN, firstName=Pengfei, middleName=null, lastName=GUAN, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=null, address=School of Materials Science and Physics, China University of Mining and Technology, Xuzhou 221116, Jiangsu, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1319996403330429761, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319973155112866567, authorId=1319996403179434814, language=CN, stringName=关朋飞, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=null, address=中国矿业大学材料与物理学院，江苏 徐州 221116, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1319996400759321387, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319973155112866567, xref=null, ext=[AuthorCompanyExt(id=1319996400771904300, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319973155112866567, companyId=1319996400759321387, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=School of Materials Science and Physics, China University of Mining and Technology, Xuzhou 221116, Jiangsu, China), AuthorCompanyExt(id=1319996400780292909, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319973155112866567, companyId=1319996400759321387, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=中国矿业大学材料与物理学院，江苏 徐州 221116)])]), Author(id=1319996403422704451, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319973155112866567, orderNo=4, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=zhengm@mail.ustc.edu.cn, emailSecond=null, emailThird=null, correspondingAuthor=1, authorType=1, ext={EN=AuthorExt(id=1319996403489813317, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319973155112866567, authorId=1319996403422704451, language=EN, stringName=Ming ZHENG, firstName=Ming, middleName=null, lastName=ZHENG, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=null, address=School of Materials Science and Physics, China University of Mining and Technology, Xuzhou 221116, Jiangsu, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1319996403577893702, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319973155112866567, authorId=1319996403422704451, language=CN, stringName=郑明, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=null, address=中国矿业大学材料与物理学院，江苏 徐州 221116, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1319996400759321387, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319973155112866567, xref=null, ext=[AuthorCompanyExt(id=1319996400771904300, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319973155112866567, companyId=1319996400759321387, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=School of Materials Science and Physics, China University of Mining and Technology, Xuzhou 221116, Jiangsu, China), AuthorCompanyExt(id=1319996400780292909, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319973155112866567, companyId=1319996400759321387, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=中国矿业大学材料与物理学院，江苏 徐州 221116)])])], keywords=[Keyword(id=1319996403716305735, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319973155112866567, language=EN, orderNo=1, keyword=rare-earth doping), Keyword(id=1319996403787608904, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319973155112866567, language=EN, orderNo=2, keyword=barium calcium zirconate titanate), Keyword(id=1319996403850523465, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319973155112866567, language=EN, orderNo=3, keyword=ferroelectric), Keyword(id=1319996403913438026, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319973155112866567, language=EN, orderNo=4, keyword=energy storage), Keyword(id=1319996403980546891, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319973155112866567, language=EN, orderNo=5, keyword=photoluminescence), Keyword(id=1319996404072821580, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319973155112866567, language=CN, orderNo=1, keyword=稀土掺杂), Keyword(id=1319996404135736141, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319973155112866567, language=CN, orderNo=2, keyword=锆钛酸钡钙), Keyword(id=1319996404202845006, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319973155112866567, language=CN, orderNo=3, keyword=铁电), Keyword(id=1319996404278342479, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319973155112866567, language=CN, orderNo=4, keyword=储能), Keyword(id=1319996404349645648, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319973155112866567, language=CN, orderNo=5, keyword=光致发光)], refs=null, funds=[Fund(id=1319996404479669073, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319973155112866567, awardId=2022QN1087, language=CN, fundingSource=中央高校基本科研业务费专项资金项目(2022QN1087), fundOrder=null, country=null)], companyList=[AuthorCompany(id=1319996400759321387, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319973155112866567, xref=null, ext=[AuthorCompanyExt(id=1319996400771904300, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319973155112866567, companyId=1319996400759321387, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=School of Materials Science and Physics, China University of Mining and Technology, Xuzhou 221116, Jiangsu, China), AuthorCompanyExt(id=1319996400780292909, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319973155112866567, companyId=1319996400759321387, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=中国矿业大学材料与物理学院，江苏 徐州 221116)])], figs=null, attaches=null, journal=Journal(id=1263186332462366751, delFlag=0, nameCn=硅酸盐学报, nameEn=Journal of the Chinese Ceramic Society, nameHistory1=null, nameHistory2=null, issn=0454-5648, eissn=null, cn=11-2310/TQ, coden=null, periodic=0, language=CN, oaType=null, ccby=null, superviseOffice=null, ownerOffice=null, pubOffice=null, editorOffice=null, officeType=null, aims=null, clcCode=null, officeProv=null, officeCity=null, officeAddr=null, officeZip=null, officeEmail=null, officePhone=null, editDirector=null, officeDirector=null, officeDirectorPhone=null, officeStaffNum=null, officeEmpNum=null, coverPicUrl=8Qg1+Is+LeRD1Lv6UJcXRg==, journalPrice=null, startedYear=null, abbrevIsoEn=Journal of the Chinese Ceramic Society, journalRemark=null, publicationField=null, createdTime=1779096690528, updatedTime=1788951192520, createdBy=18614031015, updatedBy=13041195026, firstLetterCn=G, firstLetterEn=G, subjectCode=Engineering, subjectName=null, subjectCodeEn=Engineering, subjectNameEn=null, picCn=8Qg1+Is+LeRD1Lv6UJcXRg==, picEn=AY9tl+TwuKtB81GF+w4WAg==, jcr=null, cjcr=null, exts=[JournalExt(id=1304519110767960749, language=CN, name=硅酸盐学报, nameHistory1=null, nameHistory2=null, managedBy=, sponsoredBy=, publishedBy=, editorOffice=, officeProv=null, officeCity=null, officeAddr=, officeZip=, editDirector=, officeDirector=null, officePhone=null, coverPicUrl=null, journalRemark=, submitArticleUrl=null, websiteUrl=, createdTime=1788951192800, updatedTime=1788951192800, createdBy=13041195026, updatedBy=13041195026, submissionGuidelinesUrl=, submissionAuthorUrl=https://gxyb.cbpt.cnki.net/index.aspx?t=1, submissionEditorUrl=https://gxyb.cbpt.cnki.net/index.aspx?t=3, submissionReviewUrl=https://gxyb.cbpt.cnki.net/index.aspx?t=2, submissionCeEditorUrl=, submissionAeEditorUrl=, option={"copyright":""}), JournalExt(id=1304519110839263918, language=EN, name=Journal of the Chinese Ceramic Society, nameHistory1=null, nameHistory2=null, managedBy=, sponsoredBy=, publishedBy=, editorOffice=, officeProv=null, officeCity=null, officeAddr=, officeZip=, editDirector=, officeDirector=null, officePhone=null, coverPicUrl=null, journalRemark=, submitArticleUrl=null, websiteUrl=, createdTime=1788951192817, updatedTime=1788951192817, createdBy=13041195026, updatedBy=13041195026, submissionGuidelinesUrl=, submissionAuthorUrl=https://gxyb.cbpt.cnki.net/index.aspx?t=1, submissionEditorUrl=https://gxyb.cbpt.cnki.net/index.aspx?t=3, submissionReviewUrl=https://gxyb.cbpt.cnki.net/index.aspx?t=2, submissionCeEditorUrl=, submissionAeEditorUrl=, option={"copyright":""})], databaseList=null, tenantJournalId=1263187385517883426, websiteList=[Website(id=1263188159895093557, webName=null, webTitle=null, webDomain=null, webCopyrigh=null, webIpcNo=null, seoTitle=null, seoKeywords=null, seoDescription=null, tenantJournalId=null, journalId=1263187385517883426, journalNameCn=null, journalNameEn=null, grayFlag=null, tenantId=1146029695717560320, platformId=null, journalGroupId=null, journalGroupNameCn=null, journalGroupNameEn=null, type=1, domain=https://castjournals.cast.org.cn/joweb/gsyxb/CN, language=CN, createTime=1779097126220, createBy=18614031015, updateTime=1779097837121, updateBy=18614031015, name=硅酸盐学报-中文, tplId=1146099689490845704, title=硅酸盐学报, delFlag=0, indexPage=/home, props=[WebsiteProps(id=1263191261578649862, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188159895093557, code=articleTextType, value=kx, createTime=1779097865719, updateTime=1779097865719, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191261545095427, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188159895093557, code=banner, value=null, createTime=1779097865711, updateTime=1779097865711, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191261599621385, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188159895093557, code=grayFlag, value=0, createTime=1779097865724, updateTime=1779097865724, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191261532512514, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188159895093557, code=logo, value=https://castjournals.cast.org.cn/joweb/gsyxb/CN/file/pic?fileId=Oqq9gXZG0JiYeHvLNwX/eg==, createTime=1779097865708, updateTime=1779097865708, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191261620592907, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188159895093557, code=minRunFlag, value=0, createTime=1779097865729, updateTime=1779097865729, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191261574455557, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188159895093557, code=picServerUrl, value=https://castjournals.cast.org.cn/joweb/gsyxb/CN/file/pic, createTime=1779097865718, updateTime=1779097865718, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191261616398602, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188159895093557, code=silenceFlag, value=0, createTime=1779097865728, updateTime=1779097865728, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191261566066948, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188159895093557, code=staticResourcePath, value=https://castjournals.cast.org.cn/joweb/cast_kjdb_cn_619/, createTime=1779097865716, updateTime=1779097865716, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191261587038471, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188159895093557, code=themeColor, value=null, createTime=1779097865721, updateTime=1779097865721, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191261591232776, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188159895093557, code=themeStyle, value=null, createTime=1779097865722, updateTime=1779097865722, creator=18614031015, updator=18614031015)]), Website(id=1263188160188694841, webName=null, webTitle=null, webDomain=null, webCopyrigh=null, webIpcNo=null, seoTitle=null, seoKeywords=null, seoDescription=null, tenantJournalId=null, journalId=1263187385517883426, journalNameCn=null, journalNameEn=null, grayFlag=null, tenantId=1146029695717560320, platformId=null, journalGroupId=null, journalGroupNameCn=null, journalGroupNameEn=null, type=1, domain=https://castjournals.cast.org.cn/joweb/gsyxb/EN, language=EN, createTime=1779097126348, createBy=18614031015, updateTime=1779097825280, updateBy=18614031015, name=硅酸盐学报-英文, tplId=1146101810881728533, title=Journal of the Chinese Ceramic Society, delFlag=0, indexPage=/home, props=[WebsiteProps(id=1263191231102836987, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188160188694841, code=articleTextType, value=kx, createTime=1779097858453, updateTime=1779097858453, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191231052505336, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188160188694841, code=banner, value=null, createTime=1779097858441, updateTime=1779097858441, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191231186723070, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188160188694841, code=grayFlag, value=0, createTime=1779097858473, updateTime=1779097858473, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191231039922423, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188160188694841, code=logo, value=https://castjournals.cast.org.cn/joweb/gsyxb/EN/file/pic?fileId=Oqq9gXZG0JiYeHvLNwX/eg==, createTime=1779097858438, updateTime=1779097858438, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191231358689536, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188160188694841, code=minRunFlag, value=0, createTime=1779097858514, updateTime=1779097858514, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191231094448378, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188160188694841, code=picServerUrl, value=https://castjournals.cast.org.cn/joweb/gsyxb/EN/file/pic, createTime=1779097858451, updateTime=1779097858451, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191231195111679, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188160188694841, code=silenceFlag, value=0, createTime=1779097858475, updateTime=1779097858475, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191231086059769, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188160188694841, code=staticResourcePath, value=https://castjournals.cast.org.cn/joweb/cast_kjdb_en_623/, createTime=1779097858449, updateTime=1779097858449, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191231111225596, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188160188694841, code=themeColor, value=null, createTime=1779097858455, updateTime=1779097858455, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191231144780029, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188160188694841, code=themeStyle, value=null, createTime=1779097858463, updateTime=1779097858463, creator=18614031015, updator=18614031015)])], journalTitle=硅酸盐学报, weixinUrl=null, journalUrl=https://jccsoc.cbpt.cnki.net/, iacademicId=null, status=1, seqNo=null, journalTitleEn=Journal of the Chinese Ceramic Society, journalPhotoCn=8Qg1+Is+LeRD1Lv6UJcXRg==, journalPhotoEn=AY9tl+TwuKtB81GF+w4WAg==, journalFirstLetter=G, journalRecommend=null, journalNew=null, journalCollection=null, jcrJf=null, cjcrJf=null, jcrJfStr=null, cjcrJfStr=null, submissionFirstDecision=null, sciSubjectClassification=null, casSubjectClassification=null, citeScore=null, totalCitationFrequency=null, icpCode=null, psCode=null, advertisingLicenseCode=null, copyrightInformation=null, country=null, option=, provinceCode=null, provinceName=null, collectFlag=false, interPubPlatform=, interPubPlatformUrl=null), detailUrlCn=https://castjournals.cast.org.cn/joweb/gsyxb/CN/10.14062/j.issn.0454-5648.20230594, detailUrlEn=https://castjournals.cast.org.cn/joweb/gsyxb/EN/10.14062/j.issn.0454-5648.20230594, pdfUrlCn=https://castjournals.cast.org.cn/joweb/gsyxb/CN/PDF/10.14062/j.issn.0454-5648.20230594, pdfUrlEn=https://castjournals.cast.org.cn/joweb/gsyxb/EN/PDF/10.14062/j.issn.0454-5648.20230594, aliStartDate=0, aliEndDate=0, collectionFlag=false, citedCount=null, citedUrl=null, previewStatus=0, delFlag=0, hasFullText=0, orderTime=1716134400000, fullTextJson=null, articleText=null, reference=null)
全屏
文章导航
PDF下载
56
7
关闭全屏
北京市海淀区学院南路86号
010-62662699（运营及技术支持）
qkjq@cast.org.cn
