Article(id=1318979389610639360, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318979383570837667, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20230300, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1683302400000, receivedDateStr=2023-05-06, revisedDate=1685635200000, revisedDateStr=2023-06-02, acceptedDate=null, acceptedDateStr=null, onlineDate=1792398791935, onlineDateStr=2026-10-19, pubDate=1700409600000, pubDateStr=2023-11-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792398791935, onlineIssueDateStr=2026-10-19, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792398791935, creator=13701087609, updateTime=1792398791935, updator=13701087609, issue=Issue{id=1318979383570837667, tenantId=1146029695717560320, journalId=1263187385517883426, year='2023', volume='51', issue='11', pageStart='2739', pageEnd='3038', issueExtLink='null', onlineDate='null', pubDate='1700409600000', pubDateStr='2023-11-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1792398790495, creator='13701087609', updateTime=1792399377667, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1318981846411629158, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318979383570837667, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1318981846411629159, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318979383570837667, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=2741, endPage=2749, ext={EN=ArticleExt(id=1318979389803577345, articleId=1318979389610639360, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Effect of Boron/Phosphorus Compound Doping on Formation and Properties of Sulfate-Rich Belite Sulfoaluminate Clinker, columnId=1321891504432460086, journalTitle=Journal of the Chinese Ceramic Society, columnName=Special Issue on Advanced Marine Materials—Research Articles, runingTitle=null, highlight=null, articleAbstract=

Sulfate-rich belite sulfoaluminate cement is used in rapid construction of marine engineering, but the strength of the clinker developed is not enough in the later period. The improvement of the strength in the later stage was investigated via boron/phosphorus composite doping. The effect of boron/phosphorus composite doping on the mineral formation, microstructure, and hydration of high sulfur belite aluminate clinker was analyzed by X-ray diffraction combined with Rietveld full spectrum quantitative analysis, scanning electron microscopy, isothermal calorimetry and thermogravimetric analysis. The results show that boron and phosphorus both can exist in the crystal structure of dicalcium silicate, form the crystal defects, and increase the content of α-C2S and c-C4A3$, thus promoting the early hydration and later strength development of the clinker.

, authors=Wensheng ZHANG1, Nan AN1, Hongtao ZHANG1, Xuehong REN1, Jiayuan YE1, Lei LIU1, Lixue CAO1, Jueshi QIAN2, authorsList=Wensheng ZHANG, Nan AN, Hongtao ZHANG, Xuehong REN, Jiayuan YE, Lei LIU, Lixue CAO, Jueshi QIAN, authorCompany=null, correspAuthors=null, authorNote=

ZHANG Wensheng (1969-), male, Ph. D., Professor. E-mail:

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高硫型贝利特硫铝酸盐水泥在海洋工程快速施工具有显著的优势,但是该水泥熟料后期强度发展不足。采用硼/磷复合掺杂的方法开展了提高后期强度的研究,并采用X射线衍射结合Rietveld全谱定量分析、扫描电镜、等温量热及热重分析等测试方法,研究了硼/磷复合掺杂对高硫型贝利特硫铝酸盐水泥熟料矿物形成、微观结构及水化等的影响。研究表明:硼、磷2种元素均能固溶到硅酸二钙的晶体结构中,形成结构缺陷,提高熟料中α-C2S含量,同时提高c-C4A3$的含量,促进了熟料早期的水化和后期强度的发展。

, authors=张文生1, 安楠1, 张洪滔1, 任雪红1, 叶家元1, 刘垒1, 曹立学1, 钱觉时2, authorsList=张文生, 安楠, 张洪滔, 任雪红, 叶家元, 刘垒, 曹立学, 钱觉时, authorCompany=null, correspAuthors=null, authorNote=

张文生(1969—),男,博士,教授。

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硼/磷复合掺杂对高硫型贝利特硫铝酸盐熟料形成与性能的影响
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张文生 1 , 安楠 1 , 张洪滔 1 , 任雪红 1 , 叶家元 1 , 刘垒 1 , 曹立学 1 , 钱觉时 2
硅酸盐学报 | 先进海洋材料专题—研究论文 2023,51(11): 2741-2749
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硅酸盐学报 |先进海洋材料专题—研究论文 2023 , 51 (11) : 2741 -2749
硼/磷复合掺杂对高硫型贝利特硫铝酸盐熟料形成与性能的影响
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ZHANG Wensheng (1969-), male, Ph. D., Professor. E-mail:

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张文生1 , 安楠1, 张洪滔1, 任雪红1, 叶家元1, 刘垒1, 曹立学1, 钱觉时2
作者信息
  • 1.中国建筑材料科学研究总院有限公司,绿色建筑材料国家重点实验室,北京 100024
  • 2.重庆大学材料科学与工程学院,重庆 400045
作者简介:

张文生(1969—),男,博士,教授。

Effect of Boron/Phosphorus Compound Doping on Formation and Properties of Sulfate-Rich Belite Sulfoaluminate Clinker
Wensheng ZHANG1 , Nan AN1, Hongtao ZHANG1, Xuehong REN1, Jiayuan YE1, Lei LIU1, Lixue CAO1, Jueshi QIAN2
Affiliations
  • 1.State Key Laboratory of Green Building Materials, China Building Materials Academy, Beijing 100024, China
  • 2.College of Materials Science and Engineering, Chongqing University, Chongqing 400045, China
  • ZHANG Wensheng (1969-), male, Ph. D., Professor. E-mail:

出版时间: 2023-11-20 doi: 10.14062/j.issn.0454-5648.20230300
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高硫型贝利特硫铝酸盐水泥在海洋工程快速施工具有显著的优势,但是该水泥熟料后期强度发展不足。采用硼/磷复合掺杂的方法开展了提高后期强度的研究,并采用X射线衍射结合Rietveld全谱定量分析、扫描电镜、等温量热及热重分析等测试方法,研究了硼/磷复合掺杂对高硫型贝利特硫铝酸盐水泥熟料矿物形成、微观结构及水化等的影响。研究表明:硼、磷2种元素均能固溶到硅酸二钙的晶体结构中,形成结构缺陷,提高熟料中α-C2S含量,同时提高c-C4A3$的含量,促进了熟料早期的水化和后期强度的发展。

高硫型贝利特硫铝酸盐水泥熟料  /  硼酸  /  磷酸钙  /  强度

Sulfate-rich belite sulfoaluminate cement is used in rapid construction of marine engineering, but the strength of the clinker developed is not enough in the later period. The improvement of the strength in the later stage was investigated via boron/phosphorus composite doping. The effect of boron/phosphorus composite doping on the mineral formation, microstructure, and hydration of high sulfur belite aluminate clinker was analyzed by X-ray diffraction combined with Rietveld full spectrum quantitative analysis, scanning electron microscopy, isothermal calorimetry and thermogravimetric analysis. The results show that boron and phosphorus both can exist in the crystal structure of dicalcium silicate, form the crystal defects, and increase the content of α-C2S and c-C4A3$, thus promoting the early hydration and later strength development of the clinker.

sulfate-rich belite sulfoaluminate clinker  /  boric acid  /  calcium phosphate  /  strength
张文生, 安楠, 张洪滔, 任雪红, 叶家元, 刘垒, 曹立学, 钱觉时. 硼/磷复合掺杂对高硫型贝利特硫铝酸盐熟料形成与性能的影响. 硅酸盐学报, 2023 , 51 (11) : 2741 -2749 . DOI: 10.14062/j.issn.0454-5648.20230300
Wensheng ZHANG, Nan AN, Hongtao ZHANG, Xuehong REN, Jiayuan YE, Lei LIU, Lixue CAO, Jueshi QIAN. Effect of Boron/Phosphorus Compound Doping on Formation and Properties of Sulfate-Rich Belite Sulfoaluminate Clinker[J]. Journal of the Chinese Ceramic Society, 2023 , 51 (11) : 2741 -2749 . DOI: 10.14062/j.issn.0454-5648.20230300
  • 国家自然科学基金重点项目(51832006)
  • 中国建材集团攻关专项资助项目(2021HX0304)
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2023年第51卷第11期
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doi: 10.14062/j.issn.0454-5648.20230300
  • 接收时间:2023-05-06
  • 首发时间:2026-10-19
  • 出版时间:2023-11-20
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  • 收稿日期:2023-05-06
  • 修回日期:2023-06-02
基金
国家自然科学基金重点项目(51832006)
中国建材集团攻关专项资助项目(2021HX0304)
作者信息
    1.中国建筑材料科学研究总院有限公司,绿色建筑材料国家重点实验室,北京 100024
    2.重庆大学材料科学与工程学院,重庆 400045
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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