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Article(id=1318978546085777426, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318978537852359595, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20230150, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1678636800000, receivedDateStr=2023-03-13, revisedDate=1680451200000, revisedDateStr=2023-04-03, acceptedDate=null, acceptedDateStr=null, onlineDate=1792398590822, onlineDateStr=2026-10-19, pubDate=1697731200000, pubDateStr=2023-10-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792398590822, onlineIssueDateStr=2026-10-19, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792398590822, creator=13701087609, updateTime=1792398590822, updator=13701087609, issue=Issue{id=1318978537852359595, tenantId=1146029695717560320, journalId=1263187385517883426, year='2023', volume='51', issue='10', pageStart='2517', pageEnd='2738', issueExtLink='null', onlineDate='null', pubDate='1697731200000', pubDateStr='2023-10-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1792398588860, creator='13701087609', updateTime=1792399337892, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1318981679578993157, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318978537852359595, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1318981679578993158, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318978537852359595, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=2594, endPage=2602, ext={EN=ArticleExt(id=1318978546308075539, articleId=1318978546085777426, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Reversible Performance of Flat-Tube Solid Oxide Cell Stack for Seawater, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=

Solid oxide cell (SOC) plays a pivotal role in the reversible conversion of electricity-gas-electricity. The seawater electrolysis through reversible SOC is proven to be an effective approach to the intermittent power generation such as offshore wind power and photovoltaic power generation. In this paper, a flat-tube SOC stack was tested to analyze the reversible performance for SOC stack fueled with seawater/H2 under different operating conditions (i.e., water vapor content and current density). The results show that the degradation rate in electrolysis mode is minimal at a current density of 100 mA·cm-2, a humidified temperature of 90 ℃ (volume fraction of water vapor is 65%) and 750 ℃. The minimum voltage degradation rate in fuel cell mode is attained at a current density of 100 mA/cm2, a humidified temperature of 86 ℃ (volume fraction of water vapor is 56%) and 750 ℃. The efficiency of the stack in reversible mode is 95.2% at 100 mA·cm-2. It is indicated that this study could provide a reference for the application of reversible SOC stacks in seawater environment.

, authors=Yiping YANG1, Xiaogang HU2, Xurui HUANG1, Jinyong LEI1, Beibei HAN2, Zhao LIU2, Wanbing GUAN2, authorsList=Yiping YANG, Xiaogang HU, Xurui HUANG, Jinyong LEI, Beibei HAN, Zhao LIU, Wanbing GUAN, authorCompany=null, correspAuthors=Wanbing GUAN, authorNote=

YANG Yiping (1994-), female, Master. E-mail:

, correspAuthorsNote=
GUAN Wanbing (1980-), male, Ph.D., Professor. E-mail:
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1318978546622648340, articleId=1318978546085777426, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=海水环境下平管型固体氧化物电池电堆的可逆性能, columnId=1263922770220560512, journalTitle=硅酸盐学报, columnName=研究论文, runingTitle=null, highlight=null, articleAbstract=

固体氧化物电池（SOC）可以实现电-气-电之间的可逆转换。基于海水的可逆SOC（即rSOC）可以有效解决海上风电、光伏等间歇式发电消纳问题。本工作采用平管型固体氧化物电池电堆开展了海水环境下的可逆性能研究，分析了水蒸气含量和电流密度等运行条件对固体氧化物电堆可逆性能的影响。结果表明：在750 ℃，当电解条件下电流密度为100 mA·cm-2，加湿90 ℃（水蒸气体积分数65%）时电压衰减最小；放电条件下电流密度100 mA·cm-2时且加湿86 ℃（水蒸气体积分数56%）下电压衰减最小；可逆模式下电堆的能量转化效率在100 mA·cm-2时效率最大达95.2%。本研究为固体氧化物电池电堆在海水环境下的可逆应用提供了参考。

, authors=杨怡萍1, 胡小刚2, 黄旭锐1, 雷金勇1, 韩贝贝2, 刘曌2, 官万兵2, authorsList=杨怡萍, 胡小刚, 黄旭锐, 雷金勇, 韩贝贝, 刘曌, 官万兵, authorCompany=null, correspAuthors=官万兵, authorNote=

杨怡萍（1994—），女，硕士研究生。

, correspAuthorsNote=
官万兵（1980—），男，博士，研究员。
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YANG Yiping (1994-), female, Master. E-mail:

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杨怡萍（1994—），女，硕士研究生。

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杨怡萍（1994—），女，硕士研究生。

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海水环境下平管型固体氧化物电池电堆的可逆性能
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杨怡萍 1 , 胡小刚 2 , 黄旭锐 1 , 雷金勇 1 , 韩贝贝 2 , 刘曌 2 , 官万兵 2
硅酸盐学报 | 研究论文 2023,51(10): 2594-2602
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硅酸盐学报 |研究论文 2023 , 51 (10) : 2594 -2602
海水环境下平管型固体氧化物电池电堆的可逆性能
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杨怡萍（1994—），女，硕士研究生。

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杨怡萍1 , 胡小刚2, 黄旭锐1, 雷金勇1, 韩贝贝2, 刘曌2, 官万兵2
作者信息
  • 1．广东电网有限责任公司广州供电局，广州 510600
  • 2．中国科学院宁波材料技术与工程研究所，浙江省先进燃料电池与电解池技术重点实验室，浙江 宁波 315201
通讯作者:
官万兵（1980—），男，博士，研究员。
作者简介:

杨怡萍（1994—），女，硕士研究生。

Reversible Performance of Flat-Tube Solid Oxide Cell Stack for Seawater
Yiping YANG1 , Xiaogang HU2, Xurui HUANG1, Jinyong LEI1, Beibei HAN2, Zhao LIU2, Wanbing GUAN2
Affiliations
  • 1.Guangzhou Power Supply Bureau, Guangdong Power Grid Co., Ltd. Guangzhou 510600, China
  • 2.Zhejiang Key Laboratory of Advanced Fuel Cell and Electrolytic Cell Technology, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, Zhejiang, China
    • Corresponding Author:
    GUAN Wanbing (1980-), male, Ph.D., Professor. E-mail:

    YANG Yiping (1994-), female, Master. E-mail:

出版时间: 2023-10-20 doi: 10.14062/j.issn.0454-5648.20230150
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固体氧化物电池（SOC）可以实现电-气-电之间的可逆转换。基于海水的可逆SOC（即rSOC）可以有效解决海上风电、光伏等间歇式发电消纳问题。本工作采用平管型固体氧化物电池电堆开展了海水环境下的可逆性能研究，分析了水蒸气含量和电流密度等运行条件对固体氧化物电堆可逆性能的影响。结果表明：在750 ℃，当电解条件下电流密度为100 mA·cm-2，加湿90 ℃（水蒸气体积分数65%）时电压衰减最小；放电条件下电流密度100 mA·cm-2时且加湿86 ℃（水蒸气体积分数56%）下电压衰减最小；可逆模式下电堆的能量转化效率在100 mA·cm-2时效率最大达95.2%。本研究为固体氧化物电池电堆在海水环境下的可逆应用提供了参考。

海水  /  效率  /  平管型  /  可逆  /  固体氧化物电池

Solid oxide cell (SOC) plays a pivotal role in the reversible conversion of electricity-gas-electricity. The seawater electrolysis through reversible SOC is proven to be an effective approach to the intermittent power generation such as offshore wind power and photovoltaic power generation. In this paper, a flat-tube SOC stack was tested to analyze the reversible performance for SOC stack fueled with seawater/H2 under different operating conditions (i.e., water vapor content and current density). The results show that the degradation rate in electrolysis mode is minimal at a current density of 100 mA·cm-2, a humidified temperature of 90 ℃ (volume fraction of water vapor is 65%) and 750 ℃. The minimum voltage degradation rate in fuel cell mode is attained at a current density of 100 mA/cm2, a humidified temperature of 86 ℃ (volume fraction of water vapor is 56%) and 750 ℃. The efficiency of the stack in reversible mode is 95.2% at 100 mA·cm-2. It is indicated that this study could provide a reference for the application of reversible SOC stacks in seawater environment.

Seawater  /  efficiency  /  flat-tube  /  reversible  /  solid oxide cell
杨怡萍, 胡小刚, 黄旭锐, 雷金勇, 韩贝贝, 刘曌, 官万兵. 海水环境下平管型固体氧化物电池电堆的可逆性能. 硅酸盐学报, 2023 , 51 (10) : 2594 -2602 . DOI: 10.14062/j.issn.0454-5648.20230150
Yiping YANG, Xiaogang HU, Xurui HUANG, Jinyong LEI, Beibei HAN, Zhao LIU, Wanbing GUAN. Reversible Performance of Flat-Tube Solid Oxide Cell Stack for Seawater[J]. Journal of the Chinese Ceramic Society, 2023 , 51 (10) : 2594 -2602 . DOI: 10.14062/j.issn.0454-5648.20230150
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  • 南方电网公司科技项目(030100KK52200020)
  • 国家重点研发计划项目(2022YFB4002203)
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2023年第51卷第10期
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doi: 10.14062/j.issn.0454-5648.20230150
  • 接收时间：2023-03-13
  • 首发时间：2026-10-19
  • 出版时间：2023-10-20
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  • 收稿日期：2023-03-13
  • 修回日期：2023-04-03
基金
南方电网公司科技项目(030100KK52200020)
国家重点研发计划项目(2022YFB4002203)
作者信息
    1．广东电网有限责任公司广州供电局，广州 510600
    2．中国科学院宁波材料技术与工程研究所，浙江省先进燃料电池与电解池技术重点实验室，浙江 宁波 315201

通讯作者:

官万兵（1980—），男，博士，研究员。
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2种不同金属材料的力学参数
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鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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