Article(id=1318974515548377767, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318974513019207979, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20230144, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1678377600000, receivedDateStr=2023-03-10, revisedDate=1679673600000, revisedDateStr=2023-03-25, acceptedDate=null, acceptedDateStr=null, onlineDate=1792397629867, onlineDateStr=2026-10-19, pubDate=1686067200000, pubDateStr=2023-06-07, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792397629867, onlineIssueDateStr=2026-10-19, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792397629867, creator=13701087609, updateTime=1792397629867, updator=13701087609, issue=Issue{id=1318974513019207979, tenantId=1146029695717560320, journalId=1263187385517883426, year='2023', volume='51', issue='7', pageStart='1649', pageEnd='1882', issueExtLink='null', onlineDate='null', pubDate='1689782400000', pubDateStr='2023-07-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1792397629265, creator='13701087609', updateTime=1792399256269, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1318981337223119779, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318974513019207979, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1318981337223119780, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318974513019207979, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1707, endPage=1715, ext={EN=ArticleExt(id=1318974515925865128, articleId=1318974515548377767, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Preparation and Potassium Storage of ZnSe/CoSe/SnSe@NC Nanocubes, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=

To explore the potassium storage potentials of polymetallic selenides, nitrogen-doped carbon coated ZnSe/CoSe/SnSe materials was synthesized by a hydrothermal method. The core of polymetallic selenides exhibits an enhanced electrochemical activity, and a cavity in the structure alleviates the volume effect upon cycle when this compound serves as anode materials of potassium-ion batteries. Meanwhile, the conductive coating shell effectively improves the material conductivity and prevents the active substance from agglomeration during potassium storage. Compared with the uncoated material, ZnSe/CoSe/SnSe@nitrogen-doped carbon material has a better potassium storage performance. The discharge specific capacity still maintains 193 mA·h/g after 800 cycles at a current density of 1 A/g. This work could provide a guide for the design and construction of high-performance potassium ion battery anode materials.

, authors=Hao SUN¹, Xiaojing LIU², Bo YAN¹, Xuelin YANG^{1, 2}, authorsList=Hao SUN, Xiaojing LIU, Bo YAN, Xuelin YANG, authorCompany=null, correspAuthors=Xiaojing LIU, Xuelin YANG, authorNote=, correspAuthorsNote=, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1318974516383044265, articleId=1318974515548377767, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=ZnSe/CoSe/SnSe@NC纳米立方体制备及其储钾性能, columnId=1263922770220560512, journalTitle=硅酸盐学报, columnName=研究论文, runingTitle=null, highlight=null, articleAbstract=

通过水热法首次合成了含有Zn、Co、Sn 3种金属元素的氢氧化物，后经强碱刻蚀、聚多巴胺包覆以及碳化和硒化成功制备出氮掺杂碳包覆ZnSe/CoSe/SnSe材料。该复合物用作钾离子电池负极时，多元金属硒化物内核表现出增强的电化学活性，且结构中的空腔缓解了循环时的体积效应；同时，导电包覆层外壳有效提升了材料电导率，并防止了钾化时活性物质粉化团聚。结果与原始材料相比，ZnSe/CoSe/SnSe@NC表现出更优异的储钾性能，其在1 A/g电流密度下经800次循环后，放电比容量仍高达193 mA·h/g。本工作对高性能钾离子电池负极材料的设计与构筑具有指导意义。

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SUN Hao (1999-), male, Master candidate. E-mail: 1181949695@qq.com

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