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Article(id=1318978565169860765, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318978537852359595, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20230124, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1677772800000, receivedDateStr=2023-03-03, revisedDate=1680192000000, revisedDateStr=2023-03-31, acceptedDate=null, acceptedDateStr=null, onlineDate=1792398595372, onlineDateStr=2026-10-19, pubDate=1697731200000, pubDateStr=2023-10-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792398595372, onlineIssueDateStr=2026-10-19, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792398595372, creator=13701087609, updateTime=1792398595372, updator=13701087609, issue=Issue{id=1318978537852359595, tenantId=1146029695717560320, journalId=1263187385517883426, year='2023', volume='51', issue='10', pageStart='2517', pageEnd='2738', issueExtLink='null', onlineDate='null', pubDate='1697731200000', pubDateStr='2023-10-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1792398588860, creator='13701087609', updateTime=1792399337892, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1318981679578993157, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318978537852359595, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1318981679578993158, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318978537852359595, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=2712, endPage=2726, ext={EN=ArticleExt(id=1318978565530570910, articleId=1318978565169860765, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Research Progress on Key Components and Seawater Electrolysis of Solid Oxide Electrolytic Cell, columnId=1263922772401635899, journalTitle=Journal of the Chinese Ceramic Society, columnName=Review, runingTitle=null, highlight=null, articleAbstract=

As an advanced electrochemical energy conversion device, solid oxide electrolytic cell (SOEC) can achieve the hydrogen/hydrocarbon fuel gas precipitation at the electrode side through reversible electrochemical process of solid oxide fuel cell (SOFC). SOEC is regarded as one of the most promising systems in promoting large-scale hydrogen production and energy structure optimization as well as realizing our "double carbon" goal due to its simplicity, fuel flexibility, low energy consumption and high system efficiencies (85%-95%). This review represented the research status on the material selection and service performance for the key components (i.e., fuel electrode, solid electrolyte and oxygen electrode) of SOEC. Moreover, the performance parameters (i.e., current density, voltage decay rate, impedance, conductivity and hydrogen production rate) were summarized. In addition, the application potential of SOEC technology in the future hydrogen production from electrolytic seawater as well as the future development of key component materials such as composite electrode were also proposed.

, authors=Desheng LI1, Hu GUO1, Yingzhen HU1, Xihong HE1, Guoxing QIU1, Senhui LIU2, Chengxin LI2, authorsList=Desheng LI, Hu GUO, Yingzhen HU, Xihong HE, Guoxing QIU, Senhui LIU, Chengxin LI, authorCompany=null, correspAuthors=Yingzhen HU, Xihong HE, authorNote=

LI Desheng (1999-), male, Master candidate. E-mail:

, correspAuthorsNote=
HU Yingzhen (1986-), female, Ph.D., Associate Professor; E-mail:
HE Xihong (1983-), male, Ph.D., Associate Professor.
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固体氧化物电解池（SOEC）在本质上是固体氧化物燃料电池（SOFC）的逆向模式，通过电化学过程在电极侧实现氢气/碳氢燃料气体的析出，具有简单、灵活、低能耗等显著优势，能量转换效率高达85%~95%。作为目前极有望实现大规模高效制氢的先进电化学能量转化装置，SOEC稳定性和寿命的提升，对实现中国能源结构调整、推进“双碳”目标进程具有重要意义。本文针对燃料电极、固态电解质、氧电极3大关键部件的材料选择、服役性能等研究现状展开了系统讨论，分别对其电流密度、电压衰减率、阻抗、电导率及产氢速率等性能参数进行了详细归纳。在此基础上，提出了SOEC技术在未来电解海水制氢中的应用潜力，并就复合电极等关键部件材料的发展进行了展望。

, authors=李德胜1, 郭虎1, 胡莹珍1, 何喜红1, 邱国兴1, 刘森辉2, 李成新2, authorsList=李德胜, 郭虎, 胡莹珍, 何喜红, 邱国兴, 刘森辉, 李成新, authorCompany=null, correspAuthors=胡莹珍, 何喜红, authorNote=

李德胜（1999—），男，硕士研究生。

, correspAuthorsNote=
胡莹珍（1986—），女，博士，副教授；
何喜红（1983—），男，博士，副教授。
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LI Desheng (1999-), male, Master candidate. E-mail:

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李德胜（1999—），男，硕士研究生。

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固体氧化物电解池关键材料及其海水电解研究进展
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李德胜 1 , 郭虎 1 , 胡莹珍 1 , 何喜红 1 , 邱国兴 1 , 刘森辉 2 , 李成新 2
硅酸盐学报 | 综合评述 2023,51(10): 2712-2726
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硅酸盐学报 |综合评述 2023 , 51 (10) : 2712 -2726
固体氧化物电解池关键材料及其海水电解研究进展
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李德胜（1999—），男，硕士研究生。

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李德胜1 , 郭虎1, 胡莹珍1 , 何喜红1 , 邱国兴1, 刘森辉2, 李成新2
作者信息
  • 1．西安建筑科技大学冶金工程学院，西安 710048
  • 2．西安交通大学材料科学与工程学院，金属材料强度国家重点实验室，西安 710049
通讯作者:
胡莹珍（1986—），女，博士，副教授；
何喜红（1983—），男，博士，副教授。
作者简介:

李德胜（1999—），男，硕士研究生。

Research Progress on Key Components and Seawater Electrolysis of Solid Oxide Electrolytic Cell
Desheng LI1 , Hu GUO1, Yingzhen HU1 , Xihong HE1 , Guoxing QIU1, Senhui LIU2, Chengxin LI2
Affiliations
  • 1.College of Metallurgical Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China
  • 2.State Key laboratory for Mechanical Behavior of Materials, School of Materials Science and Engineering, Xi'an Jiaotong University, Xi'an 710049, China
    • Corresponding Author:
    HU Yingzhen (1986-), female, Ph.D., Associate Professor; E-mail:
    HE Xihong (1983-), male, Ph.D., Associate Professor.

    LI Desheng (1999-), male, Master candidate. E-mail:

出版时间: 2023-10-20 doi: 10.14062/j.issn.0454-5648.20230124
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摘要
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固体氧化物电解池（SOEC）在本质上是固体氧化物燃料电池（SOFC）的逆向模式，通过电化学过程在电极侧实现氢气/碳氢燃料气体的析出，具有简单、灵活、低能耗等显著优势，能量转换效率高达85%~95%。作为目前极有望实现大规模高效制氢的先进电化学能量转化装置，SOEC稳定性和寿命的提升，对实现中国能源结构调整、推进“双碳”目标进程具有重要意义。本文针对燃料电极、固态电解质、氧电极3大关键部件的材料选择、服役性能等研究现状展开了系统讨论，分别对其电流密度、电压衰减率、阻抗、电导率及产氢速率等性能参数进行了详细归纳。在此基础上，提出了SOEC技术在未来电解海水制氢中的应用潜力，并就复合电极等关键部件材料的发展进行了展望。

固体氧化物电解池  /  制氢  /  燃料电极  /  电解质  /  氧电极

As an advanced electrochemical energy conversion device, solid oxide electrolytic cell (SOEC) can achieve the hydrogen/hydrocarbon fuel gas precipitation at the electrode side through reversible electrochemical process of solid oxide fuel cell (SOFC). SOEC is regarded as one of the most promising systems in promoting large-scale hydrogen production and energy structure optimization as well as realizing our "double carbon" goal due to its simplicity, fuel flexibility, low energy consumption and high system efficiencies (85%-95%). This review represented the research status on the material selection and service performance for the key components (i.e., fuel electrode, solid electrolyte and oxygen electrode) of SOEC. Moreover, the performance parameters (i.e., current density, voltage decay rate, impedance, conductivity and hydrogen production rate) were summarized. In addition, the application potential of SOEC technology in the future hydrogen production from electrolytic seawater as well as the future development of key component materials such as composite electrode were also proposed.

solid oxide electrolytic cell  /  hydrogen production  /  fuel electrode  /  electrolyte  /  oxygen electrode
李德胜, 郭虎, 胡莹珍, 何喜红, 邱国兴, 刘森辉, 李成新. 固体氧化物电解池关键材料及其海水电解研究进展. 硅酸盐学报, 2023 , 51 (10) : 2712 -2726 . DOI: 10.14062/j.issn.0454-5648.20230124
Desheng LI, Hu GUO, Yingzhen HU, Xihong HE, Guoxing QIU, Senhui LIU, Chengxin LI. Research Progress on Key Components and Seawater Electrolysis of Solid Oxide Electrolytic Cell[J]. Journal of the Chinese Ceramic Society, 2023 , 51 (10) : 2712 -2726 . DOI: 10.14062/j.issn.0454-5648.20230124
基金
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  • 国家自然科学基金青年基金项目(51901187)
  • 国家自然科学基金项目(52201087)
  • 陕西省自然科学基金(2022JM-253)
  • 陕西省教育厅专项科研计划项目(21JK0725)
  • 西安交通大学金属材料强度国家重点实验室开放基金(20222416)
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2023年第51卷第10期
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文章信息
doi: 10.14062/j.issn.0454-5648.20230124
  • 接收时间：2023-03-03
  • 首发时间：2026-10-19
  • 出版时间：2023-10-20
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出版历史
  • 收稿日期：2023-03-03
  • 修回日期：2023-03-31
基金
国家自然科学基金青年基金项目(51901187)
国家自然科学基金项目(52201087)
陕西省自然科学基金(2022JM-253)
陕西省教育厅专项科研计划项目(21JK0725)
西安交通大学金属材料强度国家重点实验室开放基金(20222416)
作者信息
    1．西安建筑科技大学冶金工程学院，西安 710048
    2．西安交通大学材料科学与工程学院，金属材料强度国家重点实验室，西安 710049

通讯作者:

胡莹珍（1986—），女，博士，副教授；
何喜红（1983—），男，博士，副教授。
参考文献
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https://castjournals.cast.org.cn/joweb/gsyxb/CN/10.14062/j.issn.0454-5648.20230124
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2种不同金属材料的力学参数
科
Family		 属数
Number of
genus		 种数
Number of
species		 占总种数比例
Percentage of
total species (%)		 属
Genus		 种数
Number of
species		 占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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