Article(id=1318976917584327329, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318976874252980746, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20230109, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1677513600000, receivedDateStr=2023-02-28, revisedDate=1679500800000, revisedDateStr=2023-03-23, acceptedDate=null, acceptedDateStr=null, onlineDate=1792398202557, onlineDateStr=2026-10-19, pubDate=1695139200000, pubDateStr=2023-09-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792398202557, onlineIssueDateStr=2026-10-19, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792398202557, creator=13701087609, updateTime=1792398202557, updator=13701087609, issue=Issue{id=1318976874252980746, tenantId=1146029695717560320, journalId=1263187385517883426, year='2023', volume='51', issue='9', pageStart='2119', pageEnd='2516', issueExtLink='null', onlineDate='null', pubDate='1695139200000', pubDateStr='2023-09-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1792398192226, creator='13701087609', updateTime=1792399292764, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1318981490315210817, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318976874252980746, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1318981490315210818, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318976874252980746, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=2322, endPage=2333, ext={EN=ArticleExt(id=1318976917785653922, articleId=1318976917584327329, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Fluorinated Inorganic Materials for Lithium Metal Anodes—A Short Review, columnId=1321890862989169402, journalTitle=Journal of the Chinese Ceramic Society, columnName=Special Issue Innovation of Inorganic Non-Metallic Materials and Technologies to Support “Dual-Carbon” Goal—Review, runingTitle=null, highlight=null, articleAbstract=

Lithium (Li) metal is considered as the "Holy Grail" anode material for next-generation high-energy density battery system due to its high theoretical capacity and lowest reduction potential. However, the practical application of Li metal anodes (LMAs) is still impeded due to its intrinsic issues, including the uncontrolled Li dendrites growth, unstable solid-electrolyte interface (SEI), and the accumulation of "dead Li". The fluorinated materials can stabilize the Li/electrolyte interface, lead to the uniform Li flux and suppress the growth of Li dendrites, thus becoming one of the research hotspots for LMAs. This review summarized recent progress of the fluorinated inorganic materials on constructing Li metal plated skeletons, developing artificial SEI film, introducing electrolyte additives and employing solid-state electrolytes. The rational design and mechanism of these reported fluorinated inorganic materials for stabilizing LMAs were represented. In addition, we also prospected the future research aspects.

, authors=Shaowei LI, Huadong YUAN, Jianmin LUO, Yao WANG, Yujing LIU, Jianwei NAI, Xinyong TAO, authorsList=Shaowei LI, Huadong YUAN, Jianmin LUO, Yao WANG, Yujing LIU, Jianwei NAI, Xinyong TAO, authorCompany=null, correspAuthors=Huadong YUAN, Xinyong TAO, authorNote=

LI Shaowei (1997-), male, Master candidate. E-mail:

, correspAuthorsNote=
TAO Xinyong (1979-), male, Ph.D., Professor. E-mail:
YUAN Huadong (1990-), male, Ph.D..
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1318976918096032419, articleId=1318976917584327329, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=氟化无机材料在金属锂负极中的应用, columnId=1321890863219856123, journalTitle=硅酸盐学报, columnName=无机非金属材料及技术创新助力实现双碳目标专刊—综合评述, runingTitle=null, highlight=null, articleAbstract=

金属锂被认为是高能量密度电池材料的“圣杯”,具有超高的理论容量和最低的氧化还原电位。但由于锂枝晶不可控生长、固体电解质界面膜(SEI膜)不稳定以及“死锂”累积等系列问题,限制了其商业化应用。氟化材料能有效稳定金属锂/电解液界面,均匀锂离子通量和抑制锂枝晶生长,是金属锂二次电池领域的研究重点。本文综述了近年来氟化无机材料在金属锂沉积骨架、人工SEI保护层、电解液添加剂以及固态电解质等方面的研究进展,阐述了氟化无机材料稳定金属锂负极循环的内在机理,并展望了其未来的发展前景。

, authors=李少为, 袁华栋, 罗剑敏, 王垚, 刘育京, 佴建威, 陶新永, authorsList=李少为, 袁华栋, 罗剑敏, 王垚, 刘育京, 佴建威, 陶新永, authorCompany=null, correspAuthors=袁华栋, 陶新永, authorNote=

李少为(1997—),男,硕士研究生。

, correspAuthorsNote=
陶新永(1979—),男,博士,教授;
袁华栋(1990—),男,博士。
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李少为(1997—),男,硕士研究生。

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氟化无机材料在金属锂负极中的应用
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李少为 , 袁华栋 , 罗剑敏 , 王垚 , 刘育京 , 佴建威 , 陶新永
硅酸盐学报 | 无机非金属材料及技术创新助力实现双碳目标专刊—综合评述 2023,51(9): 2322-2333
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硅酸盐学报 |无机非金属材料及技术创新助力实现双碳目标专刊—综合评述 2023 , 51 (9) : 2322 -2333
氟化无机材料在金属锂负极中的应用
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李少为 , 袁华栋 , 罗剑敏, 王垚, 刘育京, 佴建威, 陶新永
作者信息
  • 浙江工业大学材料科学与工程学院,杭州 310014
通讯作者:
陶新永(1979—),男,博士,教授;
袁华栋(1990—),男,博士。
作者简介:

李少为(1997—),男,硕士研究生。

Fluorinated Inorganic Materials for Lithium Metal Anodes—A Short Review
Shaowei LI , Huadong YUAN , Jianmin LUO, Yao WANG, Yujing LIU, Jianwei NAI, Xinyong TAO
Affiliations
  • College of Materials Science and Engineering, Zhejiang University of Technology, Hangzhou 310014, China
  • Corresponding Author:
    TAO Xinyong (1979-), male, Ph.D., Professor. E-mail:
    YUAN Huadong (1990-), male, Ph.D..

    LI Shaowei (1997-), male, Master candidate. E-mail:

出版时间: 2023-09-20 doi: 10.14062/j.issn.0454-5648.20230109
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金属锂被认为是高能量密度电池材料的“圣杯”,具有超高的理论容量和最低的氧化还原电位。但由于锂枝晶不可控生长、固体电解质界面膜(SEI膜)不稳定以及“死锂”累积等系列问题,限制了其商业化应用。氟化材料能有效稳定金属锂/电解液界面,均匀锂离子通量和抑制锂枝晶生长,是金属锂二次电池领域的研究重点。本文综述了近年来氟化无机材料在金属锂沉积骨架、人工SEI保护层、电解液添加剂以及固态电解质等方面的研究进展,阐述了氟化无机材料稳定金属锂负极循环的内在机理,并展望了其未来的发展前景。

金属锂负极  /  锂枝晶  /  固体电解质界面膜  /  氟化  /  锂离子电池

Lithium (Li) metal is considered as the "Holy Grail" anode material for next-generation high-energy density battery system due to its high theoretical capacity and lowest reduction potential. However, the practical application of Li metal anodes (LMAs) is still impeded due to its intrinsic issues, including the uncontrolled Li dendrites growth, unstable solid-electrolyte interface (SEI), and the accumulation of "dead Li". The fluorinated materials can stabilize the Li/electrolyte interface, lead to the uniform Li flux and suppress the growth of Li dendrites, thus becoming one of the research hotspots for LMAs. This review summarized recent progress of the fluorinated inorganic materials on constructing Li metal plated skeletons, developing artificial SEI film, introducing electrolyte additives and employing solid-state electrolytes. The rational design and mechanism of these reported fluorinated inorganic materials for stabilizing LMAs were represented. In addition, we also prospected the future research aspects.

lithium metal anode  /  lithium dendrites  /  solid-electrolyte interface  /  fluorination  /  lithium-ion battery
李少为, 袁华栋, 罗剑敏, 王垚, 刘育京, 佴建威, 陶新永. 氟化无机材料在金属锂负极中的应用. 硅酸盐学报, 2023 , 51 (9) : 2322 -2333 . DOI: 10.14062/j.issn.0454-5648.20230109
Shaowei LI, Huadong YUAN, Jianmin LUO, Yao WANG, Yujing LIU, Jianwei NAI, Xinyong TAO. Fluorinated Inorganic Materials for Lithium Metal Anodes—A Short Review[J]. Journal of the Chinese Ceramic Society, 2023 , 51 (9) : 2322 -2333 . DOI: 10.14062/j.issn.0454-5648.20230109
  • 国家自然科学基金(U21A20174; 52225208; 22109137)
  • 浙江省科学基金(LD18E020003; LQ20E030012)
  • 浙江省领先创新团队引进项目(2020R011002)
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2023年第51卷第9期
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doi: 10.14062/j.issn.0454-5648.20230109
  • 接收时间:2023-02-28
  • 首发时间:2026-10-19
  • 出版时间:2023-09-20
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  • 收稿日期:2023-02-28
  • 修回日期:2023-03-23
基金
国家自然科学基金(U21A20174; 52225208; 22109137)
浙江省科学基金(LD18E020003; LQ20E030012)
浙江省领先创新团队引进项目(2020R011002)
作者信息
    浙江工业大学材料科学与工程学院,杭州 310014

通讯作者:

陶新永(1979—),男,博士,教授;
袁华栋(1990—),男,博士。
参考文献
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https://castjournals.cast.org.cn/joweb/gsyxb/CN/10.14062/j.issn.0454-5648.20230109
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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