Article(id=1318976883140707219, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318976874252980746, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20230105, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1677427200000, receivedDateStr=2023-02-27, revisedDate=1681488000000, revisedDateStr=2023-04-15, acceptedDate=null, acceptedDateStr=null, onlineDate=1792398194345, onlineDateStr=2026-10-19, pubDate=1695139200000, pubDateStr=2023-09-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792398194345, onlineIssueDateStr=2026-10-19, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792398194345, creator=13701087609, updateTime=1792398194345, updator=13701087609, issue=Issue{id=1318976874252980746, tenantId=1146029695717560320, journalId=1263187385517883426, year='2023', volume='51', issue='9', pageStart='2119', pageEnd='2516', issueExtLink='null', onlineDate='null', pubDate='1695139200000', pubDateStr='2023-09-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1792398192226, creator='13701087609', updateTime=1792399292764, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1318981490315210817, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318976874252980746, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1318981490315210818, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318976874252980746, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=2254, endPage=2270, ext={EN=ArticleExt(id=1318976884323500949, articleId=1318976883140707219, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Research Progress on 3D/2D Multi-Dimensional Perovskite Materials and Photovoltaic Devices, columnId=1321890862989169402, journalTitle=Journal of the Chinese Ceramic Society, columnName=Special Issue Innovation of Inorganic Non-Metallic Materials and Technologies to Support “Dual-Carbon” Goal—Review, runingTitle=null, highlight=null, articleAbstract=

As a typical light-absorber, the three-dimensional (3D) metal halide perovskite materials exhibit superior optoelectronic properties (i.e., the low binding energy, long carrier lifetime and diffusion length, and high defect tolerance). The 3D perovskite-based perovskite solar cells (PSCs) show the excellent photoelectric conversion efficiency. However, its sensitivity to light, heat, and humidity as well as other environment factors restrict its practical application. Compared with three-dimensional perovskite, two-dimensional (2D) perovskites with high exciton binding energy and stable chemical properties enhance the long-term stability of devices. Combined with 2D perovskite, 3D/2D multi-dimensional perovskite cells can deliver a superior stability without a sacrificing efficiency. This review summarized the crystal structure and stability of 2D perovskite, and highlighted the research advances about the preparation technology and stability of 3D/2D multi-dimensional perovskite materials and relative photovoltaic devices. In addition, the further improvement of efficiency and stability of 3D/2D multidimensional PSCs was also prospected, thus providing a guidance for the commercialization of perovskite photovoltaic.

, authors=Long LUO, Shangzhi LI, Yingying SHI, Miaomiao ZENG, Jie ZHAO, Hong LIANG, Lin LI, Xiong LI, authorsList=Long LUO, Shangzhi LI, Yingying SHI, Miaomiao ZENG, Jie ZHAO, Hong LIANG, Lin LI, Xiong LI, authorCompany=null, correspAuthors=Xiong LI, authorNote=

LUO Long (1994-), male, Doctoral candidate. E-mail:

, correspAuthorsNote=
Li Xiong (1981-), male, Ph.D., Professor. E-mail:
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1318976888089985943, articleId=1318976883140707219, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=三维/二维多维度钙钛矿材料及光伏器件性能研究进展, columnId=1321890863219856123, journalTitle=硅酸盐学报, columnName=无机非金属材料及技术创新助力实现双碳目标专刊—综合评述, runingTitle=null, highlight=null, articleAbstract=

作为典型吸光层的三维金属卤化物钙钛矿材料具有较低的结合能、较长的载流子寿命及扩散长度、较高的缺陷容忍度等优异的光电性能,所制备的钙钛矿太阳能电池展现出了优异的光电转化效率。然而,对光、热、湿度等环境的敏感性限制了其实际应用。相比于三维钙钛矿,激子结合能较高、化学性质稳定的二维钙钛矿增强了器件的长期稳定性。与二维钙钛矿结合,三维/二维多维度钙钛矿电池在不损失效率的前提下获得了优越的稳定性。本文主要从二维钙钛矿的晶体结构及稳定性入手,重点阐述了三维/二维多维度钙钛矿的制备工艺及稳定性方面的研究进展,最后对三维/二维多维度钙钛矿太阳能电池效率及稳定性的进一步提升进行了总结与展望,旨在为钙钛矿光伏商业化提供指导。

, authors=罗龙, 李尚志, 史莹莹, 曾苗苗, 赵杰, 梁泓, 李琳, 李雄, authorsList=罗龙, 李尚志, 史莹莹, 曾苗苗, 赵杰, 梁泓, 李琳, 李雄, authorCompany=null, correspAuthors=李雄, authorNote=

罗龙(1994—),男,博士研究生。

, correspAuthorsNote=
李雄(1980—),男,博士,教授。
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三维/二维多维度钙钛矿材料及光伏器件性能研究进展
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罗龙 , 李尚志 , 史莹莹 , 曾苗苗 , 赵杰 , 梁泓 , 李琳 , 李雄
硅酸盐学报 | 无机非金属材料及技术创新助力实现双碳目标专刊—综合评述 2023,51(9): 2254-2270
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硅酸盐学报 |无机非金属材料及技术创新助力实现双碳目标专刊—综合评述 2023 , 51 (9) : 2254 -2270
三维/二维多维度钙钛矿材料及光伏器件性能研究进展
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罗龙(1994—),男,博士研究生。

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罗龙 , 李尚志, 史莹莹, 曾苗苗, 赵杰, 梁泓, 李琳, 李雄
作者信息
  • 华中科技大学,武汉光电国家研究中心,武汉 430074
通讯作者:
李雄(1980—),男,博士,教授。
作者简介:

罗龙(1994—),男,博士研究生。

Research Progress on 3D/2D Multi-Dimensional Perovskite Materials and Photovoltaic Devices
Long LUO , Shangzhi LI, Yingying SHI, Miaomiao ZENG, Jie ZHAO, Hong LIANG, Lin LI, Xiong LI
Affiliations
  • Wuhan National Laboratory for Optoelectronics, Huazhong University of Science and Technology, Wuhan 430074, China
  • Corresponding Author:
    Li Xiong (1981-), male, Ph.D., Professor. E-mail:

    LUO Long (1994-), male, Doctoral candidate. E-mail:

出版时间: 2023-09-20 doi: 10.14062/j.issn.0454-5648.20230105
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作为典型吸光层的三维金属卤化物钙钛矿材料具有较低的结合能、较长的载流子寿命及扩散长度、较高的缺陷容忍度等优异的光电性能,所制备的钙钛矿太阳能电池展现出了优异的光电转化效率。然而,对光、热、湿度等环境的敏感性限制了其实际应用。相比于三维钙钛矿,激子结合能较高、化学性质稳定的二维钙钛矿增强了器件的长期稳定性。与二维钙钛矿结合,三维/二维多维度钙钛矿电池在不损失效率的前提下获得了优越的稳定性。本文主要从二维钙钛矿的晶体结构及稳定性入手,重点阐述了三维/二维多维度钙钛矿的制备工艺及稳定性方面的研究进展,最后对三维/二维多维度钙钛矿太阳能电池效率及稳定性的进一步提升进行了总结与展望,旨在为钙钛矿光伏商业化提供指导。

二维  /  三维/二维多维度钙钛矿  /  太阳能电池

As a typical light-absorber, the three-dimensional (3D) metal halide perovskite materials exhibit superior optoelectronic properties (i.e., the low binding energy, long carrier lifetime and diffusion length, and high defect tolerance). The 3D perovskite-based perovskite solar cells (PSCs) show the excellent photoelectric conversion efficiency. However, its sensitivity to light, heat, and humidity as well as other environment factors restrict its practical application. Compared with three-dimensional perovskite, two-dimensional (2D) perovskites with high exciton binding energy and stable chemical properties enhance the long-term stability of devices. Combined with 2D perovskite, 3D/2D multi-dimensional perovskite cells can deliver a superior stability without a sacrificing efficiency. This review summarized the crystal structure and stability of 2D perovskite, and highlighted the research advances about the preparation technology and stability of 3D/2D multi-dimensional perovskite materials and relative photovoltaic devices. In addition, the further improvement of efficiency and stability of 3D/2D multidimensional PSCs was also prospected, thus providing a guidance for the commercialization of perovskite photovoltaic.

two-dimensional  /  3D/2D multi-dimensional perovskite  /  solar cells
罗龙, 李尚志, 史莹莹, 曾苗苗, 赵杰, 梁泓, 李琳, 李雄. 三维/二维多维度钙钛矿材料及光伏器件性能研究进展. 硅酸盐学报, 2023 , 51 (9) : 2254 -2270 . DOI: 10.14062/j.issn.0454-5648.20230105
Long LUO, Shangzhi LI, Yingying SHI, Miaomiao ZENG, Jie ZHAO, Hong LIANG, Lin LI, Xiong LI. Research Progress on 3D/2D Multi-Dimensional Perovskite Materials and Photovoltaic Devices[J]. Journal of the Chinese Ceramic Society, 2023 , 51 (9) : 2254 -2270 . DOI: 10.14062/j.issn.0454-5648.20230105
  • 国家重点研发计划(2022YFB4200305)
  • 国家自然科学基金(21875081; 22279039)
  • 纺织新材料与先进加工技术国家重点实验室基金(FZ2021011)
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2023年第51卷第9期
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doi: 10.14062/j.issn.0454-5648.20230105
  • 接收时间:2023-02-27
  • 首发时间:2026-10-19
  • 出版时间:2023-09-20
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  • 收稿日期:2023-02-27
  • 修回日期:2023-04-15
基金
国家重点研发计划(2022YFB4200305)
国家自然科学基金(21875081; 22279039)
纺织新材料与先进加工技术国家重点实验室基金(FZ2021011)
作者信息
    华中科技大学,武汉光电国家研究中心,武汉 430074

通讯作者:

李雄(1980—),男,博士,教授。
参考文献
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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