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Article(id=1318978557179707946, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318978537852359595, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20230062, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1676044800000, receivedDateStr=2023-02-11, revisedDate=1681142400000, revisedDateStr=2023-04-11, acceptedDate=null, acceptedDateStr=null, onlineDate=1792398593467, onlineDateStr=2026-10-19, pubDate=1697731200000, pubDateStr=2023-10-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792398593467, onlineIssueDateStr=2026-10-19, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792398593467, creator=13701087609, updateTime=1792398593467, updator=13701087609, issue=Issue{id=1318978537852359595, tenantId=1146029695717560320, journalId=1263187385517883426, year='2023', volume='51', issue='10', pageStart='2517', pageEnd='2738', issueExtLink='null', onlineDate='null', pubDate='1697731200000', pubDateStr='2023-10-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1792398588860, creator='13701087609', updateTime=1792399337892, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1318981679578993157, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318978537852359595, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1318981679578993158, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318978537852359595, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=2689, endPage=2699, ext={EN=ArticleExt(id=1318978558941315627, articleId=1318978557179707946, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Research Progress on Reversible Protonic Ceramic Electrochemical Cell, columnId=1263922772401635899, journalTitle=Journal of the Chinese Ceramic Society, columnName=Review, runingTitle=null, highlight=null, articleAbstract=

Reversible protonic ceramic electrochemical cell (R-PCEC) is an emerging and efficient energy conversion device that can convert chemical energy into electrical energy and electrical energy into chemical energy. The reversible operation of R-PCEC in the dual mode of fuel cell and electrolytic cell is highly flexible and is one of the most promising ways for efficient energy conversion and storage. However, for R-PCEC, the electrolyte conductivity, catalytic activity of the cathode and anode, and durability under actual operating conditions are the main factors restricting its performance. This review introduced the research and development status of each component of R-PCEC in detail, including electrolyte materials, hydrogen electrodes, and air electrodes, as well as mainly focused on the latest progress on material requirements, electrode performance and reaction mechanism of air electrodes for reversible batteries. In addition, the future developments on R-PCEC were also prospected.

, authors=Zhou WANG1, Xiaoliang ZHOU1, 2, Limin LIU1, Hanyu CHEN1, Xinyuan QIAN1, Feifan HE1, Yang SHENG1, Xingzhou JIANG1, authorsList=Zhou WANG, Xiaoliang ZHOU, Limin LIU, Hanyu CHEN, Xinyuan QIAN, Feifan HE, Yang SHENG, Xingzhou JIANG, authorCompany=null, correspAuthors=Xiaoliang ZHOU, authorNote=

WANG Zhou (1996-), male, Master candidate. E-mail:

, correspAuthorsNote=
ZHOU Xiaoliang (1978-), male, Ph.D., Professor. E-mail:
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可逆质子导体陶瓷电化学电池（R-PCEC）是一种既能够将化学能转化为电能，又能将电能转化为化学能的新兴高效能源转换装置。R-PCEC在燃料电池和电解电池双重模式下的可逆操作具有高度灵活性，是能量高效转换和存储最有发展前途的方式之一。然而，对于R-PCEC而言，其在实际操作条件下，电解质电导率，阴阳极的催化活性、耐久性是制约其性能的主要因素。为了对目前国内外R-PCEC技术发展现状形成全面的认识，本文详细介绍了R-PCEC各组成部分的研发现状，包括电解质材料、氢电极和空气电极的研究进展，重点阐述了可逆电池空气电极的材料要求、电极性能和反应机理等最新进展，最后对R-PCEC的发展前景进行了分析和展望。

, authors=王宙1, 周晓亮1, 2, 刘立敏1, 陈晗钰1, 钱欣源1, 何非凡1, 绳阳1, 蒋星洲1, authorsList=王宙, 周晓亮, 刘立敏, 陈晗钰, 钱欣源, 何非凡, 绳阳, 蒋星洲, authorCompany=null, correspAuthors=周晓亮, authorNote=

王宙（1996—），男，硕士研究生。

, correspAuthorsNote=
周晓亮（1978—），男，博士，教授。
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WANG Zhou (1996-), male, Master candidate. E-mail:

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WANG Zhou (1996-), male, Master candidate. E-mail:

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王宙（1996—），男，硕士研究生。

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王宙（1996—），男，硕士研究生。

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可逆质子导体陶瓷电化学电池研究进展
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王宙 1 , 周晓亮 1, 2 , 刘立敏 1 , 陈晗钰 1 , 钱欣源 1 , 何非凡 1 , 绳阳 1 , 蒋星洲 1
硅酸盐学报 | 综合评述 2023,51(10): 2689-2699
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硅酸盐学报 |综合评述 2023 , 51 (10) : 2689 -2699
可逆质子导体陶瓷电化学电池研究进展
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王宙1 , 周晓亮1, 2 , 刘立敏1, 陈晗钰1, 钱欣源1, 何非凡1, 绳阳1, 蒋星洲1
作者信息
  • 1．西南石油大学化学化工学院，成都 610500
  • 2．天府永兴实验室，成都 610042
通讯作者:
周晓亮（1978—），男，博士，教授。
作者简介:

王宙（1996—），男，硕士研究生。

Research Progress on Reversible Protonic Ceramic Electrochemical Cell
Zhou WANG1 , Xiaoliang ZHOU1, 2 , Limin LIU1, Hanyu CHEN1, Xinyuan QIAN1, Feifan HE1, Yang SHENG1, Xingzhou JIANG1
Affiliations
  • 1.College of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu 610500, China
  • 2.Tianfu Yongxing Laboratory, Chengdu 610042, China
    • Corresponding Author:
    ZHOU Xiaoliang (1978-), male, Ph.D., Professor. E-mail:

    WANG Zhou (1996-), male, Master candidate. E-mail:

出版时间: 2023-10-20 doi: 10.14062/j.issn.0454-5648.20230062
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可逆质子导体陶瓷电化学电池（R-PCEC）是一种既能够将化学能转化为电能，又能将电能转化为化学能的新兴高效能源转换装置。R-PCEC在燃料电池和电解电池双重模式下的可逆操作具有高度灵活性，是能量高效转换和存储最有发展前途的方式之一。然而，对于R-PCEC而言，其在实际操作条件下，电解质电导率，阴阳极的催化活性、耐久性是制约其性能的主要因素。为了对目前国内外R-PCEC技术发展现状形成全面的认识，本文详细介绍了R-PCEC各组成部分的研发现状，包括电解质材料、氢电极和空气电极的研究进展，重点阐述了可逆电池空气电极的材料要求、电极性能和反应机理等最新进展，最后对R-PCEC的发展前景进行了分析和展望。

可再生资源  /  电化学储能  /  高温可逆电池  /  质子导体  /  空气电极

Reversible protonic ceramic electrochemical cell (R-PCEC) is an emerging and efficient energy conversion device that can convert chemical energy into electrical energy and electrical energy into chemical energy. The reversible operation of R-PCEC in the dual mode of fuel cell and electrolytic cell is highly flexible and is one of the most promising ways for efficient energy conversion and storage. However, for R-PCEC, the electrolyte conductivity, catalytic activity of the cathode and anode, and durability under actual operating conditions are the main factors restricting its performance. This review introduced the research and development status of each component of R-PCEC in detail, including electrolyte materials, hydrogen electrodes, and air electrodes, as well as mainly focused on the latest progress on material requirements, electrode performance and reaction mechanism of air electrodes for reversible batteries. In addition, the future developments on R-PCEC were also prospected.

renewable resources  /  electrochemical energy storage  /  high-temperature reversible cells  /  proton conductor  /  air electrode
王宙, 周晓亮, 刘立敏, 陈晗钰, 钱欣源, 何非凡, 绳阳, 蒋星洲. 可逆质子导体陶瓷电化学电池研究进展. 硅酸盐学报, 2023 , 51 (10) : 2689 -2699 . DOI: 10.14062/j.issn.0454-5648.20230062
Zhou WANG, Xiaoliang ZHOU, Limin LIU, Hanyu CHEN, Xinyuan QIAN, Feifan HE, Yang SHENG, Xingzhou JIANG. Research Progress on Reversible Protonic Ceramic Electrochemical Cell[J]. Journal of the Chinese Ceramic Society, 2023 , 51 (10) : 2689 -2699 . DOI: 10.14062/j.issn.0454-5648.20230062
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  • 国家自然科学基金面上项目(22075231; 21875056)
  • “氢能技术”国家重点研发计划(2021YFB4001502)
  • 四川省重点研发项目（省院省校科技合作）(2020YFSY0026; 2021YFSY0022)
  • 天府实验室碳中和科技创新基地建设(2021ZYD0099)
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2023年第51卷第10期
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doi: 10.14062/j.issn.0454-5648.20230062
  • 接收时间：2023-02-11
  • 首发时间：2026-10-19
  • 出版时间：2023-10-20
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出版历史
  • 收稿日期：2023-02-11
  • 修回日期：2023-04-11
基金
国家自然科学基金面上项目(22075231; 21875056)
“氢能技术”国家重点研发计划(2021YFB4001502)
四川省重点研发项目（省院省校科技合作）(2020YFSY0026; 2021YFSY0022)
天府实验室碳中和科技创新基地建设(2021ZYD0099)
作者信息
    1．西南石油大学化学化工学院，成都 610500
    2．天府永兴实验室，成都 610042

通讯作者:

周晓亮（1978—），男，博士，教授。
参考文献
分享链接
https://castjournals.cast.org.cn/joweb/gsyxb/CN/10.14062/j.issn.0454-5648.20230062
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2种不同金属材料的力学参数
科
Family		 属数
Number of
genus		 种数
Number of
species		 占总种数比例
Percentage of
total species (%)		 属
Genus		 种数
Number of
species		 占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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