Article(id=1318974538549941073, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318974513019207979, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20230045, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1675353600000, receivedDateStr=2023-02-03, revisedDate=1676736000000, revisedDateStr=2023-02-19, acceptedDate=null, acceptedDateStr=null, onlineDate=1792397635351, onlineDateStr=2026-10-19, pubDate=1686153600000, pubDateStr=2023-06-08, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792397635351, onlineIssueDateStr=2026-10-19, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792397635351, creator=13701087609, updateTime=1792397635351, updator=13701087609, issue=Issue{id=1318974513019207979, tenantId=1146029695717560320, journalId=1263187385517883426, year='2023', volume='51', issue='7', pageStart='1649', pageEnd='1882', issueExtLink='null', onlineDate='null', pubDate='1689782400000', pubDateStr='2023-07-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1792397629265, creator='13701087609', updateTime=1792399256269, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1318981337223119779, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318974513019207979, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1318981337223119780, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318974513019207979, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1724, endPage=1732, ext={EN=ArticleExt(id=1318974538730296146, articleId=1318974538549941073, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Template-Assisted Synthesis of Iron Phosphide Hollow Nanorods and Its Electrochemical Properties, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=

As energy storage materials, transition metal phosphides have attracted recent attention. In this paper, FeP hollow nanorods were fabricated with hydrothermally synthesized MoO3 nanofibers as a template. The chemical composition, morphological structure and synthetic process of such a product were characterized. Its supercapacitive properties as an electrode material were also investigated. The results show that the developed FeP hollow nanorods have a porous nature with the specific surface area (i.e., 277.4 m2/g) and well-defined interior of about 30 nm thick shell due to the stack, aggregation and adhesion of FeP nanoparticles. The FeP hollow nanorod electrode with a unique morphological structure and a large specific surface area has a superior supercapacitive behavior with the maximum specific capacitance of 243.6 F/g, remarkable rate capability as well as outstanding cycling stability. The capacitance decay of only 13.8% can be achieved after consecutive charge/discharge for 10 000 cycles at a large current density of 5 A/g. The electrochemical performance of FeP hollow nanorods is better than that of some Fe-based supercapacitor electrode materials previously reported.

, authors=Wei XIAO, Qinglin JIANG, Xinyu YANG, Guo LIANG, Xiaobin XIAN, Yanhua ZHANG, authorsList=Wei XIAO, Qinglin JIANG, Xinyu YANG, Guo LIANG, Xiaobin XIAN, Yanhua ZHANG, authorCompany=null, correspAuthors=null, authorNote=

XIAO Wei (1984-), male, Ph.D., Associate Professor. E-mail:

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作为储能材料,过渡金属磷化物在近年来受到了人们广泛关注。以水热合成的MoO3纳米纤维为模板制备FeP空心纳米棒,系统表征其化学成分、结构形貌和制备过程,并研究其作为超级电容器电极材料的电化学性质。结果表明:FeP空心纳米棒内有空腔,外壁由纳米颗粒堆叠、聚集、粘连而成,厚度约为30 nm,形态完好,具有发达的多孔特性和高达277.4 m2/g的比表面积。得益于这些独特结构形貌和大比表面积,FeP空心纳米棒电极在三电极体系下的最大比电容可达243.6 F/g,且拥有优异的倍率性质和循环稳定性,在5 A/g高电流密度下经历反复充放电10 000次后的电容损失率仅13.8%。FeP空心纳米棒出众的电化学行为能媲美甚至优于许多已报道的铁基超级电容器电极材料的电化学表现,展现出了良好的储能优势。

, authors=肖巍, 蒋青林, 杨欣雨, 梁果, 鲜小彬, 张艳华, authorsList=肖巍, 蒋青林, 杨欣雨, 梁果, 鲜小彬, 张艳华, authorCompany=null, correspAuthors=null, authorNote=

肖巍(1984—),男,博士,副教授。

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模板法合成磷化铁空心纳米棒及其电化学性质
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肖巍 , 蒋青林 , 杨欣雨 , 梁果 , 鲜小彬 , 张艳华
硅酸盐学报 | 研究论文 2023,51(7): 1724-1732
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硅酸盐学报 |研究论文 2023 , 51 (7) : 1724 -1732
模板法合成磷化铁空心纳米棒及其电化学性质
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肖巍 , 蒋青林, 杨欣雨, 梁果, 鲜小彬, 张艳华
作者信息
  • 重庆文理学院材料科学与工程学院,重庆 402160
作者简介:

肖巍(1984—),男,博士,副教授。

Template-Assisted Synthesis of Iron Phosphide Hollow Nanorods and Its Electrochemical Properties
Wei XIAO , Qinglin JIANG, Xinyu YANG, Guo LIANG, Xiaobin XIAN, Yanhua ZHANG
Affiliations
  • School of Materials Science and Engineering, Chongqing University of Arts and Sciences, Chongqing 402160, China
  • XIAO Wei (1984-), male, Ph.D., Associate Professor. E-mail:

出版时间: 2023-06-08 doi: 10.14062/j.issn.0454-5648.20230045
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作为储能材料,过渡金属磷化物在近年来受到了人们广泛关注。以水热合成的MoO3纳米纤维为模板制备FeP空心纳米棒,系统表征其化学成分、结构形貌和制备过程,并研究其作为超级电容器电极材料的电化学性质。结果表明:FeP空心纳米棒内有空腔,外壁由纳米颗粒堆叠、聚集、粘连而成,厚度约为30 nm,形态完好,具有发达的多孔特性和高达277.4 m2/g的比表面积。得益于这些独特结构形貌和大比表面积,FeP空心纳米棒电极在三电极体系下的最大比电容可达243.6 F/g,且拥有优异的倍率性质和循环稳定性,在5 A/g高电流密度下经历反复充放电10 000次后的电容损失率仅13.8%。FeP空心纳米棒出众的电化学行为能媲美甚至优于许多已报道的铁基超级电容器电极材料的电化学表现,展现出了良好的储能优势。

超级电容器  /  磷化铁  /  模板合成  /  空心纳米棒  /  电极材料

As energy storage materials, transition metal phosphides have attracted recent attention. In this paper, FeP hollow nanorods were fabricated with hydrothermally synthesized MoO3 nanofibers as a template. The chemical composition, morphological structure and synthetic process of such a product were characterized. Its supercapacitive properties as an electrode material were also investigated. The results show that the developed FeP hollow nanorods have a porous nature with the specific surface area (i.e., 277.4 m2/g) and well-defined interior of about 30 nm thick shell due to the stack, aggregation and adhesion of FeP nanoparticles. The FeP hollow nanorod electrode with a unique morphological structure and a large specific surface area has a superior supercapacitive behavior with the maximum specific capacitance of 243.6 F/g, remarkable rate capability as well as outstanding cycling stability. The capacitance decay of only 13.8% can be achieved after consecutive charge/discharge for 10 000 cycles at a large current density of 5 A/g. The electrochemical performance of FeP hollow nanorods is better than that of some Fe-based supercapacitor electrode materials previously reported.

supercapacitor  /  iron phosphide  /  template synthesis  /  hollow nanorod  /  electrode material
肖巍, 蒋青林, 杨欣雨, 梁果, 鲜小彬, 张艳华. 模板法合成磷化铁空心纳米棒及其电化学性质. 硅酸盐学报, 2023 , 51 (7) : 1724 -1732 . DOI: 10.14062/j.issn.0454-5648.20230045
Wei XIAO, Qinglin JIANG, Xinyu YANG, Guo LIANG, Xiaobin XIAN, Yanhua ZHANG. Template-Assisted Synthesis of Iron Phosphide Hollow Nanorods and Its Electrochemical Properties[J]. Journal of the Chinese Ceramic Society, 2023 , 51 (7) : 1724 -1732 . DOI: 10.14062/j.issn.0454-5648.20230045
  • 重庆市永川区自然科学基金(2022yc-jckx20011)
  • 重庆文理学院重大培育项目(P2020CL02)
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doi: 10.14062/j.issn.0454-5648.20230045
  • 接收时间:2023-02-03
  • 首发时间:2026-10-19
  • 出版时间:2023-06-08
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  • 收稿日期:2023-02-03
  • 修回日期:2023-02-19
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重庆市永川区自然科学基金(2022yc-jckx20011)
重庆文理学院重大培育项目(P2020CL02)
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    重庆文理学院材料科学与工程学院,重庆 402160
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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