Article(id=1319222747595649802, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222716851405704, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20230044, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1675267200000, receivedDateStr=2023-02-02, revisedDate=1677859200000, revisedDateStr=2023-03-04, acceptedDate=null, acceptedDateStr=null, onlineDate=1792456813000, onlineDateStr=2026-10-20, pubDate=1687190400000, pubDateStr=2023-06-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792456813000, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792456813000, creator=13701087609, updateTime=1792456813000, updator=13701087609, issue=Issue{id=1319222716851405704, tenantId=1146029695717560320, journalId=1263187385517883426, year='2023', volume='51', issue='6', pageStart='1373', pageEnd='1648', issueExtLink='null', onlineDate='null', pubDate='1687190400000', pubDateStr='2023-06-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792456805669, creator='13701087609', updateTime=1792456995739, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319223514108903801, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222716851405704, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319223514108903802, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222716851405704, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1499, endPage=1509, ext={EN=ArticleExt(id=1319222747826336523, articleId=1319222747595649802, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Effect of Fe2O3 Addition on Phase Composition and Fabric and Densification Evolution of Ca2Mg2Al28O46, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=

Ca2Mg2Al28O46 (C2M2A14) refractory has a superior high-temperature performance for high-temperature kilns. In this paper, a ternary compounds-C2M2A14 was synthesized via high-temperature solid-state reaction sintering. Effects of firing temperature and Fe2O3 addition on the phase composition, fabric and densification evolution of the specimens were investigated. The results show that the C2M2A14 is generated by the reaction of CaAl12O19 (CA6) with spinel at 1 650 ℃, and is produced in large quantities at 1 750 ℃. The densification evolution is accelerated with the transformation from hexagonal lamellar CA6 to polyhedron C2M2A14 and the appearance of eutectic liquid. The hexagonal plate of (1,1,15) preferred orientation is changed to the rhombohedral of (119) preferred orientation after adding Fe2O3, and the densification evolution is promoted, and more dense synthetic products can be obtained at the same firing temperature due to the solid solution strengthening of Fe ions. The apparent porosity, water absorption, and bulk density of C2M2A14 (1% Fe2O3) specimen fired at 1 780 ℃ for 3 h are 12.5%, 3.9%, and 3.20 g·cm-3, respectively. A high-temperature refractory is obtained.

, authors=Yun LIU, Hongfeng YIN, Yun TANG, Yalou XIN, Xiaohu REN, Hudie YUAN, Kewei SUN, authorsList=Yun LIU, Hongfeng YIN, Yun TANG, Yalou XIN, Xiaohu REN, Hudie YUAN, Kewei SUN, authorCompany=null, correspAuthors=Hongfeng YIN, authorNote=

LIU Yun (1996-), female, Doctoral candidate. E-mail:

, correspAuthorsNote=
YIN Hongfeng (1965-), male, Ph.D., Professor. E-mail:
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1319222748145103628, articleId=1319222747595649802, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=Fe2O3对Ca2Mg2Al28O46相组成与组构及其致密化进程的影响, columnId=1263922770220560512, journalTitle=硅酸盐学报, columnName=研究论文, runingTitle=null, highlight=null, articleAbstract=

Ca2Mg2Al28O46(C2M2A14)耐火材料具有优异的高温使用性能,为了将这类耐火材料应用在高温窑炉,本工作采用高温固相反应烧结法合成了三元化合物C2M2A14,研究了烧成温度及添加1%(质量分数)Fe2O3对试样相组成演变与组构及其致密化进程的影响。结果表明:C2M2A14在1 650 ℃由六铝酸钙(CA6)与尖晶石反应生成,在1 750 ℃大量生成,随着六方板状CA6转化为多面体C2M2A14和低共熔液相的出现,致密化进程加快。加入Fe2O3后,由原来(1,1,15)晶面择优取向的六方板状晶体转变为(119)晶面择优取向的菱面体,同时由于Fe离子的固溶活化作用,促进了致密化进程,相同烧成温度可获得更加致密的合成产物,经1 780 ℃保温3 h烧成制备的C2M2A14试样显气孔率为12.5%、吸水率为3.9%、体积密度为3.20 g·cm-3,获得了一种高温耐火材料。

, authors=刘云, 尹洪峰, 汤云, 辛亚楼, 任小虎, 袁蝴蝶, 孙可为, authorsList=刘云, 尹洪峰, 汤云, 辛亚楼, 任小虎, 袁蝴蝶, 孙可为, authorCompany=null, correspAuthors=尹洪峰, authorNote=

刘云(1996—),女,博士研究生。

, correspAuthorsNote=
尹洪峰(1965—),男,博士,教授。
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刘云(1996—),女,博士研究生。

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刘云(1996—),女,博士研究生。

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Fe2O3对Ca2Mg2Al28O46相组成与组构及其致密化进程的影响
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刘云 , 尹洪峰 , 汤云 , 辛亚楼 , 任小虎 , 袁蝴蝶 , 孙可为
硅酸盐学报 | 研究论文 2023,51(6): 1499-1509
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硅酸盐学报 |研究论文 2023 , 51 (6) : 1499 -1509
Fe2O3对Ca2Mg2Al28O46相组成与组构及其致密化进程的影响
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刘云 , 尹洪峰 , 汤云, 辛亚楼, 任小虎, 袁蝴蝶, 孙可为
作者信息
  • 西安建筑科技大学材料科学与工程学院,西安 710055
通讯作者:
尹洪峰(1965—),男,博士,教授。
作者简介:

刘云(1996—),女,博士研究生。

Effect of Fe2O3 Addition on Phase Composition and Fabric and Densification Evolution of Ca2Mg2Al28O46
Yun LIU , Hongfeng YIN , Yun TANG, Yalou XIN, Xiaohu REN, Hudie YUAN, Kewei SUN
Affiliations
  • College of Materials Science and Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China
  • Corresponding Author:
    YIN Hongfeng (1965-), male, Ph.D., Professor. E-mail:

    LIU Yun (1996-), female, Doctoral candidate. E-mail:

出版时间: 2023-06-20 doi: 10.14062/j.issn.0454-5648.20230044
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Ca2Mg2Al28O46(C2M2A14)耐火材料具有优异的高温使用性能,为了将这类耐火材料应用在高温窑炉,本工作采用高温固相反应烧结法合成了三元化合物C2M2A14,研究了烧成温度及添加1%(质量分数)Fe2O3对试样相组成演变与组构及其致密化进程的影响。结果表明:C2M2A14在1 650 ℃由六铝酸钙(CA6)与尖晶石反应生成,在1 750 ℃大量生成,随着六方板状CA6转化为多面体C2M2A14和低共熔液相的出现,致密化进程加快。加入Fe2O3后,由原来(1,1,15)晶面择优取向的六方板状晶体转变为(119)晶面择优取向的菱面体,同时由于Fe离子的固溶活化作用,促进了致密化进程,相同烧成温度可获得更加致密的合成产物,经1 780 ℃保温3 h烧成制备的C2M2A14试样显气孔率为12.5%、吸水率为3.9%、体积密度为3.20 g·cm-3,获得了一种高温耐火材料。

钙镁铝氧化物  /  相组成演变  /  组构  /  致密化进程

Ca2Mg2Al28O46 (C2M2A14) refractory has a superior high-temperature performance for high-temperature kilns. In this paper, a ternary compounds-C2M2A14 was synthesized via high-temperature solid-state reaction sintering. Effects of firing temperature and Fe2O3 addition on the phase composition, fabric and densification evolution of the specimens were investigated. The results show that the C2M2A14 is generated by the reaction of CaAl12O19 (CA6) with spinel at 1 650 ℃, and is produced in large quantities at 1 750 ℃. The densification evolution is accelerated with the transformation from hexagonal lamellar CA6 to polyhedron C2M2A14 and the appearance of eutectic liquid. The hexagonal plate of (1,1,15) preferred orientation is changed to the rhombohedral of (119) preferred orientation after adding Fe2O3, and the densification evolution is promoted, and more dense synthetic products can be obtained at the same firing temperature due to the solid solution strengthening of Fe ions. The apparent porosity, water absorption, and bulk density of C2M2A14 (1% Fe2O3) specimen fired at 1 780 ℃ for 3 h are 12.5%, 3.9%, and 3.20 g·cm-3, respectively. A high-temperature refractory is obtained.

calcium magnesium aluminum oxide  /  phase composition  /  fabric  /  densification evolution
刘云, 尹洪峰, 汤云, 辛亚楼, 任小虎, 袁蝴蝶, 孙可为. Fe2O3对Ca2Mg2Al28O46相组成与组构及其致密化进程的影响. 硅酸盐学报, 2023 , 51 (6) : 1499 -1509 . DOI: 10.14062/j.issn.0454-5648.20230044
Yun LIU, Hongfeng YIN, Yun TANG, Yalou XIN, Xiaohu REN, Hudie YUAN, Kewei SUN. Effect of Fe2O3 Addition on Phase Composition and Fabric and Densification Evolution of Ca2Mg2Al28O46[J]. Journal of the Chinese Ceramic Society, 2023 , 51 (6) : 1499 -1509 . DOI: 10.14062/j.issn.0454-5648.20230044
  • 国家自然科学基金(51572213)
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2023年第51卷第6期
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doi: 10.14062/j.issn.0454-5648.20230044
  • 接收时间:2023-02-02
  • 首发时间:2026-10-20
  • 出版时间:2023-06-20
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  • 收稿日期:2023-02-02
  • 修回日期:2023-03-04
基金
国家自然科学基金(51572213)
作者信息
    西安建筑科技大学材料科学与工程学院,西安 710055

通讯作者:

尹洪峰(1965—),男,博士,教授。
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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