Article(id=1319222717543461377, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222716851405704, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20230015, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1673366400000, receivedDateStr=2023-01-11, revisedDate=1675872000000, revisedDateStr=2023-02-09, acceptedDate=null, acceptedDateStr=null, onlineDate=1792456805835, onlineDateStr=2026-10-20, pubDate=1687190400000, pubDateStr=2023-06-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792456805835, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792456805835, creator=13701087609, updateTime=1792456805835, updator=13701087609, issue=Issue{id=1319222716851405704, tenantId=1146029695717560320, journalId=1263187385517883426, year='2023', volume='51', issue='6', pageStart='1373', pageEnd='1648', issueExtLink='null', onlineDate='null', pubDate='1687190400000', pubDateStr='2023-06-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792456805669, creator='13701087609', updateTime=1792456995739, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319223514108903801, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222716851405704, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319223514108903802, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222716851405704, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1381, endPage=1389, ext={EN=ArticleExt(id=1319222717748982274, articleId=1319222717543461377, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Dynamic Evolution Behavior and Kinematic Characteristics of Each Pits on (111) Crystal Face of CaF2 Crystals, columnId=1321890965510538116, journalTitle=Journal of the Chinese Ceramic Society, columnName=Special Topics Progress of Fundamental Research of Crystal Structures and Defects—Research Articles, runingTitle=null, highlight=null, articleAbstract=

The application of CaF2 crystal in photolithographic machine becomes a hot research topic. However, differentdefects in the crystal seriously restrict its actual performance. In this paper, the morphological and spatial extension characteristics of etch pits formed by the crystal face (111) of CaF2 crystal were observed, and the corresponding defect characteristics of various etch pits were analyzed, which is aprerequisite for the accurate characterization and control of crystal defects. The results show that the etch pits on the crystal face (111) of CaF2 have three types, i.e., triangular conical pit, cone-flat bottom pit and flat bottom pit. Triangular conical pits and cone-flat bottom pits have directional movement characteristics, indicating that the corresponding defects of these pits are related to the dislocations of the materials. However, there is no spatial extension in the flat bottom pit, which is formed after the defects are completely corroded, and the corresponding defects may be the remains of local defects such as impurities, vacancies and small dislocation rings. The physical parameters of the formation process of the etch pit are obtained, and the kinematic model of the etch pit is establishedby tracking the evolution process of the etch pit in real time. This work provides a basis for further studiesonthe corrosion theory of crystal materials.

, authors=Gang TANG1, 2, 3, Bo Zhang3, Mengjun LI3, 4, Yongzhe WANG3, Huamin KOU3, Jingya WANG3, Zhonghan ZHANG3, Dapeng JIANG3, Liangbi SU1, 2, 3, authorsList=Gang TANG, Bo Zhang, Mengjun LI, Yongzhe WANG, Huamin KOU, Jingya WANG, Zhonghan ZHANG, Dapeng JIANG, Liangbi SU, authorCompany=null, correspAuthors=Bo Zhang, Liangbi SU, authorNote=

TANG Gang (1997-), male, Master candidate. E-mail:

, correspAuthorsNote=
SU Liangbi (1979-), male, Professor. E-mail:
ZHANG Bo (1986-), female, Assistant Research fellow.
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1319222718063555075, articleId=1319222717543461377, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=CaF2晶体(111)晶面腐蚀坑的动态演变行为与运动学特性, columnId=1321890966106129285, journalTitle=硅酸盐学报, columnName=晶体结构与缺陷相关基础研究进展专题—研究论文, runingTitle=null, highlight=null, articleAbstract=

CaF2晶体在光刻机中应用成为国内外研究的热点,而晶体中存在各种缺陷严重制约其实际性能。本文跟踪观察了CaF2晶体(111)晶面形成的腐蚀坑的形貌特征和空间延伸特性,并分析了各种腐蚀坑所对应的缺陷特性,是实现对晶体缺陷精确表征与控制的前提。研究表明:CaF2晶体(111)晶面的腐蚀坑具有三角锥形坑、锥形-平底坑、平底坑3种类型。三角锥形坑与锥形-平底坑具有定向移动特性,这表明这类腐蚀坑所对应的缺陷与材料的位错相关,其中:三角锥形坑的坑尖又有3种不同的精细结构,因此所对应的位错至少有3种晶体学走向;而平底坑没有观测到具有空间延伸特性,是缺陷被完全腐蚀后留下的尸体残余,其所对应的缺陷可能是杂质、空位、小的位错环等。通过实时追踪腐蚀坑的演化过程,获得腐蚀坑形成过程的物理参数,建立蚀坑的运动学模型,这也为进一步研究晶体材料的腐蚀理论提供基础。

, authors=汤港1, 2, 3, 张博3, 李梦君3, 4, 王墉哲3, 寇华敏3, 王静雅3, 张中晗3, 姜大朋3, 苏良碧1, 2, 3, authorsList=汤港, 张博, 李梦君, 王墉哲, 寇华敏, 王静雅, 张中晗, 姜大朋, 苏良碧, authorCompany=null, correspAuthors=张博, 苏良碧, authorNote=

汤港(1997—),男,硕士研究生。

, correspAuthorsNote=
苏良碧(1979—),男,博士,研究员。
张博(1986—),女,博士,助理研究员。
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2.Ganjiang Innovation Academy, Chinese Academy of Sciences, Ganzhou 341001, Jiangxi, China
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TANG Gang (1997-), male, Master candidate. E-mail:

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CaF2晶体(111)晶面腐蚀坑的动态演变行为与运动学特性
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汤港 1, 2, 3 , 张博 3 , 李梦君 3, 4 , 王墉哲 3 , 寇华敏 3 , 王静雅 3 , 张中晗 3 , 姜大朋 3 , 苏良碧 1, 2, 3
硅酸盐学报 | 晶体结构与缺陷相关基础研究进展专题—研究论文 2023,51(6): 1381-1389
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硅酸盐学报 |晶体结构与缺陷相关基础研究进展专题—研究论文 2023 , 51 (6) : 1381 -1389
CaF2晶体(111)晶面腐蚀坑的动态演变行为与运动学特性
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汤港1, 2, 3 , 张博3 , 李梦君3, 4, 王墉哲3, 寇华敏3, 王静雅3, 张中晗3, 姜大朋3, 苏良碧1, 2, 3
作者信息
  • 1.南昌大学物理与材料学院,南昌 330031
  • 2.中国科学院赣江创新研究院,江西 赣州 341001
  • 3.中国科学院上海硅酸盐研究所,上海 201899
  • 4.上海电力大学,上海 200090
通讯作者:
苏良碧(1979—),男,博士,研究员。
张博(1986—),女,博士,助理研究员。
作者简介:

汤港(1997—),男,硕士研究生。

Dynamic Evolution Behavior and Kinematic Characteristics of Each Pits on (111) Crystal Face of CaF2 Crystals
Gang TANG1, 2, 3 , Bo Zhang3 , Mengjun LI3, 4, Yongzhe WANG3, Huamin KOU3, Jingya WANG3, Zhonghan ZHANG3, Dapeng JIANG3, Liangbi SU1, 2, 3
Affiliations
  • 1.School of Physics and Materials, Nanchang University, Nanchang 330031, China
  • 2.Ganjiang Innovation Academy, Chinese Academy of Sciences, Ganzhou 341001, Jiangxi, China
  • 3.Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 201899, China
  • 4.Shanghai University of Electric Power, Shanghai 200090, China
  • Corresponding Author:
    SU Liangbi (1979-), male, Professor. E-mail:
    ZHANG Bo (1986-), female, Assistant Research fellow.

    TANG Gang (1997-), male, Master candidate. E-mail:

出版时间: 2023-06-20 doi: 10.14062/j.issn.0454-5648.20230015
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CaF2晶体在光刻机中应用成为国内外研究的热点,而晶体中存在各种缺陷严重制约其实际性能。本文跟踪观察了CaF2晶体(111)晶面形成的腐蚀坑的形貌特征和空间延伸特性,并分析了各种腐蚀坑所对应的缺陷特性,是实现对晶体缺陷精确表征与控制的前提。研究表明:CaF2晶体(111)晶面的腐蚀坑具有三角锥形坑、锥形-平底坑、平底坑3种类型。三角锥形坑与锥形-平底坑具有定向移动特性,这表明这类腐蚀坑所对应的缺陷与材料的位错相关,其中:三角锥形坑的坑尖又有3种不同的精细结构,因此所对应的位错至少有3种晶体学走向;而平底坑没有观测到具有空间延伸特性,是缺陷被完全腐蚀后留下的尸体残余,其所对应的缺陷可能是杂质、空位、小的位错环等。通过实时追踪腐蚀坑的演化过程,获得腐蚀坑形成过程的物理参数,建立蚀坑的运动学模型,这也为进一步研究晶体材料的腐蚀理论提供基础。

氟化钙晶体  /  (111)晶面  /  缺陷  /  位错  /  腐蚀坑

The application of CaF2 crystal in photolithographic machine becomes a hot research topic. However, differentdefects in the crystal seriously restrict its actual performance. In this paper, the morphological and spatial extension characteristics of etch pits formed by the crystal face (111) of CaF2 crystal were observed, and the corresponding defect characteristics of various etch pits were analyzed, which is aprerequisite for the accurate characterization and control of crystal defects. The results show that the etch pits on the crystal face (111) of CaF2 have three types, i.e., triangular conical pit, cone-flat bottom pit and flat bottom pit. Triangular conical pits and cone-flat bottom pits have directional movement characteristics, indicating that the corresponding defects of these pits are related to the dislocations of the materials. However, there is no spatial extension in the flat bottom pit, which is formed after the defects are completely corroded, and the corresponding defects may be the remains of local defects such as impurities, vacancies and small dislocation rings. The physical parameters of the formation process of the etch pit are obtained, and the kinematic model of the etch pit is establishedby tracking the evolution process of the etch pit in real time. This work provides a basis for further studiesonthe corrosion theory of crystal materials.

calcium fluoride crystal  /  (111) surface  /  defects  /  dislocation  /  etch pit
汤港, 张博, 李梦君, 王墉哲, 寇华敏, 王静雅, 张中晗, 姜大朋, 苏良碧. CaF2晶体(111)晶面腐蚀坑的动态演变行为与运动学特性. 硅酸盐学报, 2023 , 51 (6) : 1381 -1389 . DOI: 10.14062/j.issn.0454-5648.20230015
Gang TANG, Bo Zhang, Mengjun LI, Yongzhe WANG, Huamin KOU, Jingya WANG, Zhonghan ZHANG, Dapeng JIANG, Liangbi SU. Dynamic Evolution Behavior and Kinematic Characteristics of Each Pits on (111) Crystal Face of CaF2 Crystals[J]. Journal of the Chinese Ceramic Society, 2023 , 51 (6) : 1381 -1389 . DOI: 10.14062/j.issn.0454-5648.20230015
  • 国家重点研发计划(2022YFB3605701)
  • 中科院稳定支持基础研究领域青年团队项目(YSBR-024)
  • 国家自然科学基金(61925508; 21902178)
  • 上海市科委项目(20520750200; 22ZR1472000; 20511107400)
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文章信息
doi: 10.14062/j.issn.0454-5648.20230015
  • 接收时间:2023-01-11
  • 首发时间:2026-10-20
  • 出版时间:2023-06-20
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出版历史
  • 收稿日期:2023-01-11
  • 修回日期:2023-02-09
基金
国家重点研发计划(2022YFB3605701)
中科院稳定支持基础研究领域青年团队项目(YSBR-024)
国家自然科学基金(61925508; 21902178)
上海市科委项目(20520750200; 22ZR1472000; 20511107400)
作者信息
    1.南昌大学物理与材料学院,南昌 330031
    2.中国科学院赣江创新研究院,江西 赣州 341001
    3.中国科学院上海硅酸盐研究所,上海 201899
    4.上海电力大学,上海 200090

通讯作者:

苏良碧(1979—),男,博士,研究员。
张博(1986—),女,博士,助理研究员。
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https://castjournals.cast.org.cn/joweb/gsyxb/CN/10.14062/j.issn.0454-5648.20230015
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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