Article(id=1318974553255171025, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318974513019207979, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20221016, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1669305600000, receivedDateStr=2022-11-25, revisedDate=1669737600000, revisedDateStr=2022-11-30, acceptedDate=null, acceptedDateStr=null, onlineDate=1792397638858, onlineDateStr=2026-10-19, pubDate=1685289600000, pubDateStr=2023-05-29, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792397638858, onlineIssueDateStr=2026-10-19, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792397638858, creator=13701087609, updateTime=1792397638858, updator=13701087609, issue=Issue{id=1318974513019207979, tenantId=1146029695717560320, journalId=1263187385517883426, year='2023', volume='51', issue='7', pageStart='1649', pageEnd='1882', issueExtLink='null', onlineDate='null', pubDate='1689782400000', pubDateStr='2023-07-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1792397629265, creator='13701087609', updateTime=1792399256269, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1318981337223119779, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318974513019207979, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1318981337223119780, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318974513019207979, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1689, endPage=1696, ext={EN=ArticleExt(id=1318974553506829266, articleId=1318974553255171025, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Preparation and Lithium Storage Properties of Silicon/Reduced Graphene Oxide Nanocomposites, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=

Silicon has attracted wide attention due to its high theoretical specific capacity. However, the huge volume change and poor reaction kinetics in the lithiation process lead to a serious deterioration of its structure, a continuous capacity attenuation and a poor magnification performance, thus restricting its practical application. To solve these problems, silicon/reduced graphene oxide (Si/rGO) nanocomposites with a three-dimensional cage-like conductive structure were designed by an in-situ electrostatic self-assembly and hydrothermal reduction method with commercial Si nano-particles with the size of 60 nm and natural flake graphite. The lithium ion storage performance and energy storage mechanism of Si/rGO nanocomposite were investigated. The results show that Si nano-particles are uniformly encapsulated into a three-dimensional cage-like conductive network structure of rGO, effectively limiting the volume expansion of nano-Si particles and providing the more ion transport channels in the process of lithium ion intercalation/detachment. The specific capacity of Si/rGO nanocomposites is 1 246 mA·h/g at 0.1 A/g. The Coulomb efficiency is 98.2% and the capacity retention is 95.5% from fifth cycle, indicating that the nanocomposite has a fast stability behavior. The reversible capacity remains 852 mA·h/g, the Coulomb efficiency is 99.9%, and the capacity retention is 68.4% after 200 cycles.

, authors=Ming WANG^{1, 2}, Yonghao ZENG¹, Yue HE¹, Pengfei FANG¹, Xiaoliang WANG^{1, 2}, Ding SHEN^{1, 2}, authorsList=Ming WANG, Yonghao ZENG, Yue HE, Pengfei FANG, Xiaoliang WANG, Ding SHEN, authorCompany=null, correspAuthors=null, authorNote=, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1318974553741710291, articleId=1318974553255171025, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=硅/还原氧化石墨烯纳米复合材料的制备及储锂性能, columnId=1263922770220560512, journalTitle=硅酸盐学报, columnName=研究论文, runingTitle=null, highlight=null, articleAbstract=

以商业纳米Si颗粒（60 nm）和天然鳞片石墨为原料，采用静电原位自组装和水热还原的方法，设计开发了具有三维笼状导电网络结构的硅/还原氧化石墨烯（Si/rGO）纳米复合材料，以该复合材料为锂离子电池负极材料，研究了Si/rGO纳米复合材料储锂性能及储能机理。结果表明：纳米Si颗粒均匀地分布在rGO三维笼状导电网络结构中，在锂离子嵌入/脱出过程中，该网络结构有效地抑制了纳米Si颗粒的体积膨胀，并且提供了更多的离子传输通道。在0.1 A/g电流密度下，Si/rGO纳米复合材料的首次放电比容量达到了1 246 mA·h/g，第5次循环Coulombic效率为98.2%，容量保持率达到95.5%，表明纳米复合材料具有较快的稳定性。200次循环后，可逆容量保持在852 mA·h/g，Coulombic效率稳定在99.9%，容量保持率达到68.4%。

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王鸣（1982—），男，博士，副教授。

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王鸣（1982—），男，博士，副教授。

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