Article(id=1318974561585054311, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318974513019207979, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20220981, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1668355200000, receivedDateStr=2022-11-14, revisedDate=1669824000000, revisedDateStr=2022-12-01, acceptedDate=null, acceptedDateStr=null, onlineDate=1792397640843, onlineDateStr=2026-10-19, pubDate=1686153600000, pubDateStr=2023-06-08, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792397640843, onlineIssueDateStr=2026-10-19, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792397640843, creator=13701087609, updateTime=1792397640843, updator=13701087609, issue=Issue{id=1318974513019207979, tenantId=1146029695717560320, journalId=1263187385517883426, year='2023', volume='51', issue='7', pageStart='1649', pageEnd='1882', issueExtLink='null', onlineDate='null', pubDate='1689782400000', pubDateStr='2023-07-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1792397629265, creator='13701087609', updateTime=1792399256269, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1318981337223119779, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318974513019207979, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1318981337223119780, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318974513019207979, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1835, endPage=1846, ext={EN=ArticleExt(id=1318974561811546728, articleId=1318974561585054311, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Electrochemical Performance of Oxygen Vacancies Enhanced Transition Metal Oxides in Supercapacitor, columnId=1263922772401635899, journalTitle=Journal of the Chinese Ceramic Society, columnName=Review, runingTitle=null, highlight=null, articleAbstract=

As electrode materials for supercapacitors, transition metal oxides have some advantages of high theoretical specific capacity, good chemical stability, and abundant sources. However, its inherent poor conductivity, low utilization rate, and poor cycle stability greatly hinder its practical application. Oxygen vacancies in metal oxides can effectively regulate their electronic properties, reduce the band gap, and increase their electrical conductivity, thus significantly improving their electrochemical rate performance. Furthermore, oxygen vacancies can induce a low oxidation state of the metal, provide more active sites for surface redox reactions, and improve its electrochemical storage capacity. The review introduced various preparation methods and characterization techniques of oxygen-vacancy abundant transition metal oxides. This review also represented the latest advances of various metal oxides with oxygen vacancies from single metal oxides, bimetal oxides, and heteroatom doped metal oxides to achieve the superior performance for supercapacitors. In addition, some challenges and opportunities for the further development of metal oxides in electrochemical energy storage were also pointed out.

, authors=Chao JIANG, Xiaohua ZHANG, Shuaicheng LU, Weiteng ZHANG, Jie WANG, Xiaoyan YAN, Xinxin ZHAO, Baosheng LIU, authorsList=Chao JIANG, Xiaohua ZHANG, Shuaicheng LU, Weiteng ZHANG, Jie WANG, Xiaoyan YAN, Xinxin ZHAO, Baosheng LIU, authorCompany=null, correspAuthors=Xiaohua ZHANG, Baosheng LIU, authorNote=, correspAuthorsNote=, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1318974562088370793, articleId=1318974561585054311, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=氧空位增强金属氧化物的超级电容器储能性能, columnId=1263922774356181565, journalTitle=硅酸盐学报, columnName=综合评述, runingTitle=null, highlight=null, articleAbstract=

过渡金属氧化物作为超级电容器电极材料，具有理论比容量高、化学稳定性好以及来源丰富等优点。然而，其固有的导电性差、利用率低以及循环稳定性差等缺点很大程度上阻碍了其实际应用。金属氧化物中的氧空位能够有效调节其电子性能，降低能带隙，显著提高其电导率，改善电化学倍率性能。此外，氧空位可以诱导金属的低氧化状态，促进表面氧化还原反应的进行，产生更多的活性位点，提高其电化学储存能力。本文总结了氧空位的制备方法和表征技术，并分别从单金属氧化物、双金属氧化物、杂原子掺杂金属氧化物的角度进行分类描述，综述了近年来具有氧空位的金属氧化物在超级电容器中的应用进展。

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JIANG Chao (1997-), male, Master candidate. E-mail: s202114210112@stu.tyust.edu.cn

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JIANG Chao (1997-), male, Master candidate. E-mail: s202114210112@stu.tyust.edu.cn

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蒋超（1997—），男，硕士研究生。

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蒋超（1997—），男，硕士研究生。

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