Article(id=1318974515942634444, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318974513019207979, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20220901, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1666281600000, receivedDateStr=2022-10-21, revisedDate=1669651200000, revisedDateStr=2022-11-29, acceptedDate=null, acceptedDateStr=null, onlineDate=1792397629961, onlineDateStr=2026-10-19, pubDate=1685289600000, pubDateStr=2023-05-29, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792397629961, onlineIssueDateStr=2026-10-19, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792397629961, creator=13701087609, updateTime=1792397629961, updator=13701087609, issue=Issue{id=1318974513019207979, tenantId=1146029695717560320, journalId=1263187385517883426, year='2023', volume='51', issue='7', pageStart='1649', pageEnd='1882', issueExtLink='null', onlineDate='null', pubDate='1689782400000', pubDateStr='2023-07-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1792397629265, creator='13701087609', updateTime=1792399256269, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1318981337223119779, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318974513019207979, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1318981337223119780, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1318974513019207979, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1697, endPage=1706, ext={EN=ArticleExt(id=1318974516324316109, articleId=1318974515942634444, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=W Doped V₂O₅ Nanosheets as Cathode Material for High-Performance Aqueous Zinc Ion Battery, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=

Aqueous zinc-ion batteries (ZIBs) are considered to be prospective candidates in energy storage devices because of their excellent safety, crustal abundance, low cost and environmental benignity. Whereas, the design of a satisfied cathode material with a large specific capacity, superior rate performance and long-cycle life is still a significant challenge for ZIBs. Herein, a new strategy is proposed to use W doped V₂O₅ as cathode material for aqueous ZIBs. The W doping can effectively enlarge the lattice spacing and ion migration efficiency of V₂O₅, and the formation of W—O bond can obviously alleviate the capacity decay problem caused by structural damage and low intrinsic conductivity in the cycling process. As a result, the V₂O₅-W cathode exhibits an excellent capacity of 195.0 mA·h/g after 100 cycles at 0.1 A/g, and an impressive rate capability of 243.0 mA·h/g at the high current density of 1 A/g after 1 000 cycles. This work provides a simple, efficient and feasible strategy for designing high-performance cathode materials in ZIBs.

, authors=Biaoyang LI¹, Lin GAO¹, Lulu ZHANG¹, Xuelin YANG², authorsList=Biaoyang LI, Lin GAO, Lulu ZHANG, Xuelin YANG, authorCompany=null, correspAuthors=Lin GAO, authorNote=, correspAuthorsNote=, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1318974516777300942, articleId=1318974515942634444, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=W掺杂改性的V₂O₅纳米片球作为高性能水系锌离子电池正极材料, columnId=1263922770220560512, journalTitle=硅酸盐学报, columnName=研究论文, runingTitle=null, highlight=null, articleAbstract=

水系锌离子电池由于其优异的安全性、地壳丰度、成本低廉及绿色环保等优势被认为是一种有前景的储能设备，但设计出一种高比容量、长循环寿命及优异倍率性能的水系锌离子电池正极材料依然面临诸多挑战。本文提出了一种重金属钨掺杂改性的V₂O₅纳米片球水系锌离子电池正极材料。钨掺杂提高了V₂O₅的晶面间距和离子迁移速率，且W—O键的形成明显改善了V₂O₅在循环过程中因结构破坏，较低的本征电导率等问题导致的容量衰减情况。W掺杂的V₂O₅在0.1 A/g电流密度下循环100圈后比容量为195 mA·h/g，在1 A/g大电流密度下循环1 000圈后比容量为243 mA·h/g。此工作为今后设计出高性能水系锌离子电池正极材料提供了一种简易、高效、可行的方案。

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LI Biaoyang (1998-), male, Master candidate. E-mail: l_521529@163.com

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LI Biaoyang (1998-), male, Master candidate. E-mail: l_521529@163.com

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李彪阳（1998—），男，硕士研究生。

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李彪阳（1998—），男，硕士研究生。

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