Article(id=1319222607304573772, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222570398888648, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20220861, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1665417600000, receivedDateStr=2022-10-11, revisedDate=1668873600000, revisedDateStr=2022-11-20, acceptedDate=null, acceptedDateStr=null, onlineDate=1792456779551, onlineDateStr=2026-10-20, pubDate=1679241600000, pubDateStr=2023-03-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792456779551, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792456779551, creator=13701087609, updateTime=1792456779551, updator=13701087609, issue=Issue{id=1319222570398888648, tenantId=1146029695717560320, journalId=1263187385517883426, year='2023', volume='51', issue='3', pageStart='561', pageEnd='830', issueExtLink='null', onlineDate='null', pubDate='1679241600000', pubDateStr='2023-03-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792456770752, creator='13701087609', updateTime=1792456924637, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319223215889699377, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222570398888648, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319223215889699378, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222570398888648, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=669, endPage=676, ext={EN=ArticleExt(id=1319222607493317453, articleId=1319222607304573772, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Solid Solution Behavior of FeO_x and TiO_x in Low-Alumina Mullite, columnId=1321891111682027567, journalTitle=Journal of the Chinese Ceramic Society, columnName=Special Issue on Advances in Basic Research on Refractories Related—Review, runingTitle=null, highlight=null, articleAbstract=

Bauxite ores usually contain some iron and titanium oxides, which are difficult to remove simultaneously with conventional beneficiation processes. The oxides of iron and titanium will form low melting point phases during the preparation of mullite by sintering with bauxite, resulting in a reduction of the high-temperature properties of mullite. This review represented the solid solution behavior of iron oxides and titanium oxides in mullite based on the open spatial structure of mullite and its ability to accommodate different metal ions at different temperatures and atmospheres. The solubility of TiO₂ in mullite is 1.36%-4.10% at 1 400-1 700 ℃. Fe₂O₃ of 10%-12% can make a solid solution in mullite microstructure at 1 300 ℃. Ti³⁺ and Fe²⁺ are poorly solidified in mullite. Moreover, the formation of solid solutions of iron and titanium with mullite provides a limited enhancement of mullite properties. In addition, the efficient use of mullite containing iron and titanium was also discussed.

, authors=Xi YUE, Yong LI, Peng JIANG, Xiuhua ZHANG, authorsList=Xi YUE, Yong LI, Peng JIANG, Xiuhua ZHANG, authorCompany=null, correspAuthors=Yong LI, authorNote=, correspAuthorsNote=, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1319222607719809870, articleId=1319222607304573772, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=低铝莫来石中FeO_x和TiO_x固溶行为研究现状, columnId=1321891111858188336, journalTitle=硅酸盐学报, columnName=耐火材料相关基础研究进展专题—综合评述, runingTitle=null, highlight=null, articleAbstract=

铝矾土矿中通常含有一定量的铁和钛的氧化物，且常规的选矿工艺难以同时将铁和钛的氧化物除去。采用烧结法用铝矾土制备莫来石的过程中，铁和钛的氧化物会形成低熔点物相，导致莫来石的高温性能弱化。基于莫来石开放的空间结构以及随着温度和气氛的变化可以容纳不同的金属离子的特性，本文综述了铁氧化物和钛氧化物在莫来石中的固溶行为。1400~1700 ℃时TiO₂在莫来石中的固溶度为1.36%~4.10%（质量分数）。在1300 ℃时，10%~12%的Fe₂O₃在莫来石微结构中形成固溶体。Ti³⁺和Fe²⁺在莫来石中固溶度很低。并且铁和钛与莫来石形成固溶体对莫来石性能的提升有限。本文对含铁含钛的莫来石的高效化利用做出了展望。

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YUE Xi (1996-), female, Doctorial candidate. E-mail: yuexdyouxiang@163.com

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YUE Xi (1996-), female, Doctorial candidate. E-mail: yuexdyouxiang@163.com

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岳茜（1996—），女，博士研究生。

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岳茜（1996—），女，博士研究生。

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