Article(id=1319222575792763635, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222570398888648, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20220855, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1665331200000, receivedDateStr=2022-10-10, revisedDate=1667318400000, revisedDateStr=2022-11-02, acceptedDate=null, acceptedDateStr=null, onlineDate=1792456772039, onlineDateStr=2026-10-20, pubDate=1679241600000, pubDateStr=2023-03-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792456772039, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792456772039, creator=13701087609, updateTime=1792456772039, updator=13701087609, issue=Issue{id=1319222570398888648, tenantId=1146029695717560320, journalId=1263187385517883426, year='2023', volume='51', issue='3', pageStart='561', pageEnd='830', issueExtLink='null', onlineDate='null', pubDate='1679241600000', pubDateStr='2023-03-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792456770752, creator='13701087609', updateTime=1792456924637, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319223215889699377, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222570398888648, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319223215889699378, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222570398888648, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=619, endPage=627, ext={EN=ArticleExt(id=1319222575994090228, articleId=1319222575792763635, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Service Environment Simulation and Design of Refractory for Hydrogen-Based Shaft Furnace, columnId=1321891096775472081, journalTitle=Journal of the Chinese Ceramic Society, columnName=Special Issue on Advances in Basic Research on Refractories Related—Research Articles, runingTitle=null, highlight=null, articleAbstract=

With the development of hydrogen metallurgy and hydrogen-based shaft furnace, the corresponding refractories for critical parts have higher requirements. Understanding the service environment characteristic and implementing targeted design for the performance are thus particularly important for refractories. In this paper, the temperature, pressure and gas phase concentration distribution for interior and wall surface in reduction domain of hydrogen-based shaft furnace were simulated by a software named Ansys. Also, the thermodynamic stability of typical components of traditional refractory during the process was calculated by FactSage. The results show that the high-temperature and high-pressure service area is concentrated near the gas inlet, while H2O is concentrated in the top and bottom areas of the furnace. Increasing the temperature of inlet gas has a certain effect on the temperature field, but has little effect on the pressure field and gas phase composition. Among the typical components of conventional refractory, Al2O3, ZrO2, magnesium aluminum spinel, calcium-hexaluminate and TiO2 exhibit a thermodynamic stability, which can be used as potential refractory components of furnace walls. AlN or TiC can be used as additive materials to improve the relevant properties of these refractories. In addition, some impurity components as SiO2, MgO, CaO, Cr2O3, Fe2O3, SiC, Si3N4, B4C and BN can be eliminated. This study can provide a theoretical basis and methodological support for the service environment simulation and material component selection of refractory for a hydrogen-based shaft furnace.

, authors=Guohan YU1, Jingwen CUI2, Fei ZHAO2, Enxia XU2, Zhijun HE3, Enhui WANG1, Xinmei HOU1, authorsList=Guohan YU, Jingwen CUI, Fei ZHAO, Enxia XU, Zhijun HE, Enhui WANG, Xinmei HOU, authorCompany=null, correspAuthors=Enhui WANG, Xinmei HOU, authorNote=

YU Guohan (1998-), Male, Master Candidate. E-mail:

, correspAuthorsNote=
WANG Enhui (1990-), Male, Ph.D., Associate Professor; E-mail:
HOU Xinmei (1979-), Female, Ph.D., Professor.
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1319222576207999733, articleId=1319222575792763635, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=氢基竖炉用耐火材料服役环境模拟及设计, columnId=1321891096976798674, journalTitle=硅酸盐学报, columnName=耐火材料相关基础研究进展专题—研究论文, runingTitle=null, highlight=null, articleAbstract=

随着氢冶金技术及氢基竖炉的发展与推广,对其关键部位用耐火材料提出更高要求,明晰耐火材料服役环境特点并进行针对性的性能设计尤为关键。利用Ansys软件对氢基竖炉还原段内部及壁面服役过程中的温度、压强以及气相浓度分布进行数值模拟研究,并利用FactSage软件计算传统耐火材料典型组分在服役状态下的热力学稳定性。结果表明,高温高压服役区域集中在进气口附近,H2O集中在炉顶及炉底区域。提高入炉气体温度对炉内温度场有一定影响,对压强场及气相组成基本无影响。传统耐火材料典型组分中Al2O3、ZrO2、镁铝尖晶石、六铝酸钙及TiO2的热力学稳定性较强,可作为炉壁耐火材料组分,AlN或TiC可作为添加剂提高相关性能,同时避免引入SiO2、MgO、CaO、Cr2O3、Fe2O3、SiC、Si3N4、B4C、BN杂质组分。本研究可为氢基竖炉用耐火材料服役环境仿真及材料组分选择提供理论基础和方法支持。

, authors=于国瀚1, 崔竞文2, 赵飞2, 徐恩霞2, 何志军3, 王恩会1, 侯新梅1, authorsList=于国瀚, 崔竞文, 赵飞, 徐恩霞, 何志军, 王恩会, 侯新梅, authorCompany=null, correspAuthors=王恩会, 侯新梅, authorNote=

于国瀚(1998—),男,硕士研究生。

, correspAuthorsNote=
王恩会(1990—),男,博士,副研究员;
侯新梅(1979—),女,博士,教授。
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于国瀚(1998—),男,硕士研究生。

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氢基竖炉用耐火材料服役环境模拟及设计
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于国瀚 1 , 崔竞文 2 , 赵飞 2 , 徐恩霞 2 , 何志军 3 , 王恩会 1 , 侯新梅 1
硅酸盐学报 | 耐火材料相关基础研究进展专题—研究论文 2023,51(3): 619-627
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硅酸盐学报 |耐火材料相关基础研究进展专题—研究论文 2023 , 51 (3) : 619 -627
氢基竖炉用耐火材料服役环境模拟及设计
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于国瀚(1998—),男,硕士研究生。

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于国瀚1 , 崔竞文2, 赵飞2, 徐恩霞2, 何志军3, 王恩会1 , 侯新梅1
作者信息
  • 1.北京科技大学碳中和创新研究院,北京 100083
  • 2.郑州大学材料科学与工程学院,郑州 450052
  • 3.辽宁科技大学材料与冶金学院,辽宁 鞍山 114051
通讯作者:
王恩会(1990—),男,博士,副研究员;
侯新梅(1979—),女,博士,教授。
作者简介:

于国瀚(1998—),男,硕士研究生。

Service Environment Simulation and Design of Refractory for Hydrogen-Based Shaft Furnace
Guohan YU1 , Jingwen CUI2, Fei ZHAO2, Enxia XU2, Zhijun HE3, Enhui WANG1 , Xinmei HOU1
Affiliations
  • 1.Innovation Research Institute for Carbon Neutrality, University of Science and Technology Beijing, Beijing 100083, China
  • 2.School of Material Science and Engineering, Zhengzhou University, Zhengzhou 450002, China
  • 3.School of Materials and Metallurgy, University of Science and Technology Liaoning, Anshan 114051, Liaoning, China
  • Corresponding Author:
    WANG Enhui (1990-), Male, Ph.D., Associate Professor; E-mail:
    HOU Xinmei (1979-), Female, Ph.D., Professor.

    YU Guohan (1998-), Male, Master Candidate. E-mail:

出版时间: 2023-03-20 doi: 10.14062/j.issn.0454-5648.20220855
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随着氢冶金技术及氢基竖炉的发展与推广,对其关键部位用耐火材料提出更高要求,明晰耐火材料服役环境特点并进行针对性的性能设计尤为关键。利用Ansys软件对氢基竖炉还原段内部及壁面服役过程中的温度、压强以及气相浓度分布进行数值模拟研究,并利用FactSage软件计算传统耐火材料典型组分在服役状态下的热力学稳定性。结果表明,高温高压服役区域集中在进气口附近,H2O集中在炉顶及炉底区域。提高入炉气体温度对炉内温度场有一定影响,对压强场及气相组成基本无影响。传统耐火材料典型组分中Al2O3、ZrO2、镁铝尖晶石、六铝酸钙及TiO2的热力学稳定性较强,可作为炉壁耐火材料组分,AlN或TiC可作为添加剂提高相关性能,同时避免引入SiO2、MgO、CaO、Cr2O3、Fe2O3、SiC、Si3N4、B4C、BN杂质组分。本研究可为氢基竖炉用耐火材料服役环境仿真及材料组分选择提供理论基础和方法支持。

氢基竖炉  /  耐火材料  /  数值模拟  /  热力学计算

With the development of hydrogen metallurgy and hydrogen-based shaft furnace, the corresponding refractories for critical parts have higher requirements. Understanding the service environment characteristic and implementing targeted design for the performance are thus particularly important for refractories. In this paper, the temperature, pressure and gas phase concentration distribution for interior and wall surface in reduction domain of hydrogen-based shaft furnace were simulated by a software named Ansys. Also, the thermodynamic stability of typical components of traditional refractory during the process was calculated by FactSage. The results show that the high-temperature and high-pressure service area is concentrated near the gas inlet, while H2O is concentrated in the top and bottom areas of the furnace. Increasing the temperature of inlet gas has a certain effect on the temperature field, but has little effect on the pressure field and gas phase composition. Among the typical components of conventional refractory, Al2O3, ZrO2, magnesium aluminum spinel, calcium-hexaluminate and TiO2 exhibit a thermodynamic stability, which can be used as potential refractory components of furnace walls. AlN or TiC can be used as additive materials to improve the relevant properties of these refractories. In addition, some impurity components as SiO2, MgO, CaO, Cr2O3, Fe2O3, SiC, Si3N4, B4C and BN can be eliminated. This study can provide a theoretical basis and methodological support for the service environment simulation and material component selection of refractory for a hydrogen-based shaft furnace.

hydrogen-based shaft furnace  /  refractory  /  numerical simulation  /  thermodynamic calculation
于国瀚, 崔竞文, 赵飞, 徐恩霞, 何志军, 王恩会, 侯新梅. 氢基竖炉用耐火材料服役环境模拟及设计. 硅酸盐学报, 2023 , 51 (3) : 619 -627 . DOI: 10.14062/j.issn.0454-5648.20220855
Guohan YU, Jingwen CUI, Fei ZHAO, Enxia XU, Zhijun HE, Enhui WANG, Xinmei HOU. Service Environment Simulation and Design of Refractory for Hydrogen-Based Shaft Furnace[J]. Journal of the Chinese Ceramic Society, 2023 , 51 (3) : 619 -627 . DOI: 10.14062/j.issn.0454-5648.20220855
  • 国家自然科学基金资助项目(52025041; 51974021)
  • 中央高校基本科研业务费资助项目(FRF-TP-20-02C2)
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2023年第51卷第3期
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doi: 10.14062/j.issn.0454-5648.20220855
  • 接收时间:2022-10-10
  • 首发时间:2026-10-20
  • 出版时间:2023-03-20
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  • 收稿日期:2022-10-10
  • 修回日期:2022-11-02
基金
国家自然科学基金资助项目(52025041; 51974021)
中央高校基本科研业务费资助项目(FRF-TP-20-02C2)
作者信息
    1.北京科技大学碳中和创新研究院,北京 100083
    2.郑州大学材料科学与工程学院,郑州 450052
    3.辽宁科技大学材料与冶金学院,辽宁 鞍山 114051

通讯作者:

王恩会(1990—),男,博士,副研究员;
侯新梅(1979—),女,博士,教授。
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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