Article(id=1319222583787111041, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222570398888648, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20220829, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1664640000000, receivedDateStr=2022-10-02, revisedDate=1666540800000, revisedDateStr=2022-10-24, acceptedDate=null, acceptedDateStr=null, onlineDate=1792456773944, onlineDateStr=2026-10-20, pubDate=1679241600000, pubDateStr=2023-03-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792456773944, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792456773944, creator=13701087609, updateTime=1792456773944, updator=13701087609, issue=Issue{id=1319222570398888648, tenantId=1146029695717560320, journalId=1263187385517883426, year='2023', volume='51', issue='3', pageStart='561', pageEnd='830', issueExtLink='null', onlineDate='null', pubDate='1679241600000', pubDateStr='2023-03-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792456770752, creator='13701087609', updateTime=1792456924637, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319223215889699377, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222570398888648, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319223215889699378, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222570398888648, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=628, endPage=634, ext={EN=ArticleExt(id=1319222583971660418, articleId=1319222583787111041, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Design and Preparation of Y2O3-Al2O3-MgO-CaO Refractories for Titanium Alloy Smelting, columnId=1321891096775472081, journalTitle=Journal of the Chinese Ceramic Society, columnName=Special Issue on Advances in Basic Research on Refractories Related—Research Articles, runingTitle=null, highlight=null, articleAbstract=

Crucible refractories are very important for the quality of titanium alloy smelting. In order to develop novel crucible material with high performance, in this work, Y2O3-Al2O3-MgO-CaO composite refractories were prepared with commercial yttrium oxide and Al2O3-MgO-CaO powders (AMC) as raw materials, and the effects of sintering temperature (i.e., 1 500 ℃, 1 600 ℃) and AMC contents (i.e., 0, 25%, 50%, 75% and 100%, in mass fraction) on the phase compositions, sintering properties (i.e., linear shrinkage, volumetric shrinkage, apparent porosity, and bulk density), compressive strength at room temperature, thermal shock resistance and microstructures of as-prepared refractories were investigated. The results show that the most properties of the composites are improved, compared with Y2O3 and AMC. The performance becomes better as the sintering temperature increases. Moreover, the linear shrinkage, volumetric shrinkage, bulk density and compressive strength at room temperature of the composites increase with the increase of AMC contents. At the AMC content of 75%, the composite sintered at 1 500 ℃ for 3 h has the optimum comprehensive performance (i.e., the apparent porosity of 4.37%, the compressive strength at room temperature of 274.99 MPa, the residual strength after three water-cooling and thermal shocks of 161.60 MPa, and the residual strength ratio of 58.78%).

, authors=Kun LIU1, Beiyue MA1, Ping ZHOU1, Wenyu ZAN1, Chao YU2, Chengji DENG2, Zhoufu WANG2, authorsList=Kun LIU, Beiyue MA, Ping ZHOU, Wenyu ZAN, Chao YU, Chengji DENG, Zhoufu WANG, authorCompany=null, correspAuthors=Beiyue MA, authorNote=

LIU Kun (1997-), male, Master candidate. E-mail:

, correspAuthorsNote=
MA Beiyue (1978-), male, Ph.D., Professor. E-mail:
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坩埚耐火材料对钛合金熔炼的质量非常重要,为开发高性能新型坩埚材料,以工业Y2O3和Al2O3-MgO-CaO系粉末(AMC)为原料,制备出Y2O3-Al2O3-MgO-CaO系复合耐火材料,研究了烧结温度(1500 ℃、1600 ℃)和AMC含量(0、25%、50%、75%和100%,质量分数)对所制备耐火材料的物相组成、烧结性能(线收缩率、体积收缩率、显气孔率、体积密度)、常温耐压强度、抗热震性能和显微结构的影响。结果表明:相对于Y2O3和AMC材料,复合材料的性能均有所提高;提高烧结温度,其性能更佳;且随着AMC含量的提高,复合材料的线收缩率、体积收缩率、体积密度和常温耐压强度随之增大,显气孔率降低;当AMC的质量含量为75%时,1500 ℃烧结3 h制得复合材料的综合性能最优,其显气孔率为4.37%,常温耐压强度为274.99 MPa,3次水冷热震后残余强度为161.60 MPa,残余强度保持率为58.78%。

, authors=刘坤1, 马北越1, 周萍1, 昝文宇1, 余超2, 邓承继2, 王周福2, authorsList=刘坤, 马北越, 周萍, 昝文宇, 余超, 邓承继, 王周福, authorCompany=null, correspAuthors=马北越, authorNote=

刘坤(1997—),男,硕士研究生。

, correspAuthorsNote=
马北越(1978—),男,博士,教授。
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钛合金熔炼用Y2O3-Al2O3-MgO-CaO系耐火材料的设计与制备
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刘坤 1 , 马北越 1 , 周萍 1 , 昝文宇 1 , 余超 2 , 邓承继 2 , 王周福 2
硅酸盐学报 | 耐火材料相关基础研究进展专题—研究论文 2023,51(3): 628-634
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硅酸盐学报 |耐火材料相关基础研究进展专题—研究论文 2023 , 51 (3) : 628 -634
钛合金熔炼用Y2O3-Al2O3-MgO-CaO系耐火材料的设计与制备
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刘坤(1997—),男,硕士研究生。

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刘坤1 , 马北越1 , 周萍1, 昝文宇1, 余超2, 邓承继2, 王周福2
作者信息
  • 1.东北大学冶金学院,沈阳 110819
  • 2.武汉科技大学,省部共建耐火材料与冶金国家重点实验室,武汉 430081
通讯作者:
马北越(1978—),男,博士,教授。
作者简介:

刘坤(1997—),男,硕士研究生。

Design and Preparation of Y2O3-Al2O3-MgO-CaO Refractories for Titanium Alloy Smelting
Kun LIU1 , Beiyue MA1 , Ping ZHOU1, Wenyu ZAN1, Chao YU2, Chengji DENG2, Zhoufu WANG2
Affiliations
  • 1.School of Metallurgy, Northeastern University, Shenyang 110819, China
  • 2.The State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan 430081, China
  • Corresponding Author:
    MA Beiyue (1978-), male, Ph.D., Professor. E-mail:

    LIU Kun (1997-), male, Master candidate. E-mail:

出版时间: 2023-03-20 doi: 10.14062/j.issn.0454-5648.20220829
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坩埚耐火材料对钛合金熔炼的质量非常重要,为开发高性能新型坩埚材料,以工业Y2O3和Al2O3-MgO-CaO系粉末(AMC)为原料,制备出Y2O3-Al2O3-MgO-CaO系复合耐火材料,研究了烧结温度(1500 ℃、1600 ℃)和AMC含量(0、25%、50%、75%和100%,质量分数)对所制备耐火材料的物相组成、烧结性能(线收缩率、体积收缩率、显气孔率、体积密度)、常温耐压强度、抗热震性能和显微结构的影响。结果表明:相对于Y2O3和AMC材料,复合材料的性能均有所提高;提高烧结温度,其性能更佳;且随着AMC含量的提高,复合材料的线收缩率、体积收缩率、体积密度和常温耐压强度随之增大,显气孔率降低;当AMC的质量含量为75%时,1500 ℃烧结3 h制得复合材料的综合性能最优,其显气孔率为4.37%,常温耐压强度为274.99 MPa,3次水冷热震后残余强度为161.60 MPa,残余强度保持率为58.78%。

复合耐火材料  /  氧化钇  /  钙镁铝酸盐  /  烧结温度  /  原料配比

Crucible refractories are very important for the quality of titanium alloy smelting. In order to develop novel crucible material with high performance, in this work, Y2O3-Al2O3-MgO-CaO composite refractories were prepared with commercial yttrium oxide and Al2O3-MgO-CaO powders (AMC) as raw materials, and the effects of sintering temperature (i.e., 1 500 ℃, 1 600 ℃) and AMC contents (i.e., 0, 25%, 50%, 75% and 100%, in mass fraction) on the phase compositions, sintering properties (i.e., linear shrinkage, volumetric shrinkage, apparent porosity, and bulk density), compressive strength at room temperature, thermal shock resistance and microstructures of as-prepared refractories were investigated. The results show that the most properties of the composites are improved, compared with Y2O3 and AMC. The performance becomes better as the sintering temperature increases. Moreover, the linear shrinkage, volumetric shrinkage, bulk density and compressive strength at room temperature of the composites increase with the increase of AMC contents. At the AMC content of 75%, the composite sintered at 1 500 ℃ for 3 h has the optimum comprehensive performance (i.e., the apparent porosity of 4.37%, the compressive strength at room temperature of 274.99 MPa, the residual strength after three water-cooling and thermal shocks of 161.60 MPa, and the residual strength ratio of 58.78%).

composite refractories  /  yttrium oxide  /  calcium magnesium aluminate  /  sintering temperature  /  raw material ratio
刘坤, 马北越, 周萍, 昝文宇, 余超, 邓承继, 王周福. 钛合金熔炼用Y2O3-Al2O3-MgO-CaO系耐火材料的设计与制备. 硅酸盐学报, 2023 , 51 (3) : 628 -634 . DOI: 10.14062/j.issn.0454-5648.20220829
Kun LIU, Beiyue MA, Ping ZHOU, Wenyu ZAN, Chao YU, Chengji DENG, Zhoufu WANG. Design and Preparation of Y2O3-Al2O3-MgO-CaO Refractories for Titanium Alloy Smelting[J]. Journal of the Chinese Ceramic Society, 2023 , 51 (3) : 628 -634 . DOI: 10.14062/j.issn.0454-5648.20220829
  • 国家自然科学基金区域创新发展联合基金重点项目资助(U21A2057)
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doi: 10.14062/j.issn.0454-5648.20220829
  • 接收时间:2022-10-02
  • 首发时间:2026-10-20
  • 出版时间:2023-03-20
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  • 收稿日期:2022-10-02
  • 修回日期:2022-10-24
基金
国家自然科学基金区域创新发展联合基金重点项目资助(U21A2057)
作者信息
    1.东北大学冶金学院,沈阳 110819
    2.武汉科技大学,省部共建耐火材料与冶金国家重点实验室,武汉 430081

通讯作者:

马北越(1978—),男,博士,教授。
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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