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Article(id=1319222879204528434, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222716851405704, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20220757, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1663171200000, receivedDateStr=2022-09-15, revisedDate=1665417600000, revisedDateStr=2022-10-11, acceptedDate=null, acceptedDateStr=null, onlineDate=1792456844377, onlineDateStr=2026-10-20, pubDate=1687190400000, pubDateStr=2023-06-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792456844377, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792456844377, creator=13701087609, updateTime=1792456844377, updator=13701087609, issue=Issue{id=1319222716851405704, tenantId=1146029695717560320, journalId=1263187385517883426, year='2023', volume='51', issue='6', pageStart='1373', pageEnd='1648', issueExtLink='null', onlineDate='null', pubDate='1687190400000', pubDateStr='2023-06-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792456805669, creator='13701087609', updateTime=1792456995739, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319223514108903801, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222716851405704, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319223514108903802, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222716851405704, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1450, endPage=1468, ext={EN=ArticleExt(id=1319222879422632243, articleId=1319222879204528434, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Lattice Modulation, Spectral Characteristics and Emerging Applications of Transition Metal Ion-Doped Garnet Fluorescent Materials, columnId=1321890982912708732, journalTitle=Journal of the Chinese Ceramic Society, columnName=Special Topics Progress of Fundamental Research of Crystal Structures and Defects—Review, runingTitle=null, highlight=null, articleAbstract=

Garnet-based phosphor materials have some advantages of multi-site of doping icons, a wide option of doping ions, and a high efficiency of energy transfer, thus becoming a research hotspot for inorganic luminous materials. Compared with rare-earth ions, transition metal ions have superior features of spectral regulation and low cost. However, its luminous efficiency, valence, and luminous mechanism in complex lattice structures are still unclear. This review summarized the spectral characteristics and luminescent behavior of transition metal ions, especially Cr3+, Mn2+/4+. In addition, the application of transition metal ions in the fields of solid-state lighting, displays, biomedical imaging, and plant lighting was also represented.

, authors=Congcong YANG1, Le ZHANG1, Jian KANG1, Bingheng SUN2, Pengfei SANG1, Hao CHEN1, authorsList=Congcong YANG, Le ZHANG, Jian KANG, Bingheng SUN, Pengfei SANG, Hao CHEN, authorCompany=null, correspAuthors=Le ZHANG, Hao CHEN, authorNote=

YANG Congcong (1996-), female, Master candidate. E-mail:

, correspAuthorsNote=
ZHANG Le (1988-), male, Ph.D., Professor. E-mail:
CHEN Hao (1976-), male, Ph.D., Professor.
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1319222879682679092, articleId=1319222879204528434, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=过渡金属离子掺杂石榴石基荧光材料的晶格调控、光谱特性及应用, columnId=1321890983659294845, journalTitle=硅酸盐学报, columnName=晶体结构与缺陷相关基础研究进展专题—综合评述, runingTitle=null, highlight=null, articleAbstract=

石榴石基荧光材料具有多格位掺杂、离子掺杂选择范围宽、能量传递效率高等突出优势，是无机发光材料研究的热点；过渡金属离子在光谱可调谐性、原料来源广泛性等方面显著优于稀土离子；然而，其在发光效率、价态调控特别是在复杂晶格结构中的发光机理尚存在挑战，吸引了众多研究者关注。本文综述了过渡金属离子特别是Cr3+、Mn2+/4+在石榴石结构荧光材料中的光谱特性和发光行为，介绍了该类材料在固态照明与显示、生物医学成像、植物照明等前沿领域的研究与应用现状。

, authors=杨聪聪1, 张乐1, 康健1, 孙炳恒2, 桑鹏飞1, 陈浩1, authorsList=杨聪聪, 张乐, 康健, 孙炳恒, 桑鹏飞, 陈浩, authorCompany=null, correspAuthors=张乐, 陈浩, authorNote=

杨聪聪（1996—），女，硕士研究生。

, correspAuthorsNote=
张乐（1988—），男，博士，教授。
陈浩（1976—），男，博士，教授。
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YANG Congcong (1996-), female, Master candidate. E-mail:

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YANG Congcong (1996-), female, Master candidate. E-mail:

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杨聪聪（1996—），女，硕士研究生。

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杨聪聪（1996—），女，硕士研究生。

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过渡金属离子掺杂石榴石基荧光材料的晶格调控、光谱特性及应用
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杨聪聪 1 , 张乐 1 , 康健 1 , 孙炳恒 2 , 桑鹏飞 1 , 陈浩 1
硅酸盐学报 | 晶体结构与缺陷相关基础研究进展专题—综合评述 2023,51(6): 1450-1468
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硅酸盐学报 |晶体结构与缺陷相关基础研究进展专题—综合评述 2023 , 51 (6) : 1450 -1468
过渡金属离子掺杂石榴石基荧光材料的晶格调控、光谱特性及应用
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YANG Congcong (1996-), female, Master candidate. E-mail:

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杨聪聪（1996—），女，硕士研究生。

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杨聪聪1 , 张乐1 , 康健1, 孙炳恒2, 桑鹏飞1, 陈浩1
作者信息
  • 1．江苏师范大学物理与电子工程学院，江苏省先进激光材料与器件重点实验室，江苏 徐州 221116
  • 2．中国科学院上海光学精密机械研究所，上海 201800
通讯作者:
张乐（1988—），男，博士，教授。
陈浩（1976—），男，博士，教授。
作者简介:

杨聪聪（1996—），女，硕士研究生。

Lattice Modulation, Spectral Characteristics and Emerging Applications of Transition Metal Ion-Doped Garnet Fluorescent Materials
Congcong YANG1 , Le ZHANG1 , Jian KANG1, Bingheng SUN2, Pengfei SANG1, Hao CHEN1
Affiliations
  • 1.School of Physics Electronic Engineering, Jiangsu Normal University, Jiangsu Key Laboratory of Advanced Laser Materials and Devices, Xuzhou 221116, Jiangsu, China
  • 2.Shanghai Institute of Optics Fine Mechanics, Chiense Academy of Sciences, Shanghai 201800, China
    • Corresponding Author:
    ZHANG Le (1988-), male, Ph.D., Professor. E-mail:
    CHEN Hao (1976-), male, Ph.D., Professor.

    YANG Congcong (1996-), female, Master candidate. E-mail:

出版时间: 2023-06-20 doi: 10.14062/j.issn.0454-5648.20220757
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石榴石基荧光材料具有多格位掺杂、离子掺杂选择范围宽、能量传递效率高等突出优势，是无机发光材料研究的热点；过渡金属离子在光谱可调谐性、原料来源广泛性等方面显著优于稀土离子；然而，其在发光效率、价态调控特别是在复杂晶格结构中的发光机理尚存在挑战，吸引了众多研究者关注。本文综述了过渡金属离子特别是Cr3+、Mn2+/4+在石榴石结构荧光材料中的光谱特性和发光行为，介绍了该类材料在固态照明与显示、生物医学成像、植物照明等前沿领域的研究与应用现状。

过渡金属  /  石榴石体系  /  荧光材料  /  发光材料

Garnet-based phosphor materials have some advantages of multi-site of doping icons, a wide option of doping ions, and a high efficiency of energy transfer, thus becoming a research hotspot for inorganic luminous materials. Compared with rare-earth ions, transition metal ions have superior features of spectral regulation and low cost. However, its luminous efficiency, valence, and luminous mechanism in complex lattice structures are still unclear. This review summarized the spectral characteristics and luminescent behavior of transition metal ions, especially Cr3+, Mn2+/4+. In addition, the application of transition metal ions in the fields of solid-state lighting, displays, biomedical imaging, and plant lighting was also represented.

transition metals  /  garnet structure  /  fluorescent materials  /  luminescent materials
杨聪聪, 张乐, 康健, 孙炳恒, 桑鹏飞, 陈浩. 过渡金属离子掺杂石榴石基荧光材料的晶格调控、光谱特性及应用. 硅酸盐学报, 2023 , 51 (6) : 1450 -1468 . DOI: 10.14062/j.issn.0454-5648.20220757
Congcong YANG, Le ZHANG, Jian KANG, Bingheng SUN, Pengfei SANG, Hao CHEN. Lattice Modulation, Spectral Characteristics and Emerging Applications of Transition Metal Ion-Doped Garnet Fluorescent Materials[J]. Journal of the Chinese Ceramic Society, 2023 , 51 (6) : 1450 -1468 . DOI: 10.14062/j.issn.0454-5648.20220757
基金
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  • 国家重点研发计划(2021YFB3501700)
  • 国家自然科学基金(52202135; 61975070; 51902143; 61971207)
  • 江苏省高校优势学科建设项目(PAPD)
  • 江苏省重点研发项目(BE2019033; BE2021040)
  • 江苏省自然科学基金(BK20191467; BK20221226)
  • 江苏省国际科技合作项目(BZ2019063; BZ2020045; BZ2020030)
  • 江苏省高等学校自然科学基金(19KJB430018; 20KJA430003)
  • 徐州市技术创新专项(KC19250; KC20201; KC20244; KC21379)
  • 先进材料与电子元器件国家重点实验室开放课题(FHR-JS-202011017)
  • 江苏省研究生科研与实践创新计划(KYCX21_2568)
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文章信息
doi: 10.14062/j.issn.0454-5648.20220757
  • 接收时间：2022-09-15
  • 首发时间：2026-10-20
  • 出版时间：2023-06-20
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出版历史
  • 收稿日期：2022-09-15
  • 修回日期：2022-10-11
基金
国家重点研发计划(2021YFB3501700)
国家自然科学基金(52202135; 61975070; 51902143; 61971207)
江苏省高校优势学科建设项目(PAPD)
江苏省重点研发项目(BE2019033; BE2021040)
江苏省自然科学基金(BK20191467; BK20221226)
江苏省国际科技合作项目(BZ2019063; BZ2020045; BZ2020030)
江苏省高等学校自然科学基金(19KJB430018; 20KJA430003)
徐州市技术创新专项(KC19250; KC20201; KC20244; KC21379)
先进材料与电子元器件国家重点实验室开放课题(FHR-JS-202011017)
江苏省研究生科研与实践创新计划(KYCX21_2568)
作者信息
    1．江苏师范大学物理与电子工程学院，江苏省先进激光材料与器件重点实验室，江苏 徐州 221116
    2．中国科学院上海光学精密机械研究所，上海 201800

通讯作者:

张乐（1988—），男，博士，教授。
陈浩（1976—），男，博士，教授。
参考文献
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https://castjournals.cast.org.cn/joweb/gsyxb/CN/10.14062/j.issn.0454-5648.20220757
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2种不同金属材料的力学参数
科
Family		 属数
Number of
genus		 种数
Number of
species		 占总种数比例
Percentage of
total species (%)		 属
Genus		 种数
Number of
species		 占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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